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Factors triggering the ecotoxicity of metal-based nanoparticles towards aquatic invertebrates
(2015)
Nanoparticles are produced and used in huge amounts increasing their probability to end up in surface waters. There, they are subject to environmentally driven modification processes. Consequently, aquatic life may be exposed to different nanoparticle agglomerate sizes, while after sedimentation benthic organisms are more likely to be affected.
However, most ecotoxicity studies with nanoparticles exclusively investigated implications of their characteristics (e.g. size) on pelagic organisms, ignoring environmentally modified nanoparticles. Therefore, a systematic assessment of factors triggering the fate and toxicity of nanoparticles under environmentally relevant conditions is needed. The present thesis, therefore, investigates the implications of nanoparticle related factors (i.e., inherent material-properties and nanoparticle characteristics) as well as environmental conditions towards the pelagic living organism Daphnia magna and the benthic species Gammarus fossarum. In detail, inert titanium dioxide (nTiO2) and ion-releasing silver nanoparticles (nAg), both of varying particle characteristics (e.g. initial size), were tested for their toxicity under different environmental conditions (e.g. ultraviolet-light (UV-light)).
The results indicate that the toxicity of nTiO2 and nAg is mainly determined by: their adsorption potential onto biota, and their fate in terms of reactive oxygen species or Ag+ ion release. Thus, inherent material-properties, nanoparticle characteristics and environmental conditions promoting or inhibiting these aspects revealed significant implications in the toxicity of nTiO2 and nAg towards daphnids.
Furthermore, the presence of ambient UV-light, for example, adversely affected gammarids at 0.20 mg nTiO2/L, while under darkness no effects occurred even at 5.00 mg nTiO2/L. Hence, the currently associated risk of nanoparticles might be underestimated if disregarding their interaction with environmental parameters
Placing questions before the material or after the material constitute different reading situations. To adapt to these reading situations, readers may apply appropriate reading strategies. Reading strategy caused by location of question has been intensively explored in the context of text comprehension. (1) However, there is still not enough knowledge about whether text plays the same role as pictures when readers apply different reading strategies. To answer this research question, three reading strategies are experimentally manipulated by displaying question before or after the blended text and picture materials: (a) Unguided processing with text and pictures and without the question. (b) Information gathering to answer the questions after the prior experience with text and pictures. (c) Comprehending text and pictures to solve the questions with the prior information of the questions. (2) Besides, it is arguable whether readers prefer text or pictures when the instructed questions are in different difficulty levels. (3) Furthermore, it is still uncertain whether students from higher school tier (Gymnasium) emphasize more on text or on pictures than students from lower school tier (Realschule). (4) Finally, it is rarely mentioned whether higher graders are more able to apply reading strategies in text processing and picture processing than lower graders.
Two experiments were undertaken to investigate the usage of text and pictures in the perspectives of task orientation, question difficulty, school and grade. For a 2x2(x2x2x2) mixed design adopting eye tracking method, participants were recruited from grade 5 (N = 72) and grade 8 (N = 72). In Experiment 1, thirty-six 5th graders were recruited from higher tier (Gymnasium) and thirty-six 5th graders were from lower tier (Realschule). In Experiment 2, thirty-six 8th graders were recruited from higher tier and thirty-six were from lower tier. They were supposed to comprehend the materials combining text and pictures and to answer the questions. A Tobii XL60 eye tracker recorded their eye movements and their answers to the questions. Eye tracking indicators were analyzed and reported, such as accumulated fixation duration, time to the first fixation and transitions between different Areas of Interest. The results reveal that students process text differently from pictures when they follow different reading strategies. (1) Consistent with Hypothesis 1, students mainly use text to construct their mental model in unguided spontaneous processing of text and pictures. They seem to mainly rely on the pictures as external representations when trying to answer questions after the prior experience with the material. They emphasize on both text and pictures when questions are presented before the material. (2) Inconsistent with Hypothesis 2, students are inclined to emphasize on text and on pictures as question difficulty increases. However, the increase of focus on pictures is more than on text when the presented question is difficult. (3) Different from Hypothesis 3, the current study discovers that higher tier students did not differ from lower tier students in text processing. Conversely, students from higher tier attend more to pictures than students from lower tier. (4) Differed from Hypothesis 4, 8th graders outperform 5th graders mainly in text processing. Only a subtle difference is found between 5th graders and 8th graders in picture processing.
To sum up, text processing differs from picture processing when applying different reading strategies. In line with the Integrative Model of Text and Picture Comprehension by Schnotz (2014), text is likely to play a major part in guiding the processing of meaning or general reading, whereas pictures are applied as external representations for information retrieval or selective reading. When question is difficulty, pictures are emphasized due to their advantages in visualizing the internal structure of information. Compared to lower tier students (poorer problem solvers), higher tier students (good problem solvers) are more capable of comprehending pictures rather than text. Eighth graders are more efficient than 5th graders in text processing rather than picture processing. It also suggests that in designing school curricula, more attention should be paid to students’ competence on picture comprehension or text-picture integration in the future.
The increasing application of titanium dioxide nanoparticles (nTiO2) entails an increased risk regarding their release to surface water bodies, where they likely co-occur with other anthropogenic stressors, such as heavy metals. Their co-occurrence may lead to an adsorption of the metal ions onto the particles. These nanoparticles often sediment, due to their agglomeration, and thus pose a risk for pelagic or benthic species. The combined toxicity of nTiO2 and heavy metals is likely influenced by the properties of both stressors (since they may alter their interaction) and by environmental parameters (e.g., organic matter, pH, ionic strength) affecting their fate.
These issues were not yet systematically examined by the recent literature. Therefore, this thesis investigated the influence of nTiO2-products with differing crystalline phase composition on the toxicity of copper (as representative for heavy metals) in presence of different organic matters using the pelagic test organism Daphnia magna.
Moreover, the duration of the stressors` interaction (=aging) likely modulates the combined toxicity. Hence, the influence of nTiO2 on copper toxicity after aging as a function of environmental parameters (i.e., organic matter, pH, ionic strength) was additionally investigated.
Finally, the transferability of the major findings to benthic species was examined using Gammarus fossarum. The present thesis discovered a reduction of the copper toxicity facilitated by nTiO2 for all assessed scenarios, while its magnitude was determined by the surface area and structure of nTiO2, the quantity and quality of organic matter as well as the aging of both stressors. The general copper toxicity reduction by nTiO2 was also transferable to benthic species, despite their potentially increased exposure due to the sedimentation of nTiO2 with adsorbed copper. These observations suggest the application of nTiO2 as remediation agent, but potential side effects (e.g., chronic toxicity, reactive oxygen species formation) require further investigations. Moreover, questions regarding the transferability to other stressors (e.g., different heavy metals, organic chemicals) and the fate of stressors adsorbed to nTiO2 in aquatic ecosystems remain open.
Die vorliegende Forschungsarbeit beschäftigt sich mit der Positionierung und anbieterinternen Kommunikation der innovativen IT-Architektur SOA. Die zentralen Ziele der vorliegenden explorativen und empirischen Forschungsarbeit, die im Kontext der Innovations-Erfolgsfaktorenforschung angesiedelt ist, bestehen in der Beantwor-tung der beiden folgenden forschungsleitenden Fragestellungen:
Forschungsfrage 1: Welche Bedingungen tragen zu einer erfolgreichen Positionierung von SOA bei? Forschungsfrage 2: Welche Bedingungen tragen zu einer erfolgreichen anbieterinternen Kommunikation bezüglich SOA bei? Zur Überprüfung dieser beiden Forschungsfragen wurde ein zweistufiges Delphi-Verfahren durchgeführt. Hierbei wurde zunächst eine qualitative Befragungswelle (N=53) zur Identifizierung der SOA-Positionierungsbedingungen und anbieterinternen SOA-Kommunikations-bedingungen durchgeführt. Insgesamt wurden in der ersten Befragungswelle 122 SOA-Positionierungsbedingungen identifiziert, die sich in 65 Bedingungen auf Anbieterseite, 35 Bedingungen auf Kundenseite, 19 Bedingungen auf SOA-Seite und 3 Bedingungen aufseiten des weiteren Umfeldes aufteilen. Im Rahmen der anbieterinternen SOA-Kommunikation konnten 31 Bedingungen identifiziert werden. Die in der ersten Welle identifizierten SOA-Positionie-rungsbedingungen und anbieterinternen SOA-Kommunikationsbedingungen wurden mittels der zweiten Befragungswelle (N=83) einer quantitativen Analyse unterzogen. Somit liefert die vorliegende Studie Bedingungen, die sowohl zu einer erfolgreichen SOA-Positionierung als auch zu einer erfolgreichen anbieterinternen SOA-Kommunikation beitragen.
Die Resultate dieser Arbeit werden zusammengefasst und theoretisch eingeordnet. Ebenfalls wird die methodische Vorgehensweise kritisch diskutiert und die Güte der Daten beurteilt. Schließlich wird ein Ausblick auf zukünftige Forschungsfelder gegeben.
Protest & Gerechtigkeit - Thema in Forschung und Lehre am Campus Landau
Erwachsenenbildung: Die Herausforderung einer modernen Weiterbildung
Hospizarbeit: Neuer Qualitätsindex startklar für die Praxis
Unzufrieden im Job? Wie positive Psychologie helfen kann
Psychotherapie: Neue Kinder- und Jugendambulanz
NeuLand 2011,02 = Nr. 31
(2015)
Campusschule: Uni goes Schulpraxis
Praxisluft schnuppern - Wie in der Lehre praktisches Know-how vermittelt wird
Money, money, money - Fördermöglichkeiten für Studierende und Promovierende
Hinter den Kulissen - Ein Tag mit Chefhausmeister Hans-Jürgen Lösch
Wolfgang Huber - Interview mit dem Frank-Loeb-Gastprofessor 2011
Virtueller Konsum - Warenkörbe, Wägungsschemata und Verbraucherpreisindizes in virtuellen Welten
(2015)
Virtual worlds have been investigated by several academic disciplines for several years, e.g. sociology, psychology, law and education. Since the developers of virtual worlds have implemented aspects like scarcity and needs, even economic research has become interested in these virtual environments. Exploring virtual economies mainly deals with the research of trade regarding the virtual goods used to supply the emerged needs. On the one hand, economics analyzes the meaning of virtual trade according to the overall interpretation of the economical characteristics of virtual worlds. As some virtual worlds allow the change of virtual world money with real money and vice versa, virtual goods are traded by the users for real money, researchers on the other hand, study the impact of the interdependencies between virtual economies and the real world. The presented thesis mainly focuses on the trade within virtual worlds in the context of virtual consumption and the observation of consumer prices. Therefore, the four virtual worlds World of Warcraft, RuneScape, Entropia Universe and Second Life have been selected. There are several components required to calculate consumer price indices. First, a market basket, which contains the relevant consumed goods existing in virtual worlds, must be developed. Second, a weighting scheme has to be established, which shows the dispersion of consumer tendencies. Third, prices of relevant consumer goods have to be taken. Following real world methods, it is the challenge to apply those methods within virtual worlds. Therefore, this dissertation contains three corresponding investigation parts. Within a first analysis, it will be evaluated, in how far virtual worlds can be explored to identify consumable goods. As a next step, the consumption expenditures of the avatars will be examined based on an online survey. At last, prices of consumable goods will be recorded. Finally, it will be possible to calculate consumer price indices. While investigating those components, the thesis focuses not only on the general findings themselves, but also on methodological issues arising, like limited access to relevant data, missing legal legitimation or security concerns of the users. Beside these aspects, the used methods also allow the examination of several other economic aspects like the consumption habits of the avatars. At the end of the thesis, it will be considered to what extent virtual world economic characteristics can be compared with the real world.
Aspects like the important role of weapons or the different usage of food show significant differences to the real world, caused by the business models of virtual worlds.
Demographic change forces companies in the social sector, which already face more difficulties recruiting from the primary labor market and keep qualified workers committed then other enterprises, to deal with the increase of employees satisfaction. This research paper analyses the context of dialogic management in the relation between the manager and her staff and satisfaction of employees. It measures the personal preferences of leaders and staff from the employee perception.
The following personal preferences are distinguished: Harmony-seeking relation preference versus dominant autonomy preferencern Thrill-seeking stimulant preference versus controlling balance preference according to Riemann, 1999 und Pashen Dihsmaier 2011. The empiric research was done with help of a survey at the Samaritan institution Fürstenwalde with a 364 out of 560 employees´ participation. It finds significant correlation between the satisfaction of the employees with their managers and their dialogic expertise as well as with their skill to create confidence and spread appreciation. It determines differences in job satisfication of employees between the perceived psychological preferences of the staff and the perceived preference of their managers. It can be proved that relationship-oriented leaders show a higher degree of willingness for dialogue then autonomy-oriented managers. The satisfaction of employees with these leaders is clearly higher then with managers who are perceived as autonomy- oriented. A higher degree of correlation between the contentment and dialogic behavior of management could be determined with stimulant- and relationship-oriented employee against employees with a preference for autonomy or balance. The highest value of contentment could be reached by relationship- oriented workers, who perceive their management also relationship-oriented. The foundation of dialogic thought and behavior based on trust and appreciation must be developed upon managers and employees, first, before dialogic management can be introduced to a company.
In this context the relationship-oriented management approaches should be taken into consideration when recruiting managers and should also have a high priority in the human resources development.
Die UN-Behindertenrechtskonvention von 2008 formuliert einen Rechtsanspruch auf inklusive Bildung für Menschen mit Beeinträchtigungen. Diesem wird in Deutschland seit 2009 durch Schulgesetzänderungen Rechnung getragen, mit denen inklusive Bildung durch ein Elternwahlrecht implementiert wird. Bislang ist vor dem Hintergrund der neu geschaffenen elterlichen Entscheidungsmöglichkeiten noch nicht untersucht worden, welche Vorstellungen Eltern von Kindern mit komplexen Beeinträchtigungen mit dem inklusiven Bildungsanspruch ihres Kindes verbinden und in welcher Weise sie diesen an der Schulform ihrer Wahl eingelöst sehen. Im Zentrum der vorliegenden Arbeit steht die Rekonstruktion des Bildungsangebots aus der Perspektive der Eltern im Abgleich mit der Sicht der pädagogischen Klassenteams. Den Fragen nach den elterlichen Erwartungen und Erfahrungen wurde aus der systemtheoretischen Perspektive von Luhmann nachgegangen. In der qualitativ angelegten Untersuchung geht es um Schülerinnen und Schüler mit komplexen Beeinträchtigungen, die nach der Schulgesetznovellierung in Hamburg (2009) in den Jahren 2010 und 2011 eingeschult worden sind und aufgrund der Entscheidung ihrer Eltern in unterschiedlichen Settings an Grund- und Sonderschulen lernen. Die Datenerhebung erfolgte durch leitfadengestützte Interviews mit Eltern, Pädagoginnen und Pädagogen sowie Schulleitungen, ergänzt durch Hospitationen im Schuljahr 2011/12 und Dokumente, die von den Schulen zur Verfügung gestellt wurden. Die Datenanalyse erfolgt mithilfe der Grounded Theory nach Strauß/Corbin (1996). Die Ergebnisse der Untersuchung zeigen elterliche Bildungserwartungen im Hinblick auf ein Ermöglichen von Autonomie und Teilhabe ihrer Kinder und eine differenzierte Wahrnehmung der Umsetzung ihrer Erwartungen im Schulalltag. Einen besonderen Stellenwert messen Eltern der Zusammenarbeit zwischen Schule und Familie bei, die für das Entstehen von Vertrauen bzw. Misstrauen bedeutsam ist. Aus den Erkenntnissen und deren Rückbindung an die Systemtheorie wurde ein Modell des Professionsvertrauens/-misstrauens entwickelt.
Die Auswertung ergibt Hinweise zu Qualitätskriterien eines inklusiven Bildungsangebots und zu Entwicklungsanforderungen in der Professionalisierung, die sowohl auf die Ebene der Organisation Schule als auch der Interaktion zwischen schulischen Akteurinnen und Akteuren sowie Eltern abzielen.
Uniprisma Ausg. 2010
(2015)
Uniprisma Ausg. 2009
(2015)