In international business relationships, such as international railway operations, large amounts of data can be exchanged among the parties involved. For the exchange of such data, a limited risk of being cheated by another party, e.g., by being provided with fake data, as well as reasonable cost and a foreseeable benefit, is expected. As the exchanged data can be used to make critical business decisions, there is a high incentive for one party to manipulate the data in its favor. To prevent this type of manipulation, mechanisms exist to ensure the integrity and authenticity of the data. In combination with a fair exchange protocol, it can be ensured that the integrity and authenticity of this data is maintained even when it is exchanged with another party. At the same time, such a protocol ensures that the exchange of data only takes place in conjunction with the agreed compensation, such as a payment, and that the payment is only made if the integrity and authenticity of the data is ensured as previously agreed. However, in order to be able to guarantee fairness, a fair exchange protocol must involve a trusted third party. To avoid fraud by a single centralized party acting as a trusted third party, current research proposes decentralizing the trusted third party, e.g., by using a distributed ledger based fair exchange protocol. However, for assessing the fairness of such an exchange, state-of-the-art approaches neglect costs arising for the parties conducting the fair exchange. This can result in a violation of the outlined expectation of reasonable cost, especially when distributed ledgers are involved, which are typically associated with non-negligible costs. Furthermore, the performance of typical distributed ledger-based fair exchange protocols is limited, posing an obstacle to widespread adoption. To overcome the challenges, in this thesis, we introduce the foundation for a data exchange platform allowing for a fully decentralized fair data exchange with reasonable cost and performance. As a theoretical foundation, we introduce the concept of cost fairness, which considers cost for the fairness assessment by requesting that a party following the fair exchange protocol never suffers any unilateral disadvantages. We prove that cost fairness cannot be achieved using typical public distributed ledgers but requires customized distributed ledger instances, which usually lack complete decentralization. However, we show that the highest unilateral cost are caused by a grieving attack. To allow fair data exchanges to be conducted with reasonable cost and performance, we introduce FairSCE, a distributed ledger-based fair exchange protocol using distributed ledger state channels and incorporating a mechanism to protect against grieving attacks, reducing the possible unilateral cost that have to be covered to a minimum. Based on our evaluation of FairSCE, the worst-case cost for data exchange, even in the presence of malicious parties, is known, which allows an estimate of the possible benefit and, thus, the preliminary estimate of economic utility. Furthermore, to allow for an unambiguous assessment of the correct data being transferred while still allowing for sensitive parts of the data to be masked, we introduce an approach for the hashing of hierarchically structured data, which can be used to ensure integrity and authenticity of the data being transferred.

This work investigates the occurrence of post-event processing (PEP) in the context of test anxiety; PEP involves rumination and self-critical thinking following an event and commonly observed in social anxiety. Three short-term longitudinal studies in student samples examined whether PEP occurs after exams and how it is associated with test anxiety. University students (N =35 in Study 1, N =146 in Study 2, and N =37 in Study 3) completed measures of trait and state test anxiety before an actual exam; PEP related to the exam was assessed at various time points afterward. Results revealed that PEP occurred to a meaningful extent after exam situations. Overall, it was positively associated with trait and state test anxiety, although some variations in the relations were found across the three studies. These findings underscore the relevance of PEP in the context of test anxiety, as PEP might contribute to maintaining test anxiety in the long term. Implications for future studies are discussed.

The biodegradable polymers polylactic acid (PLA) and polyhydroxybutyrate (PHB) produced from renewable raw materials were coated with hydrogenated amorphous carbon layers (a-C:H) at different deposition angles with various thicknesses as part of this thesis. Similar to conventional polymers, biopolymers often have unsuitable surface properties for industrial purposes, e.g. low hardness. For some applications, it is therefore necessary and advantageous to modify the surface properties of biopolymers while retaining the main properties of the substrate material. A suitable surface modification is the deposition of thin a-C:H layers. Their properties depend essentially on the sp² and sp³ hybridization ratio of the carbon atoms and the content of hydrogen atoms. The sp²/sp³ ratio was to be controlled in the present work by varying the coating geometry. Since coatings at 0°, directly in front of the plasma source, contain a higher percentage of sp³ and indirectly coated (180°) a higher amount of sp², it is shown in this work that it is possible to control the sp²/sp³ ratio. For this purpose, the samples are placed in front of the plasma source at angles of 0, 30, 60, 90, 120, 150 and 180° and coated for 2.5, 5.0, 7.5 and 10.0 minutes. For the angles 0°, the layer thicknesses were 25, 50, 75 and 100 nm. The a-C:H layers were all deposited using radio-frequency plasma-enhanced chemical vapor deposition and acetylene as C and H sources after being pretreated with an oxygen plasma for 10 minutes. Following the O₂ treatment and the a-C:H deposition, the surfaces are examined using macroscopic and microscopic measurement methods and the data is then analyzed. The surface morphology is recorded using scanning electron microscopy and atomic force microscopy. In addition, data on the stability of the layer and the surface roughness can be collected. Contact angle (CA) measurements are used to determine not only the wettability, but also the contact angle hysteresis by pumping the drop volume up and down. By measuring the CA with different liquids and comparing them, the surface free energy (SFE) and its polar and disperse components are determined. The changes in barrier properties are verified by water vapor transmission rate tests (WVTR). The chemical analysis of the surface is carried out on the one hand by Fourier transform infrared spectroscopy with specular reflection and on the other hand by synchrotron-supported techniques such as near-edge X-ray absorption fine structure and X-ray photoelectron spectroscopy. When analyzing the surfaces after the O₂ treatment, which was initially assumed to serve only to clean and activate the surface for the a-C:H coating, it was found that the changes were more drastic than originally assumed. For example, if PLA is treated at 0° for 10 minutes, the roughness increases fivefold. As the angle increases, it decreases again until it returns to the initial value at 180°. This can be recognized to a lesser extent with PHB at 30°. For both polymers, it can be shown that the polar fraction of the SFE increases. In the WVTR, a decrease in permeability can be observed for PLA and an increase in the initial value for PHB. The chemical surface analysis shows that the O₂ treatment has little effect on the surface bonds. Overall, it can be shown in this work that the O₂ treatment has an effect on the properties of the surface and cannot be regarded exclusively as a cleaning and activation process. With direct a-C:H coating (at 0°), a layer failure due to internal stress can be observed for both PLA and PHB. This also occurs with PHB at 30°, but to a lesser extent. Permeability of the polymers is reduced by 47% with a five-minute coating and the layer at 10.0 minutes continues to have this effect despite cracks appearing. The application of a-C:H layers shows a dominance of sp³ bonds for both polymer types with direct coating. This decreases with increasing angle and sp² bonds become dominant for indirect coatings. This result is similar for all coating thicknesses, only the angle at which the change of the dominant bond takes place is different. It is shown that it is possible to control the surface properties by an angle-dependent coating and thus to control the ratio sp²/sp³.

The title compound, [Fe(C5H5)(C21H24NO2)], which is produced by the oxidation of 1-(4-tert-butylphenyl)-2-ethyl-3-ferrocenylpyrrole, crystallizes as a racemic mixture in the centrosymmetric space group P21/n. The central heterocyclic pyrrole ring system subtends dihedral angles of 13.7 (2)° with respect to the attached cyclopentadienyl ring and of 43.6 (7)° with the major component of the disordered phenyl group bound to the N atom. The 4-tert-butylphenyl group, as well as the non-substituted Cp ring are disordered with s.o.f. values of 0.589 (16) and 0.411 (16), respectively. In the crystal, molecules with the same absolute configuration are linked into infinite chains along the b-axis direction by O—H···O hydrogen bonds between the hydroxy substituent and the carbonyl O atom of the adjacent molecule.

How to begin? This short question addresses a problem that is anything but simple, especially when regarding something as sophisticated and multilayered as musical theatre. However, scholars of this vast research area have mostly neglected this question so far. This study analyses and compares the initial sections of late Victorian popular musical theatre and is therefore a contribution to several fields of research: the analysis of initial sections of musical theatre in general, the analysis of the music of popular musical theatre in particular, and therefore operetta studies. The 1890s are especially interesting times for popular musical theatre in London: The premiered works include the last collaborations of Gilbert and Sullivan as well as offshoots of Savoy opera; but the so-called ‘naughty nineties’ also saw the emergence of a new genre, musical comedy, which captured the late Victorian zeitgeist like no other. This new form of theatrical entertainment was carefully and consciously constructed and promoted as modern and fashionable, walking a fine line between respectability and mildly risqué excitement. Because a deep understanding of the developments and new tendencies concerning popular musical theatre in the 1890s is crucial in order to interpret differences as well as similarities, the analyses of the opening numbers are preceded by a detailed discussion of the relevant genres: comic opera, musical comedy, musical play and operetta. Since the producers of the analysed works wanted to distance themselves from former and supposedly old-fashioned traditions, this book also considers influences from their British predecessors, but also from Viennese operetta and French opéra bouffe.

The production of isolated metallic nanoparticles with multifunctionalized properties, such as size and shape, is crucial for biomedical, photocatalytic, and energy storage or remediation applications. This study investigates the initial particle formations of gold nanoparticles (AuNPs) bioproduced in the cyanobacteria Anabaena sp. using high-resolution transmission electron microscopy images for digital image analysis. The developed method enabled the discovery of cerium nanoparticles (CeNPs), which were biosynthesized in the cyanobacteria Calothrix desertica. The particle size distributions for AuNPs and CeNPs were analyzed. After 10 h, the average equivalent circular diameter for AuNPs was 4.8 nm, while for CeNPs, it was approximately 5.2 nm after 25 h. The initial shape of AuNPs was sub-round to round, while the shape of CeNPs was more roundish due to their amorphous structure and formation restricted to heterocysts. The local PSDs indicate that the maturation of AuNPs begins in the middle of vegetative cells and near the cell membrane, compared to the other regions of the cell.

This thesis explores and examines the effectiveness and efficacy of traditional machine learning (ML), advanced neural networks (NN) and state-of-the-art deep learning (DL) models for identifying mental distress indicators from the social media discourses based on Reddit and Twitter as they are immensely used by teenagers. Different NLP vectorization techniques like TF-IDF, Word2Vec, GloVe, and BERT embeddings are employed with ML models such as Decision Tree (DT), Random Forest (RF), Logistic Regression (LR) and Support Vector Machine (SVM) followed by NN models such as Convolutional Neural Network (CNN), Recurrent Neural Network (RNN) and Long Short-Term Memory (LSTM) to methodically analyse their impact as feature representation of models. DL models such as BERT, DistilBERT, MentalRoBERTa and MentalBERT are end-to-end fine tuned for classification task. This thesis also compares different text preprocessing techniques such as tokenization, stopword removal and lemmatization to assess their impact on model performance. Systematic experiments with different configuration of vectorization and preprocessing techniques in accordance with different model types and categories have been implemented to find the most effective configurations and to gauge the strengths, limitations, and capability to detect and interpret the mental distress indicators from the text. The results analysis reveals that MentalBERT DL model significantly outperformed all other model types and categories due to its specific pretraining on mental data as well as rigorous end-to-end fine tuning gave it an edge for detecting nuanced linguistic mental distress indicators from the complex contextual textual corpus. This insights from the results acknowledges the ML and NLP technologies high potential for developing complex AI systems for its intervention in the domain of mental health analysis. This thesis lays the foundation and directs the future work demonstrating the need for collaborative approach of different domain experts as well as to explore next generational large language models to develop robust and clinically approved mental health AI systems.

Zweite Ordnung zur Änderung der Promotionsordnung des Fachbereichs 1: Bildungswissenschaften der Universität Koblenz Satzung der Studierendenschaft der Universität Koblenz

This work addresses the challenge of calibrating multiple solid-state LIDAR systems. The study focuses on three different solid-state LIDAR sensors that implement different hardware designs, leading to distinct scanning patterns for each system. Consequently, detecting corresponding points between the point clouds generated by these LIDAR systems—as required for calibration—is a complex task. To overcome this challenge, this paper proposes a method that involves several steps. First, the measurement data are preprocessed to enhance its quality. Next, features are extracted from the acquired point clouds using the Fast Point Feature Histogram method, which categorizes important characteristics of the data. Finally, the extrinsic parameters are computed using the Fast Global Registration technique. The best set of parameters for the pipeline and the calibration success are evaluated using the normalized root mean square error. In a static real-world indoor scenario, a minimum root mean square error of 7 cm was achieved. Importantly, the paper demonstrates that the presented approach is suitable for online use, indicating its potential for real-time applications. By effectively calibrating the solid-state LIDAR systems and establishing point correspondences, this research contributes to the advancement of multi-LIDAR fusion and facilitates accurate perception and mapping in various fields such as autonomous driving, robotics, and environmental monitoring.

Classical music has played a central role in German music education since at least the second half of the 20th century. However, in more recent music pedagogical discourse, classical music remains a controversial topic. But what do music teachers think about classical music as a subject for music education? This topic has not yet been systematically researched in German-speaking music education. In this qualitative-empirical study, eight semi-structured interviews were conducted to address the question of how music teachers perceive classical music in music education. The data was evaluated using the Grounded Theory Methodology. The theory developed from the study indicates that music teachers have varying objectives when using classical music in music education. However, they generally consider it unfamiliar to their students. To address this situation, music teachers develop various methods and strategies. These can be categorized into three approaches for dealing with the unfamiliarity of classical music: avoidance, reduction/relativization, and utilization. The study's findings are contextualized within the framework of foreignness theory, music didactics, and transformational educational theory. This dissertation contributes to the field of music education in classical music, laying the groundwork for further theoretical, empirical, and didactic research.

Ordnung zur Änderung der Beitragsordnung des Studierendenwerks Koblenz Ordnung zur Regelung von Anwesenheitspflichten in Lehrveranstaltungen an der Universität Koblenz Leitlinie zur Informationssicherheit an der Universität Koblenz

Im Rahmen der Masterthesis „Analyse des Managements invasiver gebietsfremder Arten am Beispiel des Roten Amerikanischen Sumpfkrebses (Procambarus clarkii) während und im Anschluss an notwendige Sanierungsarbeiten am Hochwasserrückhaltebecken Breitenauer See östlich von Heilbronn“ wurde das Vorkommen des invasiven Roten Amerikanischen Sumpfkrebses am Breitenauer See umfangreich kartiert. Auch die nahegelegene Sulm mit bekanntem Vorkommen des Signalkrebses sowie das Nonnenbachsystem mit bekanntem Vorkommen des Steinkrebses wurden erfasst. Der Fokus lag auf der Beantwortung dreier Kernfragen. Zunächst wurde untersucht, ob und wie ein dauerhaftes IAS-Management (invasive alien species) des Roten Amerikanischen Sumpfkrebses am Breitenauer See nachhaltig durchgeführt werden kann, um inakzeptable ökologische Effekte zu vermeiden. Die zweite Fragestellung bezog sich auf die Wirksamkeit ergriffener Risikomanagementmaßnahmen während der Ablassaktion des Breitenauer Sees. Abschließend war fraglich, wie sich der Rote Amerikanische Sumpfkrebs verhält, wenn sein besiedeltes Gewässer trockenfällt.

Sind Menschen von einer Pflegebedürftigkeit in Deutschland betroffen, so regelt der durch § 14 SGB XI festgeschriebene Pflegebedürftigkeitsbegriff den Zugang zu Leistungen der Pflegeversicherung. Der Pflegebedürftigkeitsbegriff ist dabei ein normativ gesetzter und basiert bislang nicht auf empirischen Studien aus dem Bereich der Pflege und der Pflegewissenschaft. Durch seine gesetzliche Fundierung lenkt er die Bedingungen und Strukturen, unter welchen Pflegeleistungen in Deutschland von Pflegefachpersonen erbracht werden. Weiterhin ist davon auszugehen, dass die Pflegefachpersonen durch ihre professionelle Sozialisierung einen fachlichen Fokus auf das Konstrukt der Pflegebedürftigkeit legen, welcher sich vom Pflegebedürftigkeitsbegriff unterscheidet und strukturell nicht in die Leistungsbemessung einfließt. Daraus ergeben sich Aspekte einer pflegerischen Unter- und Überversorgung. Die vorliegende Ph.D.-Thesis verfolgt das Anliegen, die Herausforderungen des Pflegebedürftigkeitsbegriffs in Deutschland aufzuzeigen, indem die Aspekte der Pflegebedürftigkeit von Pflegefachpersonen im ambulanten Setting im Hinblick auf deren Interaktion mit pflegebedürftigen Menschen empirisch erfasst und zu einem theoretischen Konzept ausgearbeitet werden. Zur methodischen Bearbeitung des Forschungsinteresses werden problemzzentrierte Interviews mit ambulanten Pflegefachpersonen geführt, die mit Rückbezug auf den Symbolischen Interaktionismus nach Herbert Blumer unter methodologischen und methodischen Gesichtspunkten mittels einer Grounded Theory nach Kathy Charmaz sowie Juliet Corbin und Anselm Strauss erhoben und ausgewertet werden. Dabei kommt ein reflexives-konstruktivistisches Forschen und Schreiben als Konsequenz der epistemologisch-methodologischen Fundierung der Autorin zur Anwendung. Die erarbeitete Theorie beschreibt die Herausforderungen der Pflegebedürftigkeit aus Sicht der befragten Pflegefachpersonen. So werden in der Kernkategorie Aushandlungsprozesse in den Bereichen Nähe und Distanz, Anwaltschaft und Verantwortungsüberlassung sowie Ethos und Technokratie beschrieben. Sämtliche Aspekte zeigen auf, inwiefern der gesetzliche Pflegebedürftigkeitsbegriff zu Herausforderungen innerhalb der pflegerischen Arbeit führt. Die Ph.D.-Thesis liefert mit ihren Ergebnissen einen Beitrag zur Einordnung und Relevanz pflegerischer Beziehungsarbeit im Hinblick auf herrschende Rahmenbedingungen der Pflegebedürftigkeit und zeigt auf, inwiefern sich Interaktion und Kommunikation der Akteur*innen vor dem Anspruch individueller Pflege und dem deutschen ambulanten Pflegesystem wechselseitig bedingen. Sie liefert damit einen professionell und empirisch begründeten Ansatz für die Einschätzung und Bearbeitung von pflegefachlich erlebter Pflegebedürftigkeit.

In the last years, the public interest in epidemiology and mathematical modeling of disease spread has increased - mainly caused by the COVID-19 pandemic, which has emphasized the urgent need for accurate and timely modelling of disease transmission. However, even prior to that, mathematical modelling has been used for describing the dynamics and spread of infectious diseases, which is vital for developing effective interventions and controls, e.g., for vaccination campaigns and social restrictions like lockdowns. The forecasts and evaluations provided by these models influence political actions and shape the measures implemented to contain the virus. This research contributes to the understanding and control of disease spread, specifically for Dengue fever and COVID-19, making use of mathematical models and various data analysis techniques. The mathematical foundations of epidemiological modelling, as well as several concepts for spatio-temporal diffusion like ordinary differential equation (ODE) models, are presented, as well as an originally human-vector model for Dengue fever, and the standard (SEIR)-model (with the potential inclusion of an equation for deceased persons), which are suited for the description of COVID-19. Additionally, multi-compartment models, fractional diffusion models, partial differential equations (PDE) models, and integro-differential models are used to describe spatial propagation of the diseases. We will make use of different optimization techniques to adapt the models to medical data and estimate the relevant parameters or finding optimal control techniques for containing diseases using both Metropolis and Lagrangian methods. Reasonable estimates for the unknown parameters are found, especially in initial stages of pandemics, when little to no information is available and the majority of the population has not got in contact with the disease. The longer a disease is present, the more complex the modelling gets and more things (vaccination, different types, etc.) appear and reduce the estimation and prediction quality of the mathematical models. While it is possible to create highly complex models with numerous equations and parameters, such an approach presents several challenges, including difficulties in comparing and evaluating data, increased risk of overfitting, and reduced generalizability. Therefore, we will also consider criteria for model selection based on fit and complexity as well as the sensitivity of the model with respect to specific parameters. This also gives valuable information on which political interventions should be more emphasized for possible variations of parameter values. Furthermore, the presented models, particularly the optimization using the Metropolis algorithm for parameter estimation, are compared with other established methods. The quality of model calculation, as well as computational effort and applicability, play a role in this comparison. Additionally, the spatial integro-differential model is compared with an established agent-based model. Since the macroscopic results align very well, the computationally faster integro-differential model can now be used as a proxy for the slower and non-traditionally optimizable agent-based model, e.g., in order to find an apt control strategy.

Leichte Sprache (LS, easy-to-read German) is a simplified variety of German. It is used to provide barrier-free texts for a broad spectrum of people, including lowliterate individuals with learning difficulties, intellectual or developmental disabilities (IDD) and/or complex communication needs (CCN). In general, LS authors are proficient in standard German and do not belong to the aforementioned group of people. Our goal is to empower the latter to participate in written discourse themselves. This requires a special writing system whose linguistic support and ergonomic software design meet the target group’s specific needs. We present EasyTalk a system profoundly based on natural language processing (NLP) for assistive writing in an extended variant of LS (ELS). EasyTalk provides users with a personal vocabulary underpinned with customizable communication symbols and supports in writing at their individual level of proficiency through interactive user guidance. The system minimizes the grammatical knowledge needed to produce correct and coherent complex contents by intuitively formulating linguistic decisions. It provides easy dialogs for selecting options from a natural-language paraphrase generator, which provides context-sensitive suggestions for sentence components and correctly inflected word forms. In addition, EasyTalk reminds users to add text elements that enhance text comprehensibility in terms of audience design (e.g., time and place of an event) and improve text coherence (e.g., explicit connectors to express discourse-relations). To tailor the system to the needs of the target group, the development of EasyTalk followed the principles of human-centered design (HCD). Accordingly, we matured the system in iterative development cycles, combined with purposeful evaluations of specific aspects conducted with expert groups from the fields of CCN, LS, and IT, as well as L2 learners of the German language. In a final case study, members of the target audience tested the system in free writing sessions. The study confirmed that adults with IDD and/or CCN who have low reading, writing, and computer skills can write their own personal texts in ELS using EasyTalk. The positive feedback from all tests inspires future long-term studies with EasyTalk and further development of this prototypical system, such as the implementation of a so-called Schreibwerkstatt (writing workshop)

The trends of industry 4.0 and the further enhancements toward an ever changing factory lead to more mobility and flexibility on the factory floor. With that higher need of mobility and flexibility the requirements on wireless communication rise. A key requirement in that setting is the demand for wireless Ultra-Reliability and Low Latency Communication (URLLC). Example use cases therefore are cooperative Automated Guided Vehicles (AGVs) and mobile robotics in general. Working along that setting this thesis provides insights regarding the whole network stack. Thereby, the focus is always on industrial applications. Starting on the physical layer, extensive measurements from 2 GHz to 6 GHz on the factory floor are performed. The raw data is published and analyzed. Based on that data an improved Saleh-Valenzuela (SV) model is provided. As ad-hoc networks are highly depended onnode mobility, the mobility of AGVs is modeled. Additionally, Nodal Encounter Patterns (NEPs) are recorded and analyzed. A method to record NEP is illustrated. The performance by means of latency and reliability are key parameters from an application perspective. Thus, measurements of those two parameters in factory environments are performed using Wireless Local Area Network (WLAN) (IEEE 802.11n), private Long Term Evolution (pLTE) and 5G. This showed auto-correlated latency values. Hence, a method to construct confidence intervals based on auto-correlated data containing rare events is developed. Subsequently, four performance improvements for wireless networks on the factory floor are proposed. Of those optimization three cover ad-hoc networks, two deal with safety relevant communication, one orchestrates the usage of two orthogonal networks and lastly one optimizes the usage of information within cellular networks. Finally, this thesis is concluded by an outlook toward open research questions. This includes open questions remaining in the context of industry 4.0 and further the ones around 6G. Along the research topics of 6G the two most relevant topics concern the ideas of a network of networks and overcoming best-effort IP.

Satzung zur Festsetzung von Zulassungszahlen an der Universität Koblenz für das Studienjahr 2023/2024 Satzung zur Festsetzung der Normwerte für den Ausbildungsaufwand (Curricularnormwerte) der Universität Koblenz Satzung der Universität Koblenz über das Auswahlverfahren in zulassungsbeschränkten Studiengängen Qualitätssicherungskonzept für das Promotions- und Habilitationswesen der Universität Koblenz (Satzung über die Genehmigung von Promotions- und Habilitationsordnungen) Dritte Ordnung zur Änderung der Prüfungsordnung für Studierende des Bachelorstudiengangs „Pädagogik“ (B.A.) und des Masterstudiengangs „Erziehungswissenschaft mit dem Schwerpunkt Forschung und Entwicklung in Organisationen“ (M.A.) des Fachbereichs 1: Bildungswissenschaften an der Universität Koblenz Ordnung zum Betrieb eines Forschungsinformationssystems an der Universität Koblenz (FIS-Ordnung)

Die Geometrie unseres Anschauungsraumes – die euklidische Geometrie – ist für einen allgemeinbildenden Mathematikunterricht elementar. Seitens der Mathematiklehrkraft stellt grundsätzlich ihr Fachwissen das Fundament des Unterrichtens dar. Als Teil ihres Professionswissens sollten Mathematiklehrkräfte prinzipiell über ein Fachwissen verfügen, das in Bezug zur akademischen Mathematik den unterrichtlichen Anforderungen der schulischen Mathematik gerecht wird. Die im Rahmen der Dissertation entwickelte Theorie des metrisch-normalen euklidischen Raumes charakterisiert sich in ihrer perspektivischen Dualität, der mathematischen Stringenz eines axiomatisch-deduktiven Vorgehens auf der einen und der Berücksichtigung der fachdidaktischen Anforderungen an Mathematiklehrkräfte auf der anderen Seite; sie hebt sich darin von bestehenden Theorien ab.

Thematik: Die vorliegende Forschungsarbeit befasst sich mit dem Thema Sustainable Leadership. Dieses Forschungsgebiet der nachhaltigkeitsorientierten Forschung hat in den letzten Jah- ren durch die immer stärker werden Auswirkungen des Klimawandels erheblich an Bedeutung gewonnen. In diesem Zusammenhang rücken Unternehmen immer mehr in den Fokus. Diese müssen nun Wege und Methoden finden, die ihre Arbeitsweise und Prozesse nachhaltiger und umweltschonender gestalten. Die in der vorliegenden Arbeit zu untersuchende Forschungsfrage lautet: „Wie gestaltet sich ein Sustainable Leadership Ansatz in Unternehmen?“ Aufbauend auf dieser übergeordneten Forschungsfrage werden in untergeordneten Forschungsfrage insbesondere Merkmale, Kompetenzen und Verhaltensweisen eines nachhaltigkeitsorientierten Führungsstils betrachtet. Methodik: Die Forschungsmethodik der vorliegenden Arbeit ist eine qualitative Inhaltsanalyse nach Mayring (2019). Mittels semistrukturierter Interviews wurden Führungspersönlichkeiten aus Großunternehmen befragt. Auf Grundlage dieses Datenmaterials wurden induktive Kategorien abgeleitet und qualitativ analysiert und interpretiert. Ergebnisse: Die Ergebnisse der empirischen Forschung wurden in insgesamt fünf Oberkategorien mit jeweils zwei Unterkategorien zusammengefasst. Es wurden die theoretischen Erkennt- nisse des Forschungsbereichs mit den praktischen Erkenntnissen aus den durchgeführten Interviews ergänzt und interpretiert. Des Weiteren wurden die Ergebnisse aus Sicht einer holistischen Unternehmensperspektive in einem konzeptionellen Ansatz modelliert. Ab- schließend wurden aus den Praxiserfahrungen einige Handlungsempfehlungen formuliert und die Merkmale, Kompetenzen, Verhaltensweisen und Auswirkungen eines nachhal- tigkeitsorientierten Führungsstils diskutiert.

Bauxite is, among other raw materials, an important material for the production of refractories. However, the availability of refractory raw material grades is limited worldwide. As high iron contents have a negative influence on the temperature resistance of the refractory material produced, a maximum iron oxide content of 2 wt.-% in the bauxite is acceptable. This means that only native raw materials from a few deposits can be used. In order to counteract the problem of too high iron oxide contents in natural bauxites, the possibility of processing bauxite for the refractory industry by using an acid leaching process was to be investigated within the scope of this work. In previous studies on this topic, some investigations on iron leaching have already been carried out on individual bauxites. However, the resulting bauxite composition was mostly neglected in its entirety and only the influences of individual leaching parameters on the leaching result were investigated independently. Moreover, the results and procedures generated are not generally valid and cannot be transferred to bauxites of other chemical or mineralogical compositions. In order to clarify the open questions in the processing of natural bauxites, leaching tests with hydrochloric acid were carried out on five different bauxites within this work. By using computerized statistical design of experiments, an individual model was generated for each bauxite to predict the optimal factor settings. The factors investigated were acid concentration, solid-acid ratio, leaching temperature, leaching time and grain fraction. The general planning method for bauxite processing developed in this context contains all necessary factors, useful factor settings and the effects to be considered during planning and evaluation. It could be shown that, based on this planning method, a significant, individual model can be created for each of the bauxites investigated, which predicts the optimal leaching settings for the corresponding bauxite. Furthermore, it was found that the transfer of an already created model to another bauxite of similar composition is possible. Based on the results obtained from the leaching tests and model fittings, in combination with further results on the structural analysis of the bauxites, insights into the leachability of various aluminium and iron minerals from bauxite could be gained. To develop a sustainable acid leaching process, the possibility of regenerating the contaminated acid produced was also tested as an example. It was shown that liquid-liquid extraction can extract more than 99 % of the iron present in the solution and that the regenerated acid can then be reused for the leaching process.

Die Umsetzung von Fernarbeitsregelungen wurde bisher überwiegend in allgemeiner Natur betrachtet. In der vorliegenden Arbeit wird mit Hilfe von Interviews mit Führungskräften, Mitarbeitern und IT-Dienstleistern die Umsetzung von Fernarbeitsregelungen in deutschen Regionalbanken betrachtet. Mit Hilfe der Grounded Theory werden dabei Herausforderungen, Lösungsansätze, Vorteile und Nachteile einer Umsetzung herausgearbeitet. Dabei zeigt sich, dass die Umsetzung zwischen den verschiedenen Banken starke Unterschiede aufweist, was den Fortschritt betrifft. Besonders die Überzeugung, dass eine Umsetzung vorteilhaft für die Bank sowie die Mitarbeiter ist, zeigt sich als Kernproblem in der eher konservativen Bankenlandschaft. Mit Hilfe der Arbeit werden Lösungsansätze gezeigt, um Herausforderungen bewältigen zu können und den Einfluss von Nachteilen zu minimieren. Dadurch dient die Arbeit dazu, Regionalbanken bei einer Umsetzung von Fernarbeitsregelungen zu unterstützen, indem sie Potenziale erkennen können und Möglichkeiten aufgezeigt bekommen, eine Umsetzung zu gewährleisten.

Wie hingen Sprache und Gewalt im Nationalsozialismus zusammen? Ausgehend von der konstitutiven Sprachphilosophie des kanadischen Philosophen Charles Taylor untersucht die Dissertation die destruktive Wirkmacht der Sprache am Fall des Nationalsozialismus, der auf ungekannte Weise in die Sprache eingriff und damit Gewalt begünstigte, die bis heute ohnegleichen ist.

Increasingly, problematic smartphone use behavior (PSU) and excessive consumption are reported. In this study, an experiment was developed to investigate the influence of screen coloration using the grayscale setting on smartphone usage time in repeated measurements. We also investigated how individuals perceived suffering correlates with smartphone usage time and PSU, and whether differences exist by smartphone usage type (social, process, habitual). 240 subjects completed a questionnaire about smartphone usage time, PSU, perceived suffering, and smartphone usage types. Afterward, their smartphones were switched to grayscale setting for at least 24h, and thereafter 92 of these participants completed the second questionnaire. Analyses showed that grayscale setting decreases usage time and that there is a positive correlation between PSU, smartphone usage duration, and perceived suffering. The types of use (process and habitual) influence one’s perceived suffering. Thus, it shows that individuals are aware of their PSU and suffer from it. Using grayscale setting is effective in reducing smartphone use time.

Eltern spielen eine entscheidende Rolle bei der Inanspruchnahme von kultureller Bildung durch Kinder und Jugendliche. Häufig sind sie in die Organisation und Finanzierung der kulturellen Bildungsangebote involviert. Insbesondere in ländlichen Räumen kommt die Besonderheit hinzu, dass Eltern aufgrund größerer räumlicher Distanzen und einer unzureichenden Ausstattung des ÖPNV Begleitfahrten mit dem eigenen PKW durchführen müssen. Häufig werden ländliche Räume anhand objektivierbarer Daten als strukturschwach oder kulturarm beschrieben. Darüber, ob oder inwiefern das von ländlich lebenden Eltern ebenso gesehen wird, ist jedoch wenig bekannt. Die vorliegende Dissertationsschrift gibt einen Einblick in die elterlichen Perspektiven auf kulturelle Bildung in ländlichen Räumen. Sie basiert auf offenen, qualitativen Leitfadeninterviews mit Eltern aus vier ländlichen Regionen Deutschlands, die diskursanalytisch und unter Zuhilfenahme von Kodierungspraktiken aus dem Kontext der Grounded Theory ausgewertet wurden. In den Interviews zeigt sich eine Vielzahl an elterlichen Verständnissen und Positionierungsweisen zur kulturellen Bildung in ländlichen Regionen. Es stellt sich heraus, dass der elterliche Diskurs auf einem komplexen Zusammenspiel sozioökonomischer bzw. -kultureller Bedingungen, raumstruktureller Gegebenheiten und individueller Präferenzen hinsichtlich kultureller Bildung auf dem Land basiert.

Praktika als gängige Lehr-Lernformate in hochschulischen Kontexten setzen stets die Zusammenarbeit verschiedener Institutionen und Personen voraus, da Studierende mit einem Praktikum den Lernort der Universität verlassen und in einen beruflichen Handlungszusammenhang mit den zugehörigen organisationalen Strukturen versetzt werden. Praktika werden unter anderem als Elemente der Berufsorientierung gesellschaftliche Implikationen zugeschrieben. Als Format innerhalb eines hochschulischen Bildungsgangs sind sie darüber hinaus mit didaktischen Begründungen verbunden und durch die Beteiligung verschiedener Personen auch mit individuellen Interessen. Studierende sind während eines Praktikums in der Rolle als Praktikant*in in besonderer Weise individuell gefordert. Ergänzt werden diese Perspektiven durch die Betrachtung disziplinärer und professioneller Implikationen, die sich für Praktika erziehungswissenschaftlicher Studiengänge ergeben. Zusammenarbeit findet in Praktika zwischen Organisationen, in Organisationen und zwischen Personen statt. Der geringe Forschungsstand zu Perspektiven auf Fragen der Zusammenarbeit für in erziehungswissenschaftliche Studiengänge integrierte Praktika bietet den Anlass der Studie. Um die verschiedenen Perspektiven auf Praktika als Zusammenarbeit zu erheben, werden qualitative episodische Interviews sowohl mit den Studierenden und Lehrenden einer Universität, als auch mit für Praktika verantwortlichen Tätigen aus dem beruflichen Bereich durchgeführt, die nach der qualitativen inhaltlich strukturierenden Inhaltsanalyse ausgewertet werden. Aus der Auswertung der geführten Interviews mit den drei Akteur*innen-Gruppen ergibt sich ein Einblick darin, wie sich Zusammenarbeit zwischen pädagogisch tätigen Institutionen, Universitäten und Studierenden in und durch Praktika konkretisiert. Es werden beispielsweise Aspekte der Interaktionsbezogenen Dimensionen beschrieben, wie auftauchende Dilemmata, Resonanzen, Kulturen des Umgangs, Interessenslagen und Konstellationen von Akteur*innen. Diese werden ergänzt um Aspekte der Dimensionen mit Bezug zu Institutionen, Umwelt, Aufgaben und Personen. Die Interviewaussagen von drei interviewten Akteur*innen-Gruppen Studierende, Praxisanleiter*innen, universitäre Lehrende werden vergleichend anhand dieser Dimensionen betrachtet und als Ergebnisse dieser Studie dargestellt. Die Ergebnisse liefern Aussagen dazu, wie Zusammenarbeit in Praktika erziehungswissenschaftlicher Studiengänge von den beteiligten Akteur*innen-Gruppen wahrgenommen wird. Dies kann dazu beitragen die differierenden Perspektiven anschlussfähig zu machen für die didaktische und organisatorische Gestaltung von Praktika durch Institutionen wie Universitäten und Praktikumseinrichtungen, aber auch durch Initiative von Studierenden in der Rolle als Praktikant*innen während eines erziehungswissenschaftlichen Studiums. Auch für weitere Forschungsprojekte zum Zusammenwirken der Beteiligten in Praktika kann die Studie Anstöße bieten.