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Diet-related effects of antimicrobials in aquatic decomposer-shredder and periphyton-grazer systems
(2022)
Leaf-associated microbial decomposers as well as periphyton serve as important food sources for detritivorous and herbivorous macroinvertebrates (shredders and grazers) in streams. Shredders and grazers, in turn, provide not only collectors with food but also serve as prey for predators. Therefore, decomposer-shredder and periphyton-grazer systems (here summarized as freshwater biofilm-consumer systems) are highly important for the energy and nutrient supply in heterotrophic and autotrophic stream food webs. However, both systems can be affected by chemical stressors, amongst which antimicrobials (e.g., antibiotics, fungicides and algaecides) are of particular concern. Antimicrobials can impair shredders and grazers not only via waterborne exposure (waterborne effect pathway) but also through dietary exposure and microorganism-mediated alterations in the food quality of their diet (dietary effect pathway). Even though the relevance of the latter pathway received more attention in recent years, little is known about the mechanisms that are responsible for the observed effects in shredders and grazers. Therefore, the first objective of this thesis was to broaden the knowledge of indirect antimicrobial effects in a model shredder and grazer via the dietary pathway. Moreover, although freshwater biofilm-consumer systems are most likely exposed to antimicrobial mixtures comprised of different stressor groups, virtually nothing is known of these mixture effects in both systems. Therefore, the second objective was to assess and predict diet-related antimicrobial mixture effects in a model freshwater biofilm-consumer system. During this thesis, positive diet-related effects of a model antibiotic on the energy processing and physiology of the shredder Gammarus fossarum were observed. They were probably triggered by shifts in the leaf-associated microbial community in favor of aquatic fungi that increased the food quality of leaves for the shredder. Contrary to that, a model fungicide induced negative effects on the energy processing of G. fossarum via the dietary pathway, which can be explained by negative impacts on the microbial decomposition efficiency leading to a reduced food quality of leaf litter for gammarids. For diet-related antimicrobial effects in periphyton-grazer systems, a model algaecide altered the periphyton community composition by increasing nutritious and palatable algae. This resulted in an enhanced consumption and physiological fitness of the grazer Physella acuta. Finally, it was shown that complex horizontal interactions among leaf-associated microorganisms are involved, making diet-related antimicrobial mixture effects in the shredder G. fossarum difficult to predict. Thus, this thesis provides new insights into indirect diet-related effects of antimicrobials on shredders and grazers as well as demonstrates uncertainties of antimicrobial mixture effect predictions for freshwater biofilm-consumer systems. Moreover, the findings in this thesis are not only informative for regulatory authorities, as indirect effects and effects of mixtures across chemical classes are not considered in the environmental risk assessment of chemical substances, but also stimulate future research to close knowledge gaps identified during this work.
Remote Working Study 2022
(2022)
The Remote Working Study 2022 is focused on the transition to work from home (WFH) triggered by the stay at home directives of 2020. These directives required employees to work in their private premises wherever possible to reduce the transmission of the coronavirus. The study, conducted by the Center for Enterprise Information Research (CEIR) at the University of Koblenz from December 2021 to January 2022, explores the transition to remote working.
The objective of the survey is to collect baseline information about organisations’ remote work experiences during and immediately following the COVID-19 lockdowns. The survey was completed by the key persons responsible for the implementation and/or management of the digital workplace in 19 German and Swiss organisations.
The data presented in this report was collected from member organisations of the IndustryConnect initiative. IndustryConnect is a university-industry research programme that is coordinated by researchers from the University of Koblenz. It focuses on research in the areas of the digital workplace and enterprise collaboration technologies, and facilitates the generation of new research insights and the exchange of experiences among user companies.
Beim Zugang zur dualen Berufsausbildung haben Jugendliche und junge Erwachsene mit Migrationshintergrund schlechtere Chancen in eine betriebliche Berufsausbildung einzumünden. Vermehrt wird ein Forschungsbedarf thematisiert, der den Blick darauf richtet, wie die entsprechenden Auswahlentscheidungen in den Betrieben getroffen werden. Die Dissertation setzt an dieser Frage an und befasst sich mittels eines biographischen Zugangs mit den Personalentscheiderinnen und Personalentscheidern, den sogenannten Gatekeepern, in den Betrieben. Im Erkenntnisinteresse steht die Frage, ob und wie biographische Erfahrungen Bedeutung für Auswahlentscheidungen zugunsten zugewanderter junger Menschen haben.
To render the surface of a material capable of withstanding mechanical and electrochemical loads, and to perform well in service, the deposition of a thin film or coating is a solution. In this project, such a thin film deposition is carried out. The coating material chosen is titanium nitride (TiN) which is a ceramic material known to possess a high hardness (>10 GPa) as well as good corrosion resistance. The method of deposition selected is high power impulse magnetron sputtering (HiPIMS) that results in coatings with high quality and enhanced properties. Sputtering is a physical process that represents the removal or dislodgment of surface atoms by energetic particle bombardment. The term magnetron indicates that a magnetic field is utilized to increase the efficiency of the sputtering process. In HiPIMS, a high power is applied in pulses of low duty cycles to a cathode that is sputtered and that consists of the coating material. As result of the high power, the ionization of the sputtered material takes place giving the possibility to control these species with electric and magnetic field allowing thereby the improvement and tuning of coating properties. However, the drawback of HiPIMS is a low deposition rate.
In this project, it is demonstrated first that it is possible to deposit TiN coating using HiPIMS with an optimized deposition rate, by varying the magnetic field strength. It was found that low magnetic field strength (here 22mT) results in a deposition rate similar to that of conventional magnetron sputtering in which the average power is applied continuously, called also direct current magnetron sputtering (dcMS). The high deposition rate at low magnetic field strength was attributed to a reduction in the back attraction probability of the sputtered species. The magnetic field strength did not show noticeable influence on the mechanical properties. The proposed explanation was that the considered peak current density interval 1.22-1.72 A∙cm-2 does not exhibit dramatic changes in the plasma dynamics.
In a second part, using the optimized deposition rate, the optimized chemical composition of TiN was determined. It was shown that the chemical composition of TiN does not significantly influence the corrosion performance but impacts considerably the mechanical properties. It was also shown that the corrosion resistance of the coatings deposited using HiPIMS was higher than that of the coatings deposited using dcMS.
The third study was the effect of annealing post deposition on the properties of TiN coating deposited using HiPIMS. The hardness of the coatings showed a maximum at 400°C reaching 24.8 GPa. Above 400°C however, a lowering of the hardness was measured and was due to the oxidation of TiN which led to the formation of TiN-TiO2 composites with lower mechanical properties.
The coating microscopic properties such as crystal orientation, residual stresses, average grain size were determined from X-ray diffraction data and the roughness was measured using atomic force microscopy. These properties were found to vary with the magnetic field strength, the chemical composition as well as the annealing temperature.
Der Zweck dieser Arbeit ist es, sich auf die kritischen Forschungsherausforderungen und -themen zu konzentrieren, die UI/UX-Designprinzipien umgeben, mit einem Schwerpunkt auf kulturübergreifenden Konzepten aus der Perspektive von E-Learning-Plattformen. Zu diesem Zweck betrachten wir zunächst die kulturellen Dimensionen auf der Grundlage des Hofstede-Rahmens mit dem Ziel, wichtige kulturelle Werte zu identifizieren. Als zweites Ziel der Forschung erleichtert eine Reihe von Kriterien, die so genannte Usability-Heuristik von Nielsen, die Erkennung von Usability Problemen bei der Gestaltung von Benutzeroberflächen (UI). Die Usability-Heuristiken umfassen zehn Variablen, die die Interaktion zwischen dem Benutzer und einem Produkt oder System beeinflussen. Wenn wir uns näher mit
diesen Themen befassen, werden wir in der Lage sein, eine Matrix mit Beziehungen zwischen der heuristischen Bewertung von Nielsen und dem kulturellen Rahmen von Geert Hofstede aufzudecken. Abschließend erörtern wir das mögliche Potenzial kultureller Werte zur Beeinflussung von Benutzeroberflächen für E-Learning-Plattformen. In der Tat gibt es einige Funktionen in E-Learning-Plattformen, die aufgrund der Kultur weniger diskutiert werden, obwohl sie sehr praktisch in die Plattformen integriert werden können.
The use of agricultural plastic covers has become common practice for its agronomic benefits such as improving yields and crop quality, managing harvest times better, and increasing pesticide and water use efficiency. However, plastic covers are suspected of partially breaking down into smaller debris and thereby contributing to soil pollution with microplastics. A better understanding of the sources and fate of plastic debris in terrestrial systems has so far been hindered by the lack of adequate analytical techniques for the mass-based and polymer-selective quantification of plastic debris in soil. The aim of this dissertation was thus to assess, develop, and validate thermoanalytical methods for the mass-based quantification of relevant polymers in and around agricultural fields previously covered with fleeces, perforated foils, and plastic mulches. Thermogravimetry/mass spectrometry (TGA/MS) enabled direct plastic analyses of 50 mg of soil without any sample preparation. With polyethylene terephthalate (PET) as a preliminary model, the method limit of detection (LOD) was 0.7 g kg−1. But the missing chromatographic separation complicated the quantification of polymer mixtures. Therefore, a pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) method was developed that additionally exploited the selective solubility of polymers in specific solvents prior to analysis. By dissolving polyethylene (PE), polypropylene (PP), and polystyrene (PS) in a mixture of 1,2,4-trichlorobenzene and p-xylene after density separation, up to 50 g soil became amenable to routine plastic analysis. Method LODs were 0.7–3.3 mg kg−1, and the recovery of 20 mg kg−1 PE, PP, and PS from a reference loamy sand was 86–105%. In the reference silty clay, however, poor PS recoveries, potentially induced by the additional separation step, suggested a qualitative evaluation of PS. Yet, the new solvent-based Py-GC/MS method enabled a first exploratory screening of plastic-covered soil. It revealed PE, PP, and PS contents above LOD in six of eight fields (6% of all samples). In three fields, PE levels of 3–35 mg kg−1 were associated with the use of 40 μm thin perforated foils. By contrast, 50 μm PE films were not shown to induce plastic levels above LOD. PP and PS contents of 5–19 mg kg−1 were restricted to single observations in four fields and potentially originated from littering. The results suggest that the short-term use of thicker and more durable plastic covers should be preferred to limit plastic emissions and accumulation in soil. By providing mass-based information on the distribution of the three most common plastics in agricultural soil, this work may facilitate comparisons with modeling and effect data and thus contribute to a better risk assessment and regulation of plastics. However, the fate of plastic debris in the terrestrial environment remains incompletely understood and needs to be scrutinized in future, more systematic research. This should include the study of aging processes, the interaction of plastics with other organic and inorganic compounds, and the environmental impact of biodegradable plastics and nanoplastics.
Agriculture requires a sustainable intensification to feed the growing world population without exacer-bating soil degradation and threatening soil quality. Globally, plastic mulching (PM) is increasingly used to improve crop growth and yields and consequently agronomic productivity. However, recent literature reported also critical aspects of PM for soil quality and showed contradictory outcomes. This might result from the numerous applications of PM in different climates across various crops, soils and agri-cultural techniques. Thus, a closer look is necessary on how PM influences soil processes under certain climate and cultivation conditions to obtain a comprehensive understanding of its effects, which is im-portant to evaluate PM in terms of a sustainable agriculture.
The aim of this PhD thesis was to understand how multiannual PM influences soil properties and pro-cesses under the temperate, humid Central European cultivation conditions and to evaluate the resulting consequences for soil quality. I designed a three-year field study to investigate the influence of PM (black polyethylene, 50 μm) on microclimate, structural stability, soil organic matter (SOM) and the concentrations of selected fungicides and mycotoxins in three soil layers (0–10, 10–30 and 30–60 cm) compared to straw mulching (SM). Both mulching types were applied in a drip-irrigated ridge-furrow system in strawberry cultivation.
PM shifted the soil microclimate to higher soil temperatures and lower soil moistures. The higher soil temperature seems thus to be the key factor for the increased crop growth and yields under the present humid climate. The reduced soil moisture under PM indicated that under PM the impeded rainfall infil-tration had a stronger effect on the water balance than the reduced evaporation. This indicate an ineffi-cient rainwater use in contrast to arid climates. PM changed the water cycling in the ridges from down-ward directed water flows to lateral water flows from furrows to ridges. This reduced nitrogen leaching in the topsoil (0–10 cm) in the strawberry establishment period. The plastic mulches avoided aggregate breakdown due to rapid soil wetting and excess water during rainfalls and thus maintained a loose and stable soil structure in the surface soil, which prevents soil compaction and made soil less prone to erosion. PM changed carbon fluxes and transformation so that a larger total and more stable SOM was observed. Thus, the higher belowground biomass productivity under PM compensated the impeded aboveground biomass input and the temperature-induced SOM decomposition. However, SM increased the labile and total SOM in the topsoil after the first experiment year and promoted microbial growth due to the aboveground biomass incorporation. PM reduced fungicide entry into soil compared to SM and reduced consequently the fungal biomass reduction and the biosynthesis of the mycotoxin deoxyni-valenol. The modified microclimate under PM did not increase mycotoxin occurrence. In this context, PM poses no risk for an increased soil contamination, impairing soil quality. This PhD thesis demon-strated that the PM effects on soil can vary depending on time, season and soil depth, which emphasizes the importance to include soil depth and time in future studies.
Compared to semiarid and arid regions, the PM effects found in this PhD thesis were small, absent or in another way. I attributed this to the fact that PM under humid climate reduced instead of increased soil moisture and that SM had due to straw und strawberry canopy a similar ‘covering effect’ as PM. Thus, generalizing the PM effects on soil across different climates seems hardly possible as they differ in type and extent depending on climate. A differentiated consideration is hence necessary to evaluate the PM effects on soil quality. I conclude that PM under temperate, humid climate might contribute to reduce soil degradation (e.g., SOM depletion, erosion, nutrient leaching, soil compaction and soil contamina-tion), which sustains soil quality and helps to enable a sustainable agricultural intensification. However, further research is necessary (1) to support my findings on a larger scale, longer time periods and across various soil and crop types, (2) to address remaining open questions and (3) to develop optimization to overcome the critical aspects of PM (e.g. macro- and microplastic waste in soil, mulch disposal).
Resumen del libro impreso : Walden, R. (2008). Psicología arquitectónica: Escuela, escuela superior y edificios de oficinas del futuro. Lengerich: Pabst Science Publishers. Las personas desean, por lo general, un “contr ol“ sobre las condiciones de su entorno (comp. Flammer, 1990; Burger, 1992). Esta necesidad queda de manifiesto en forma de autoorganizaciones de la arquitectura y la autorregulación de los factores de estrés. Por esta razón, el concepto de control del medio ambiente se aplica como criterio central para los entornos construidos en los tres estudios de caso: de la escuela, de la universidad y de la s oficinas. Los métodos de encuesta "Programming" (desarrollo del programa orientado al usuario), "U ser-Needs Analysis" (análisis de necesidades del usuario) y "Post-Occupancy Evaluation" (análisis post-ocupacional) se explican con vistas a su importancia para la "Building Performance Evaluation" (evaluación del rendimiento del edificio) (Preiser & Araña, 1997; 2005). La “evaluación arquitectónica de Koblenz“ se presenta como instrumento para evaluar los entornos construidos en tres variantes. Los resultados elegidos de dichos tres estudios se relacionan, a su vez, con dos entornos diferentes. Los efectos de la arquitectura sobre el rendimiento de los usuarios (comp. Estudios BOSTI, 1984 y 2001) se establecen en la parte empírica en tres estudios de edificios innovadores (Escuela Waldorf en Köln, Universidad de Koblenz, Post Tower en Bonn). La eficacia se mide a través de: 1) el rendimiento de aprendizaje y laboral, 2) el bienestar y 3) el control del medio ambiente, así como 4) el comportamiento social en el caso del estudio escola r y con la ayuda de 16 (edificios de oficina) y 21 (universidades) criterios psicológicos para el éxito de las organizaciones. La meta de los tres estudios es, entre otras cosas, revisar el concepto teórico de "control del medio ambiente" y poder dar nuevas recomendaciones para mejorar en las reformas y ta mbién en las nuevas construcciones. Por eso, dos planteamientos centrales son: en el análisis de necesidades del usuario, la opinión del edificio "en la actualidad", ¿se diferencia de la evaluación de la “importancia en el futuro”?; las características de la arquitectura ¿tienen repercusión en los criterios de rendimiento?. Con los estudios se desarrollaron tres teoremas según el enfoque de facetas (Borg, 1996) y dos esquemas para la evaluación de calidad de los edificios escolares y de oficinas. De los esquemas se obtuvieron: para la escuela, 139 preguntas para 26 profesores y 86 preguntas para 122 alumnos; para la escuela superior, 203 preguntas para 147 estudian tes y 28 docentes, así como para el edificio de oficinas 254 preguntas para 56 censores estudiantiles. Las características particulares de los edificios se calificaron mediante una escala de +2 ☺☺ ("en la actualidad" muy buenas y “en el futuro” muy importantes respectivamente) a –2 // ("en la actualidad" muy malas y “en el futuro“ muy insignificantes respectivamente). Los tres criterios principales de rendimiento, especialmente para la evaluación de la “importancia en el futuro“, están correlacionados uno con el otro en los tres estudios, por lo general, de manera sustancial y muy significativa, de manera que se puede esperar que una evaluación superior del control del medio ambiente llevada a cabo por los usuarios conduzca a más bienestar y que, sobre ambas variables, también puedan ser aumentadas las evaluaciones de rendimientos de aprendizaje y laboral “en el futuro“. Según los resultados de los tres estudios, los usuarios y los censores desean por ejemplo, en los tres entornos, la posibilidad de retiro: en la escuela, en forma de oficinas de alumnos, nichos y tresillos en el aula; en la universidad, en forma de bancos protegidos en el área exterior y mesas de trabajo, por ejemplo, en la cafetería; y en el edificio de ofic inas a través de menos transparencia en las oficinas compartidas y con eso menos visión de todas las actividades entre jefes y compañeros. Las relaciones de los criterios de rendimiento centrales establecidas en los tres estudios dejan suponer de modo justificado que, mediante mejoras concretas de aspectos importantes del entorno -sobre todo de aquellos que permiten el control del mismo-, se puede influir de manera positiva sobre el bienestar y, con esto, sobre el rendimiento de los usuarios. Palabras claves: necesidades del usuario, análisis; evaluación del rendimiento del edificio; control del medio ambiente (autoorganización, regulación de los factores de estrés, control social), bienestar, rendimientos de aprendizaje y laboral, comportamiento social; criterios del éxito de las Resumen 5 organizaciones; teoría de las facetas; esquema para la evaluación de la calidad de los edificios; recomendaciones para la construcción de edificios con visión de futuro.
Abstract for the print-book: Walden, R. (2008). Architectural Psychology: School, University Campus, and Office Building of the Future. Lengerich: Pabst Science Publishers (in German). The need for display of self in architecture and for users' self-regulation of stress factors, which demonstrate that users crave individual control of their environment (cf. Flammer, 1990; Burger, 1992) motivated this study to use the concept of environmental control as a central criterion for the evaluation of built environment. It was applied to three case studies: a school, a university campus, and an office building. Advantages and disadvantages of the data- gathering methods of architectural Programming, User-Needs Analysis, and Post-Occupancy Evaluation were analyzed to highlight their significance in terms of Building Performance Evaluation as described by Preiser and Sc hramm (1997, 2005). The “Koblenz Architecture Questionnaire” was used as an instrument for assessing the built environment of the three case studies, and the study reports selected findings from these questionnaires. The investigation seeks to determine the effect of architecture - especially buildings' provisions for user control of environmental conditions - on user performance (cf. BOSTI studies, 1984, 2001) in three innovative buildings: the Waldorf School in Cologne, the new campus for the University in Koblenz, and the Office Tower of the Deutsche Post World Net AG in Bonn. Performance is measured in terms of (1) Lear ning and Work Efficiency, (2) Well-being, (3) Environmental Control, (4) Social Behavior (the latter just for the school project), and by means of 21 and 16 additional psychological criteria for success of the organization in the cases of the university and the office building, respectively. The study aims, among other things, at reassessing the theoretical concept of 'environmental control' and at making recommendations for both improvement of existing buildings and the design of new projects. Two central questions are: In User-Needs Analysis, what is the difference between the assessment of a building for its current use and its estimated performance in future? Do certain architectural features influence user assessments on the given performance criteria? In the studies, three mapping sentences were developed according to the 'facet approach' (Borg, 1996) as well as two systems to judge the quality of school and office buildings. Using these systems, information was obtained in all three studies to construct questionnaires. In the school study, teachers were asked 139 questions, pupils 86 questions. Responses were obtained from 26 teachers and 122 pupils. For the university, 147 students and 28 faculty members responded to 203 questions. For the office building, 56 student-experts were asked 254 questions. Characteristics of the built environment were rated using the following scale: +2 ☺☺ (very good “at present”, and accordingly very important “in the future”) down to –2 // (very bad “at present”, and very unimportant “in the future”). A general finding was a high and significant co rrelation between the responses for the three main performance criteria in all three case studies, especially for the 'importance for the future' aspect. This supports the conclusion that a perception of higher degree of environmental control by users will lead to an increased sense of well-being and consequently, there will also be a higher expectation of improved work or learning efficiency 'in the future'. The three studies further show for example that users in all three environments desire 'retreat opportunities' which may take the form of student offices in schools, niches and small group seating in classrooms, and sheltered seating in outdoor areas and work tables in the cafeteria for the university. For the offices, users wanted more visual privacy (less transparent office partitions in Combi Offices) for less visual control of their activities by supervisors and co-workers. The relationships found by the studies between the responses on the central performance criteria and the spatial characteristics of the three buildings support the contention that focused improvements in the built environment, especially with respect to features that enhance user control of environmental conditions, will influence users’ well-being as well as work performance and work or learning efficiency in a positive way.
