In a world where language defines the boundaries of one's understanding, the words of Austrian philosopher Ludwig Wittgenstein resonate profoundly. Wittgenstein's assertion that "Die Grenzen meine Sprache bedeuten die Grenzen meiner Welt" (Wittgenstein 2016: v. 5.6) underscores the vital role of language in shaping our perceptions. Today, in a globalized and interconnected society, fluency in foreign languages is indispensable for individual success. Education must break down these linguistic barriers, and one promising approach is the integration of foreign languages into content subjects. Teaching content subjects in a foreign language, a practice known as Content Language Integrated Learning (CLIL), not only enhances language skills but also cultivates cognitive abilities and intercultural competence. This approach expands horizons and aligns with the core principles of European education (Leaton Gray, Scott & Mehisto 2018: 50). The Kultusministerkonferenz (KMK) recognizes the benefits of CLIL and encourages its implementation in German schools (cf. KMK 2013a). With the rising popularity of CLIL, textbooks in foreign languages have become widely available, simplifying teaching. However, the appropriateness of the language used in these materials remains an unanswered question. If textbooks impose excessive linguistic demands, they may inadvertently limit students' development and contradict the goal of CLIL. This thesis focuses on addressing this issue by systematically analyzing language requirements in CLIL teaching materials, emphasizing receptive and productive skills in various subjects based on the Common European Framework of Reference. The aim is to identify a sequence of subjects that facilitates students' language skill development throughout their school years. Such a sequence would enable teachers to harness the full potential of CLIL, fostering a bidirectional approach where content subjects facilitate language learning. While research on CLIL is extensive, studies on language requirements for bilingual students are limited. This thesis seeks to bridge this gap by presenting findings for History, Geography, Biology, and Mathematics, allowing for a comprehensive understanding of language demands. This research endeavors to enrich the field of bilingual education and CLIL, ultimately benefiting the academic success of students in an interconnected world.

Organic binder mixtures and process additives have been used in refractory materials for a long time due to their property-improving effect. Coal tar pitches in particular can contain thousands of chemical compounds, of which especially polycyclic aromatic hydrocarbons (PAHs) are known to be carcinogenic and mutagenic and thus pose a risk to both the environment and human health. However, despite intensive research, the exact structure of these carbon mixtures is still not fully clarified. This is becoming an increasing problem, especially with regard to more stringent legal requirements arising from REACH, the European Chemicals Regulation for the Registration, Evaluation, Authorization and Restriction of Chemicals. Furthermore, the knowledge of the structural and chemical composition is also of great importance for optimal processing of the carbon mixtures to high-quality technical products. In the present work, an analytical strategy for the investigation of complex carbon mixtures containing PAHs is developed. Due to their complexity, a combination of different methods is used, including elemental analysis, solvent extraction, thermogravimetry, differential thermal analysis, raman and infrared spectroscopy as well as high-resolution mass spectrometry. In addition, a procedure for the evaluation of mass spectrometric data based on multivariate statistical methods such as hierarchical cluster analysis and principal component analysis is developed. The application of the developed analytical strategy to various industrially used carbon-based binder mixtures allowed the elucidation of characteristic properties, including aromaticity, molecular mass distribution, degree of alkylation and elemental composition. It was also shown that combining high-resolution time-of-flight mass spectrometry with multivariate statistical data analysis is a fast and effective tool for the classification of complex binder mixtures and the identification of characteristic molecular structures. In addition, the analytical strategy was applied to manufactured refractory products. Despite the small amount of the contained organic phase, characteristic structural features of each sample could be identified and extracted, which enabled an unambiguous classification of the refractory products.

With the increasing importance and urgency of climate change, companies are challenged to contribute to sustainable development, especially by younger generations. However, existing corporate contributions have been criticized as insufficient, which could be particularly caused by a lack of employee engagement in corporate sustainability. In this context, gamification has been proposed and increasingly investigated in recent years as a promising, innovative tool to motivate sustainable employee behaviors in the workplace. However, there are few studies and applicable gamification solutions that address more than one specific sustainability issue and thus take a holistic perspective on sustainable behaviors in the workplace. Moreover, previous research lacks a comprehensive understanding of how different gamification elements elicit specific psychological effects, how these manifest in behavioral changes, and how these, in turn, cumulatively result in measurable corporate outcomes. The path from gamification as ”input” to corporate sustainability as ”output” thus remains unexplored. This dissertation fills this gap by conceptualizing, designing, and evaluating a holistic gamified intervention that supports employees in various sustainable behaviors in their daily activities. The project uses a design science research approach that closely involves employees in the incremental development of the solution. As part of the iterative design process, this dissertation presents six studies to extend the theoretical understanding of gamification for sustainable employee behaviors. First, a comprehensive review of existing research on gamification for sustainable employee behavior is provided, analyzing gamification designs and results of previous studies and outlining an agenda for further research (Study 1). Theoretical foundations of research on gamification, serious games, and game-based learning (Study 2) and empirical design principles for gamification and persuasive systems (Study 3) are then systematically reviewed as a basis for the successful design of gamified applications. Subsequently, empirical studies explore employees’ motivations for sustainable behavior and illuminate their expectations for design features (Study 4), and identify contextual challenges and design dilemmas when implementing gamification in an organizational context (Study 5). Finally, a quantitative field study (Study 6) explores how different gamification designs influence sustainable employee behavior and corporate sustainability in organizations. Based on the findings, this dissertation presents a comprehensive framework of gamification for sustainable employee behavior that incorporates design, individual behavior, and organizational perspectives. Finally, building on these insights, it provides practical recommendations for designing gamification to encourage sustainable employee behavior at work.

Bauxite is, among other raw materials, an important material for the production of refractories. However, the availability of refractory raw material grades is limited worldwide. As high iron contents have a negative influence on the temperature resistance of the refractory material produced, a maximum iron oxide content of 2 wt.-% in the bauxite is acceptable. This means that only native raw materials from a few deposits can be used. In order to counteract the problem of too high iron oxide contents in natural bauxites, the possibility of processing bauxite for the refractory industry by using an acid leaching process was to be investigated within the scope of this work. In previous studies on this topic, some investigations on iron leaching have already been carried out on individual bauxites. However, the resulting bauxite composition was mostly neglected in its entirety and only the influences of individual leaching parameters on the leaching result were investigated independently. Moreover, the results and procedures generated are not generally valid and cannot be transferred to bauxites of other chemical or mineralogical compositions. In order to clarify the open questions in the processing of natural bauxites, leaching tests with hydrochloric acid were carried out on five different bauxites within this work. By using computerized statistical design of experiments, an individual model was generated for each bauxite to predict the optimal factor settings. The factors investigated were acid concentration, solid-acid ratio, leaching temperature, leaching time and grain fraction. The general planning method for bauxite processing developed in this context contains all necessary factors, useful factor settings and the effects to be considered during planning and evaluation. It could be shown that, based on this planning method, a significant, individual model can be created for each of the bauxites investigated, which predicts the optimal leaching settings for the corresponding bauxite. Furthermore, it was found that the transfer of an already created model to another bauxite of similar composition is possible. Based on the results obtained from the leaching tests and model fittings, in combination with further results on the structural analysis of the bauxites, insights into the leachability of various aluminium and iron minerals from bauxite could be gained. To develop a sustainable acid leaching process, the possibility of regenerating the contaminated acid produced was also tested as an example. It was shown that liquid-liquid extraction can extract more than 99 % of the iron present in the solution and that the regenerated acid can then be reused for the leaching process.

Im Rahmen des vorliegenden Promotionsprojekts wird untersucht, welche Körperideologien in den drei unterschiedlichen Sportfeldern Hochleistungs-, Gesundheits- sowie Erlebnis- bzw. Funsport gegeben sind und welchen gesellschaftswirksamen Einfluss diese Ideologien aufweisen. Im Rahmen der zentralen Forschungsfrage wird des Weiteren erforscht, welche diskursiven Mittel bei Körperideologien im Sportbereich eingesetzt werden, welche Formationen in Bezug auf den Gegenstand, welche Äußerungsmodalitäten, Begrifflichkeiten und Strategien dem Diskurs zugrundeliegen und wer als TrägerIn oder AdressatIn des Diskurses identifiziert werden kann. Außerdem steht die Fragestellung im Fokus, welche Bezüge zu anderen Diskursen bestehen und um welche Diskurse es sich dabei handelt. Körperideologien des Sports werden in diesem Zusammenhang als Vorstellungen von einem (idealen) Körper betrachtet, welche durch den Sport übertragen und in der Gesellschaft verbreitet werden. Dabei wird zunächst der Begriff der Ideologie theoretisch hergeleitet und definiert sowie im Hinblick auf die vorliegende Arbeit als Weltdeutung mit einem Anspruch auf Alleinvertretung aufgefasst. Des Weiteren wird die Gouvernementalitätstheorie von Foucault aufgegriffen und für die Identifizierung der Macht- und Herrschaftsstrukturen in Bezug auf die untersuchten Körperideologien herangezogen. Dabei geht es darum, inwieweit die durch den Sport übermittelten Körperideologien dazu geeignet sind, in einem gouvernementalitätstheoretischen Sinne Führung zur Selbstführung zu ermöglichen. In einer sportsoziologischen Hinsicht beinhaltet der Sport leistungsbezogene Eigenschaften, welche in auf Effektivität abzielenden wirtschaftlichen Prozessen eine grundlegende Voraussetzung darstellen. Im Rahmen der Studie werden für jeden der drei genannten Sportbereiche jeweils zwei Individualsportarten ausgewählt, bei welchen die fokussierten Körperideologien untersucht werden. Während im Bereich des Hochleistungssports Schwimmen und Biathlon und im Bereich des Gesundheitssports Nordic Walking sowie Pilates betrachtet werden, stellen Stand Up Paddling und Parkour die fokussierten Sportarten im Bereich des Fun- bzw. Erlebnissports dar. Für die vorliegende Untersuchung kommt das Verfahren der kritischen Diskursanalyse (KDA) von Jäger zur Anwendung, da dieses für die Rekonstruktion von ideologischen Diskursen geeignet erscheint. Hierfür werden aus den drei Sportbereichen sowohl Print- als auch Onlinepublikationen sondiert und anhand von Strukturanalysen hinsichtlich verschiedener formaler und inhaltlicher Charakteristika untersucht. Des Weiteren wird mit Hilfe der tiefergehenden Feinanalyse jeweils ein Artikel pro Sportart explorativ analysiert, um verschiedene Muster zu vorhandenen Körperideologien in den fokussierten Sportarten und Sportbereichen identifizieren und anhand ausgewählter Textstellen belegen zu können. Bei den Ergebnissen zeigt sich, dass der Körper in den Hochleistungssportarten Schwimmen und Biathlon als formbares Material bzw. als Instrument zur Erbringung sportlicher Höchstleistungen betrachtet und dargestellt wird. Auch im Gesundheitssport wird der Körper als form- bzw. trainierbar hervorgehoben, wobei hierbei die Gesundheit im Fokus steht und mit Schlankheit gleichgesetzt wird. Im Bereich des Fun- bzw. Erlebnissports zeigt sich bei der Sportart Stand Up Paddling der Körper ebenfalls als zu bearbeitendes Objekt. Dagegen wird bei der Sportart Parkour der angenommene Normalismus von Jugendlichkeit anhand der Ergebnisse widerlegt. Deutlich wird, dass als diskursives Mittel vor allem der Körper als formbares Material erscheint. Dabei stehen in Bezug auf die Äußerungsmodalitäten und Begrifflichkeiten der Diskurse vor allem das Leistungsmaximum, aber auch Schlankheit und Fitness im Fokus. Die identifizierten Diskurse sind an die gesamte Gesellschaft adressiert und werden zudem durch sich selbst getragen, wodurch sie nicht nur die Realität abbilden, sondern auch ein Eigenleben in der Form entwickeln, dass sie als Träger von Wissen fungieren.