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  • The title compound, [Fe(C5H5)(C21H24NO2)], which is produced by the oxidation of 1-(4-tert-butylphenyl)-2-ethyl-3-ferrocenylpyrrole, crystallizes as a racemic mixture in the centrosymmetric space group P21/n. The central heterocyclic pyrrole ring system subtends dihedral angles of 13.7 (2)° with respect to the attached cyclopentadienyl ring and of 43.6 (7)° with the major component of the disordered phenyl group bound to the N atom. The 4-tert-butylphenyl group, as well as the non-substituted Cp ring are disordered with s.o.f. values of 0.589 (16) and 0.411 (16), respectively. In the crystal, molecules with the same absolute configuration are linked into infinite chains along the b-axis direction by O—H···O hydrogen bonds between the hydroxy substituent and the carbonyl O atom of the adjacent molecule.

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Author:Tobias Biletzki, Helmar Görls, Wolfgang Imhof
Parent Title (English):Crystallographic communications
Document Type:Article
Date of completion:2024/06/10
Date of publication:2024/06/10
Publishing institution:Universität Koblenz, Universitätsbibliothek
Release Date:2024/06/10
Tag:crystal structure; ferrocene; pyrrole; pyrrolone
First page:264
Last page:266
Institutes:Fachbereich 3 / Institut für Integrierte Naturwissenschaften / Institut für Integrierte Naturwissenschaften, Abt. Chemie
Licence (German):License LogoEs gilt das deutsche Urheberrecht: § 53 UrhG