Praktika als gängige Lehr-Lernformate in hochschulischen Kontexten setzen stets die Zusammenarbeit verschiedener Institutionen und Personen voraus, da Studierende mit einem Praktikum den Lernort der Universität verlassen und in einen beruflichen Handlungszusammenhang mit den zugehörigen organisationalen Strukturen versetzt werden. Praktika werden unter anderem als Elemente der Berufsorientierung gesellschaftliche Implikationen zugeschrieben. Als Format innerhalb eines hochschulischen Bildungsgangs sind sie darüber hinaus mit didaktischen Begründungen verbunden und durch die Beteiligung verschiedener Personen auch mit individuellen Interessen. Studierende sind während eines Praktikums in der Rolle als Praktikant*in in besonderer Weise individuell gefordert. Ergänzt werden diese Perspektiven durch die Betrachtung disziplinärer und professioneller Implikationen, die sich für Praktika erziehungswissenschaftlicher Studiengänge ergeben. Zusammenarbeit findet in Praktika zwischen Organisationen, in Organisationen und zwischen Personen statt. Der geringe Forschungsstand zu Perspektiven auf Fragen der Zusammenarbeit für in erziehungswissenschaftliche Studiengänge integrierte Praktika bietet den Anlass der Studie. Um die verschiedenen Perspektiven auf Praktika als Zusammenarbeit zu erheben, werden qualitative episodische Interviews sowohl mit den Studierenden und Lehrenden einer Universität, als auch mit für Praktika verantwortlichen Tätigen aus dem beruflichen Bereich durchgeführt, die nach der qualitativen inhaltlich strukturierenden Inhaltsanalyse ausgewertet werden. Aus der Auswertung der geführten Interviews mit den drei Akteur*innen-Gruppen ergibt sich ein Einblick darin, wie sich Zusammenarbeit zwischen pädagogisch tätigen Institutionen, Universitäten und Studierenden in und durch Praktika konkretisiert. Es werden beispielsweise Aspekte der Interaktionsbezogenen Dimensionen beschrieben, wie auftauchende Dilemmata, Resonanzen, Kulturen des Umgangs, Interessenslagen und Konstellationen von Akteur*innen. Diese werden ergänzt um Aspekte der Dimensionen mit Bezug zu Institutionen, Umwelt, Aufgaben und Personen. Die Interviewaussagen von drei interviewten Akteur*innen-Gruppen Studierende, Praxisanleiter*innen, universitäre Lehrende werden vergleichend anhand dieser Dimensionen betrachtet und als Ergebnisse dieser Studie dargestellt. Die Ergebnisse liefern Aussagen dazu, wie Zusammenarbeit in Praktika erziehungswissenschaftlicher Studiengänge von den beteiligten Akteur*innen-Gruppen wahrgenommen wird. Dies kann dazu beitragen die differierenden Perspektiven anschlussfähig zu machen für die didaktische und organisatorische Gestaltung von Praktika durch Institutionen wie Universitäten und Praktikumseinrichtungen, aber auch durch Initiative von Studierenden in der Rolle als Praktikant*innen während eines erziehungswissenschaftlichen Studiums. Auch für weitere Forschungsprojekte zum Zusammenwirken der Beteiligten in Praktika kann die Studie Anstöße bieten.

With the increasing importance and urgency of climate change, companies are challenged to contribute to sustainable development, especially by younger generations. However, existing corporate contributions have been criticized as insufficient, which could be particularly caused by a lack of employee engagement in corporate sustainability. In this context, gamification has been proposed and increasingly investigated in recent years as a promising, innovative tool to motivate sustainable employee behaviors in the workplace. However, there are few studies and applicable gamification solutions that address more than one specific sustainability issue and thus take a holistic perspective on sustainable behaviors in the workplace. Moreover, previous research lacks a comprehensive understanding of how different gamification elements elicit specific psychological effects, how these manifest in behavioral changes, and how these, in turn, cumulatively result in measurable corporate outcomes. The path from gamification as ”input” to corporate sustainability as ”output” thus remains unexplored. This dissertation fills this gap by conceptualizing, designing, and evaluating a holistic gamified intervention that supports employees in various sustainable behaviors in their daily activities. The project uses a design science research approach that closely involves employees in the incremental development of the solution. As part of the iterative design process, this dissertation presents six studies to extend the theoretical understanding of gamification for sustainable employee behaviors. First, a comprehensive review of existing research on gamification for sustainable employee behavior is provided, analyzing gamification designs and results of previous studies and outlining an agenda for further research (Study 1). Theoretical foundations of research on gamification, serious games, and game-based learning (Study 2) and empirical design principles for gamification and persuasive systems (Study 3) are then systematically reviewed as a basis for the successful design of gamified applications. Subsequently, empirical studies explore employees’ motivations for sustainable behavior and illuminate their expectations for design features (Study 4), and identify contextual challenges and design dilemmas when implementing gamification in an organizational context (Study 5). Finally, a quantitative field study (Study 6) explores how different gamification designs influence sustainable employee behavior and corporate sustainability in organizations. Based on the findings, this dissertation presents a comprehensive framework of gamification for sustainable employee behavior that incorporates design, individual behavior, and organizational perspectives. Finally, building on these insights, it provides practical recommendations for designing gamification to encourage sustainable employee behavior at work.

Die Geometrie unseres Anschauungsraumes – die euklidische Geometrie – ist für einen allgemeinbildenden Mathematikunterricht elementar. Seitens der Mathematiklehrkraft stellt grundsätzlich ihr Fachwissen das Fundament des Unterrichtens dar. Als Teil ihres Professionswissens sollten Mathematiklehrkräfte prinzipiell über ein Fachwissen verfügen, das in Bezug zur akademischen Mathematik den unterrichtlichen Anforderungen der schulischen Mathematik gerecht wird. Die im Rahmen der Dissertation entwickelte Theorie des metrisch-normalen euklidischen Raumes charakterisiert sich in ihrer perspektivischen Dualität, der mathematischen Stringenz eines axiomatisch-deduktiven Vorgehens auf der einen und der Berücksichtigung der fachdidaktischen Anforderungen an Mathematiklehrkräfte auf der anderen Seite; sie hebt sich darin von bestehenden Theorien ab.

In the last years, the public interest in epidemiology and mathematical modeling of disease spread has increased - mainly caused by the COVID-19 pandemic, which has emphasized the urgent need for accurate and timely modelling of disease transmission. However, even prior to that, mathematical modelling has been used for describing the dynamics and spread of infectious diseases, which is vital for developing effective interventions and controls, e.g., for vaccination campaigns and social restrictions like lockdowns. The forecasts and evaluations provided by these models influence political actions and shape the measures implemented to contain the virus. This research contributes to the understanding and control of disease spread, specifically for Dengue fever and COVID-19, making use of mathematical models and various data analysis techniques. The mathematical foundations of epidemiological modelling, as well as several concepts for spatio-temporal diffusion like ordinary differential equation (ODE) models, are presented, as well as an originally human-vector model for Dengue fever, and the standard (SEIR)-model (with the potential inclusion of an equation for deceased persons), which are suited for the description of COVID-19. Additionally, multi-compartment models, fractional diffusion models, partial differential equations (PDE) models, and integro-differential models are used to describe spatial propagation of the diseases. We will make use of different optimization techniques to adapt the models to medical data and estimate the relevant parameters or finding optimal control techniques for containing diseases using both Metropolis and Lagrangian methods. Reasonable estimates for the unknown parameters are found, especially in initial stages of pandemics, when little to no information is available and the majority of the population has not got in contact with the disease. The longer a disease is present, the more complex the modelling gets and more things (vaccination, different types, etc.) appear and reduce the estimation and prediction quality of the mathematical models. While it is possible to create highly complex models with numerous equations and parameters, such an approach presents several challenges, including difficulties in comparing and evaluating data, increased risk of overfitting, and reduced generalizability. Therefore, we will also consider criteria for model selection based on fit and complexity as well as the sensitivity of the model with respect to specific parameters. This also gives valuable information on which political interventions should be more emphasized for possible variations of parameter values. Furthermore, the presented models, particularly the optimization using the Metropolis algorithm for parameter estimation, are compared with other established methods. The quality of model calculation, as well as computational effort and applicability, play a role in this comparison. Additionally, the spatial integro-differential model is compared with an established agent-based model. Since the macroscopic results align very well, the computationally faster integro-differential model can now be used as a proxy for the slower and non-traditionally optimizable agent-based model, e.g., in order to find an apt control strategy.

Leitfrage: Inwieweit ist der Physikdidaktiker und Pädagoge Martin Wagenschein heute noch relevant? Antwort: Er ist!

Wie hingen Sprache und Gewalt im Nationalsozialismus zusammen? Ausgehend von der konstitutiven Sprachphilosophie des kanadischen Philosophen Charles Taylor untersucht die Dissertation die destruktive Wirkmacht der Sprache am Fall des Nationalsozialismus, der auf ungekannte Weise in die Sprache eingriff und damit Gewalt begünstigte, die bis heute ohnegleichen ist.

Efforts to induce customers to buy groceries through the Internet have existed for around twenty years. Early on, the market structures of the digital grocery trade were still strongly fragmented and poorly coordinated. Due to the technological advancement in the past decade, the digital purchase of groceries has become more attractive. The adoption rate of these services varies greatly between different regions. In Germany in particular, the digital grocery trade is stagnating at a comparatively low level. In this regard, this dissertation analyzes both the retail-side market structures and the expectations and obstacles of German consumers. The year 2020 connotes a turning point for the online grocery trade, as daily routines such as grocery shopping were subject to strict regulations imparted at a governmental level in order to reduce COVID-19 infections. At the same time, despite this opportunity, the digital grocery trade has not yet established itself nationwide in Germany. This can be attributed to a lack of investments, but also to inadequate digitization measures. A stronger synchronization between the digital and stationary offer, better integration of digital food services at a regional level as well as adapted, target group-appropriate digital solutions for the efficient breakdown of usage barriers will benefit service usage. The importance of stable food chains and distribution channels was illustrated by the COVID-19 pandemic. Further research should help to develop the digital food trade into a stable and sustainable supplementation of the stationary store.

Today’s agriculture heavily relies on pesticides to manage diverse pests and maximise crop yields. Despite elaborate regulation of pesticide use based on a complex environmental risk assessment (ERA) scheme, the widespread use of these biologically active compounds has been shown to be a threat to the environment. For surface waters, pesticide exposure has been observed to exceed safe concentration levels and negatively impact stream ecology leading to the question whether current ERA schemes ensure a sustainable use of pesticides. To answer this, the large-scale “Kleingewässer-Monitoring” (KgM) assessed the occurrence of pesticides and related effects in 124 streams throughout Germany, Central Europe, in 2018 and 2019. Based on five scientific publications originating from the KgM, this thesis evaluated pesticide exposure in streams, ecological effects and the regulatory implications. More than 1,000 water samples were analysed for over 100 pesticide analytes to characterise occurrence patterns (publication 1). Measured concentrations and effects were used to validate the exposure and effect concentrations predicted in the ERA (publication 2). By jointly analysing real-world pesticide application data and measured pesticide mixtures in streams, the disregard of environmental pesticide mixtures in the ERA was evaluated (publication 3). The toxic potential of mixtures in stream water was additionally investigated using suspect screening for 395 chemicals and a battery of in-vitro bioassays (publication 4). Finally, the results from the KgM stream monitoring were used to assess the capability to identify pesticide risks in governmental monitoring programmes (publication 5). The results of this thesis reveal the widespread occurrence of pesticides in non-target stream ecosystems. The water samples contained a variety of pesticides occurring in complex mixtures predominantly in short-term peaks after rainfall events (publications 1 & 4). Respective pesticide concentration maxima were linked to declines in vulnerable invertebrate species and exceeded regulatory acceptable concentrations in about 80% of agricultural streams, while these thresholds were still estimated partly insufficient to protect the invertebrate community (publication 2). The co-occurrence of pesticides in streams led to a risk underestimated in the single substance-oriented ERA by a factor of about 3.2 in realistic worst-case scenarios, which is further exacerbated by a high frequency at which non-target organism are exposed to pesticides (publication 3). Stream water samples taken after rainfall caused distinct effects in bioassays which were only explainable to a minor extent by the many analytes, indicating the relevance of unknown chemical or biological mixture components (publication 4). Finally, the regulatory monitoring of surface waters under the Water Framework Directive (WFD) was found to significantly underestimate pesticide risks, as about three quarters of critical pesticides and more than half of streams at risk were overlooked (publication 5). Essentially, this thesis involves a new level of validation of the ERA of pesticides in aquatic ecosystems by assessing pesticide occurrence and environmental impacts at a scale so far unique. The overall results demonstrate that the current agricultural use of pesticides leads to significant impacts on stream ecology that go beyond the level tolerated under the ERA. This thesis identified the underestimation of pesticide exposure, the potential insufficiency of regulatory thresholds and the general inertia of the authorisation process as the main causes why the ERA fails to meet its objectives. To achieve a sustainable use of pesticides, the thesis proposes substantial refinements of the ERA. Adequate monitoring programmes such as the KgM, which go beyond current government monitoring efforts, will continue to be needed to keep pesticide regulators constantly informed of the validity of their prospective ERA, which will always be subject to uncertainty.

This thesis was motivated by the need to advance the knowledge on the variability and dynamics of energy fluxes in lakes and reservoirs, as well as about the physical processes that regulate the fluxes at both the air and water side of the air-water interface. In the first part, I re-examine how mechanical energy, resulting from its major source – the vertical wind energy flux - distributes into the various types of water motions, including turbulent flows and surface and internal waves. Although only a small fraction of the wind energy flux from the atmosphere is transferred to the water, it is crucial for physical, biogeochemical and ecological processes in lentic ecosystems. Based on extensive air- and water-side measurements collected at two small water bodies (< 10 km2), we estimated the energy fluxes and energy content in surface and in internal waves. Overall, the estimated energy fluxes and energy content agree well with results reported for larger water bodies, suggesting that the energetics driving the water motions in enclosed basins is similar, independently of the basin size. Our findings highlight the importance of the surface waves that receive the largest fraction of the wind energy flux, which strongly nonlinearly increases for wind speeds exceeding 3 m s-1. We found that the existing parameterization of the wave height as a function of wind speed and fetch length did not reproduce the measured wave amplitude in lakes. On average, the highest energy content was observed in basin-scale internal waves, together with high-frequency internal waves exhibiting seasonal variability and varies among the aquatic systems. During our analysis, we discovered the diurnal variability of the energy dissipation rates in the studied lake, suggesting biogenic turbulence generation, which appears to be a widespread phenomenon in lakes and reservoirs. In the second part of the thesis, I addressed current knowledge gaps related to the bulk transfer coefficients (also known as the drag coefficient, the Stanton number and the Dalton number), which are of a particular importance for the bulk estimation of the surface turbulent fluxes of momentum, sensible and latent heat in the atmospheric boundary layer. Their inaccurate representation may lead to significant errors in flux estimates, affecting, for example, the weather and climate predictions or estimations of the near-surface current velocities in lake hydrodynamic models. Although the bulk transfer coefficients have been extensively studied over the past several decades (mainly in marine and large-lake environments), there has been no systematic analysis of measurements obtained at lakes of different size. A significant increase of the transfer coefficients at low wind speeds (< 3 m s-1) has been observed in several studies, but, to date, it has remained unexplained. We evaluated the bulk transfer coefficients using flux measurements from 31 lakes and reservoirs. The estimates were generally within the range reported in previous studies for large lakes and oceans. All transfer coefficients increased substantially at low wind speeds, which was found to be associated with the presence of gusts and capillary waves (except the Dalton number). We found that the Stanton number is systematically higher than the Dalton number. This challenges the assumption made in the Bowen-ratio method, which is widely used for estimating evaporation rates from micrometeorological measurements. We found that the variability of the transfer coefficients among the lakes could be associated with lake surface area. In flux parameterizations at lake surfaces, it is recommended to consider variations in the drag coefficient and the Stanton number due to wind gustiness and capillary wave roughness while the Dalton number could be considered as constant at all wind speeds. In the third part of the thesis, I address the key drivers of the near-surface turbulence that control the gas exchange in a large regulated river. As all inland waters, rivers are an important natural source of greenhouse gases. The effects of the widespread alteration and regulation of river flow for human demands on gas exchange is largely unknown. In particular, the near-surface turbulence in regulated rivers has been rarely measured and its drivers have not been identified. While in lakes and reservoirs, near-surface turbulence is mainly related to atmospheric forcing, in shallow rivers and streams it is generated by bottom friction of the gravity-forced flow. The studied large regulated river represents a transition between these two cases. Atmospheric forcing and gravity were the dominant drivers of the near-surface turbulence for a similar fraction of the measurement period. Based on validated scalings, we derived a simple model for estimating the relative contributions of wind and bottom friction to near-surface turbulence in lotic ecosystems with different flow depths. Large diel variability in the near-surface energy dissipation rates due to flow regulation leads to the same variability in gas exchange. This suggests that estimates of gas fluxes from rivers are biased by measurements performed predominantly during daytime. In addition, the novelty in all the analyses described above is the use of the turbulent surface fluxes measured directly by the eddy-covariance technique – at the moment of writing, the most advanced method. Overall, this thesis is of a potential interest for a broad range of scientific disciplines, including limnology, micrometeorology and open channel hydraulics.

This dissertation is dedicated to a new concept for capturing renunciation-oriented attitudes and beliefs — sufficiency orientation. Sufficiency originates in the interdisciplinary sustain-ability debate. In contrast to efficiency and consistency, sufficiency considers human behaviour as the cause of socio-ecological crises and strives for a reduction in consumption respecting the planetary boundaries. The present work places sufficiency in a psychological research context and explores it qualitatively and quantitatively. On the basis of five manuscripts, the overarching question pursued is to what extent sufficiency orientation contributes to socio-ecological transformation. Based on one qualitative study and five further quantitative studies, sufficiency orientation is investigated in different behavioural contexts that are of particular importance with regard to CO2 emissions. In addition, sufficiency orientation is linked to a wider range of psychologically relevant theories that help gain an overview of correlates and possible causes for the development of a sufficiency orientation. Manuscript 1 uses expert interviews (N = 21) to develop a heuristic framework on a transformation towards societal sufficiency orientation including barriers and enablers, as well as ambiguities on such a change. The derived elements are interpreted in the light of the leverage points approach. This framework can serve as a heuristic for future research and to develop measures concerning sufficiency orientation. As part of an online study (N = 648), Manuscript 2 examines the extent to which sufficiency orientation can be embedded in classic models for explaining pro-environmental intentions and behaviour (Theory of Planned Behaviour, Norm Activation Model), and showed a significant contribution to the explanation of intentions and behaviour in the field of plastic consumption. Manuscript 3 reports two framing experiments (Study 1, N = 123, Study 2, N = 330) to investigate how pro-social justice sensitivity contributes to making sufficiency orientation more salient and promoting it. While sufficiency orientation and pro-social facets of justice sensitivity were positively related to each other, there was no effect of the framing intervention in the hypothesised direction. The results indicate that justice-related information at least in the presented manner is more likely to generate reactance. Manuscript 4 presents an online study (N = 317) and targets the importance of sufficiency orientation for predicting actual greenhouse gas emissions in relation to flight behav-iour and policy support for the decarbonisation of mobility. In addition, the connection between sufficiency orientation and global identity is examined. It turns out that sufficiency orientation is superior to global identity in predicting actual emissions and decarbonisation policies. Contrary to expectations, sufficiency orientation and the form of global identity operationalised in the presented study shows a positive correlation and are compatible. Manuscript 5 reports a reflective diary intervention (N = 252) that should lead to a short- and long-term increase in sufficiency orientation by satisfying basic psychological needs through induced self-reflection. For both groups with or without the intervention, sufficiency orientation increased slightly but significantly. Although no specific effect of the manipulation was found, basic psychological need satisfaction turns out to be the largest predictor for sufficiency orientation. Subjective well-being is positively associated with sufficiency orientation, while time affluence shows no clear associations in the study. Overall, the results highlight the relevance of sufficiency orientation in relation to socio-ecological transformation and actual behavioural change. Sufficiency orientation is related to low-emission behaviour and support for political measures to decarbonize infrastructures. These results contribute to the discussion on the intention-behaviour gap in regard to impact-relevant behaviour, i.e. behaviour producing high emissions. The present findings suggest, that sufficiency orientation could be related to a strong intention-behavioural consistency. However, further research is needed to validate these results and improve the measurement of sufficiency orientation. Furthermore, the studies provided insights on correlates of sufficiency orientation: justice sensitivity, global identity, subjective well-being and left-wing liberal political ideologies are all found to be positively related to sufficiency orien-tation. Moreover, basic psychological need satisfaction was identified as a potential mechanism that can support the emergence of sufficiency orientation, however, causality remains unclear. From these findings, the work derives practical implications how to possibly strengthen sufficiency orientation on the micro, meso and macro levels of society. Taken together, the dissertation provides important insights into a new and still developing concept, and shows its connectivity to psychological theories. However, future research is required in order to grasp more precisely the complexity of sufficiency orientation and to understand origins and predictors of sufficiency orientation. This work contributes to the interdisciplinary debate on socio-ecological transformation and points out that sufficiency orientation can serve to a future worth living as being related to reduced consumption.

This study examines the contribution of saving and credit cooperatives (SACCOS) on the improvement of members‘ socio economic development in Rwanda: Opportunities and challenges‖, Evidence from Umwalimu SACCO- Huye District‖. The appearance of saving and credit cooperatives or credit unions has been known as remedy for social ills rooted in poverty because of its efficiency in loans or credits dispensation, social equality for enhancement and reduction of poverty amongst low income earners. Therefore, millions and millions of poor people and non-bankable in developing countries (or third world countries) have been provided access to formal financial services through saving and credit cooperatives‘ programs. The targeted population concerned by the study was 1,940 members of USACCO from which a sample of 92 respondents was purposively selected. The study has adopted a combination of correlation and descriptive research design. It has employed both quantitative and qualitative approaches. The study used both primary and secondary data. The primary data was collected using questionnaire and interview and, while secondary data was collected using documentations techniques whereby, Manual of procedures and Credit policies of USACCO and financial reports have been consulted. The analysis of data was done using SPSS version 21. The data was presented in form of tables, charts and graphs designed by SPSS v. 21. The bio-characteristics of respondents showed that, the majority of respondents were women with 55.4%, majority of respondents‘ age is between 26 to 45 years Furthermore, and majority 77.20% of respondents were married. 100% of respondents attended school, where the majority of respondents attended secondary school with certificate A2. The study has revealed that Umwalimu SACCO services offered to its members have a positive effect on the improvement of members‘ welfare. It was found that USACCO services have slightly affected income level of members, assets acquired, access to education and medical care as well as small income generating activities established by members in Huye District. The analysis of data also revealed that there are some variables which have effected USACCO members‘ socio-economic status, these were listed as: Education background of a member, number of dependents, the occupation of a member, and number of loans got from USACCO, government programs against teachers‘ welfare, and membership duration played very important role on the improvement of standard living of teachers. All these variables were found to have positive effects on teachers‘ socio-economic status, except the family size of respondents. In addition, the findings showed that, the majority of respondents confirmed that, they did not find opportunities to save with other financial institutions, and other respondents did not have access to loan from other financial institutions due to complicated loan requirements. In addition, after they have joined USACCO, their deplorable status somewhat changed, both socially and economically which has contributed to the improvement of their welfare. Therefore, the study testified that, the welfare of USACCO members in terms of assets acquired, income increased was improved compared to situation before joining USACCO. The study concludes that ―the level of improvement of living conditions of teachers depends largely to the level of loan granted by USACCO to teachers and membership duration. If the level of teachers‘ loan and saving increases, there will be also improvement of teachers‘ wellbeing‖ and finally, USACCO financial service is a veritable instrument for better improvement of economic and social conditions of teachers. The study recommends that, USACCO should provide frequent and regular trainings on business management game to their members. This could help members for good management of their loans and reducing loan defaulters‘ cases observed at USACCO. Challenges observed were lack of physical collateral security required by USACCO, complicated loan requirements terms and conditions and insufficient trainings on business management game.

The presented study was motivated by the dynamic phenomena observed in basic catalytic surface reactions, especially by bi- and tristability, and the interactions between these stable states. In this regard, three reaction-diffusion models were developed and examined using bifurcation theory and numerical simulations. A first model was designed to extend the bistable CO oxidation on Ir(111) to include hydrogen and its oxidation. The differential equation system was analyzed within the framework of bifurcation theory, revealing three branches of stable solutions. One state is characterized by high formation rates (upper rate state, UR), while the other two branches display low formation rates (lower rate (LR) \& very low rate (VLR) states). The overlapping branches form the shape of a `swallowtail', the curve of saddle-node bifurcations forming two cusps. Increasing the temperature leads to a subsequent unfolding and hence decreases the system complexity. A series of numerical simulations representing possible experiments was conducted to illustrate the experimental accessibility (or the lack) of said states. Relaxation experiments show partially long decay times. Quasistatic scanning illustrates the existence of all three states within the tristable regime and their respective conversion once crossing a fold. A first attempt regarding the state dominance in reaction-diffusion fronts was done. While UR seems to dominate in 1D, a 2D time-evolution shows that LR invades the interphase between UR and VLR. Subsequently, a generic monospecies mock model was used for the comprehensive study of reaction-diffusion fronts. A quintic polynomial as reaction term was chosen, derived by the sixth-order potential associated with the `butterfly bifurcation'. This ensures up to three stable solutions($u_{0}$,$u_{1}$,$u_{2}$), depending on the four-dimensional parameter space. The model was explored extensively, identifying regions with similar behaviors. A term for the front velocity connecting two stable states was derived, depending only on the relative difference of the states' potential wells. Equipotential curves were found, where the front velocity vanishes of a given front. Numerical simulations on a two-dimensional, finite disk using a triangulated mesh supported these findings. Additionally, the front-splitting instability was observed for certain parameters. The front solution $u_{02}$ becomes unstable and divides into $u_{01}$ and $u_{12}$, exhibiting different front velocities. A good estimate for the limit of the front splitting region was given and tested using time evolutions. Finally, the established mock model was modified from continuous to discrete space, utilizing a simple domain in 1D and three different lattices in 2D (square, hexagonal, triangular). For low diffusivities or large distances between coupling nodes, fronts can become pinned, if the parameters are within range of the equipotential lines. This phenomenon is known as propagation failure and its extent in parameter space was explored in 1D. In 2D, an estimate was given for remarkable front orientations respective to the lattice using a pseudo-2D approximation. Near the pinning region, front velocities differ significantly from the continuous expectation as the shape of the curve potential becomes significant. Factors that decide the size and shape of the pinning regions are the coupling strength, the lattice, the front orientation relative to the lattice, and the front itself. The bifurcation diagram shows a snaking curve in the pinning region, each alternating branch representing a stable or unstable frozen front solution. Numerical simulations supported the observations concerning propagation failure and lattice dependence. Furthermore, the influence of front orientation on the front velocity was explored in greater detail, showing that fronts with certain lattice-dependent orientations are more or less prone to propagation failure. This leads to the possibility of pattern formation, reflecting the lattice geometry. An attempt to quantify the front movement depending on angular front orientation has shown reasonable results and good agreement with the pseudo-2D approach.

This study was conducted in Nyungwe National Park (NNP); a biodiversity hotspot Mountain rainforest of high conservation importance in Central Africa, but with little knowledge of its insect communities including butterflies, good indicators of climate change, and forest ecosystem health. The study aimed at availing baseline data on butterfly species diversity and distribution in NNP, for future use in monitoring climate change-driven shifts and the effects of forest fragmentation on the biodiversity of Nyungwe. Butterflies were collected seasonally using fruit-baited traps and hand nets along elevational transects spanning from 1700 m up to 2950 m of altitude. Two hundred forty-two species including 28 endemics to the Albertine Rift and 18 potential local climate change indicators were documented. Species richness and abundance declined with increasing elevation and higher seasonal occurrence was observed during the dry season. This was the first study on the spatial and temporal distribution of butterflies in NNP and further studies could be conducted to add more species and allow a depth understanding of the ecology of Nyungwe butterflies.

Die Arbeit stellt eine Systematisierung der wissenschaftsphilosophischen Gedanken der klassischen Pragmatisten (Charles S. Peirce, William James, John Dewey) dar. Deren Erfahrungstheorie sowie die Bestimmung des Verhältnisses von Theorie und Praxis bilden die Grundlage einer holistischen Wissenschaftsphilosophie. Die exemplarische Anwendung auf klassische wissenschaftstheoretische Fragestellungen zeigt die Aktualität des Ansatzes.

Eine Ursache des Insektenrückgangs ist die Abnahme der für Arthropoden wichtigen Lebensräume. Der kleinstrukturierte Obstanbau als Dauerkultur mit vielfältigen Strukturen (Bäume, Grünland, offener Boden) kann als Refugium wirken. Gerade Dauerkulturen, welche über viele Jahre bestehen bleiben, können einen großen ökologischen Wert für Insekten und Spinnentiere darstellen, wenn die negativen Einflüsse der Bewirtschaftung durch gezielte Maßnahmen minimiert werden. Im Gegensatz zu den gut untersuchten Streuobstwiesen liegen bisher nur wenige oder ungenaue Daten über die Arthropodenfauna in Erwerbsobstanlagen vor. Ziele dieser Arbeit sind eine genauere Erfassung der Arthropodenfauna in Erwerbsobstanlagen, Benennung der Einflussfaktoren und Erarbeitung einer indikatorgestützten Bewertungsmethode mit Entwicklung von Maßnahmen zur Förderung der Biodiversität. Es wurde eine intensive Erfassung der Insekten und Spinnentiere auf Basis von Individuenzahlen, Verteilung der Tiere auf Großgruppen, Artenzahlen der Käfer (inkl. Rote Liste) und Wanzen, deren Diversität und der sie beeinflussenden Faktoren auf vier Erwerbsobstflächen und einer Streuobstwiese als Referenzfläche in der Gemeinde Zornheim (Rheinland-Pfalz) untersucht. Mittels des erarbeiteten Bewertungsbogens wurden die Auswirkungen der fünf Faktorenkomplexe: Sonderstrukturen, Anlagenstruktur, Beschattung, Mahdregime und Einsatz von Pflanzenschutzmitteln auf die Arthropodenfauna erhoben und die auf der Fläche zu erwartende Biodiversität ermittelt. Die visuelle Darstellung der Einflussfaktoren mit Netzdiagrammen zeigt biodiversitätsbeeinträchtigende Faktoren und ermöglicht so Empfehlungen zur Aufwertung der Biodiversität. Die Bewertungsmethode kann nach Verifizierung im Rahmen von erfolgsorientierten Agrarumwelt- und Klimamaßnahmen (AUKM), zur Anerkennung von Kompensationsmaßnahmen (z.B. PIK) und zur Ermittlung des ökologischen Wertes (Ökosystemdienstleistung) von Obstanlagen genutzt werden. In modifizierter Form könnte es ebenfalls im Bereich der Flächenbewertung in Landschafts- und Bauleitplanung eingesetzt werden.

Social media provides a powerful way for people to share opinions and sentiments about a specific topic, allowing others to benefit from these thoughts and feelings. This procedure generates a huge amount of unstructured data, such as texts, images, and references that are constantly increasing through daily comments to related discussions. However, the vast amount of unstructured data presents risks to the information-extraction process, and so decision making becomes highly challenging. This is because data overload may cause the loss of useful data due to its inappropriate presentation and its accumulation. To this extent, this thesis contributed to the field of analyzing and detecting feelings in images and texts. And that by extracting the feelings and opinions hidden in a huge collection of image data and texts on social networks After that, these feelings are classified into positive, negative, or neutral, according to the features of the classified data. The process of extracting these feelings greatly helps in decision-making processes on various topics as will be explained in the first chapter of the thesis. A system has been built that can classify the feelings inherent in the images and texts on social media sites, such as people’s opinions about products and companies, personal posts, and general messages. This thesis begins by introducing a new method of reducing the dimension of text data based on data-mining approaches and then examines the sentiment based on neural and deep neural network classification algorithms. Subsequently, in contrast to sentiment analysis research in text datasets, we examine sentiment expression and polarity classification within and across image datasets by building deep neural networks based on the attention mechanism.

Manmade dams have been constructed from centuries for multiple purposes, and in the past decades they have been constructed in a fast pace, with the hotspot in tropical and subtropical regions. However, studies that explore hydrodynamics in these areas are scarce and biased to the rich literature available for temperate regions. Lakes and reservoirs have the same controlling mechanisms for physical processes and primary production, hence, analyses that were initially conceptualized for lakes are frequently applied for reservoirs. Nevertheless, longitudinal gradients in reservoirs challenges the application of these approaches. Degradation of water quality in reservoirs is a major concern, and it is expected to be aggravated with climate change. Therefore, studies that explore mechanisms controlling water quality are essential for the maintenance of these systems, especially in tropical and subtropical regions. The aim of this thesis is to comprehend the role of hydrodynamic processes in the fate of nutrients in reservoirs and its implications on water quality, in a subtropical region. With focus on the relevance of different density current patterns. For that, analyses combining field measurements and numerical simulations were performed in a medium to small size subtropical drinking water reservoir for a complete seasonal cycle. Measurements were conducted combining several approaches: traditional sampling, sensors in high temporal and spatial resolution, and remote sensing. Besides, hydrodynamic models were set up and calibrated to reproduce observations, and to simulate scenarios that assisted on the analysis. Results showed that different flow paths of density currents did not influence on phytoplankton dynamics. At the regions where the main nutrient supply was the river inflow (upstream), the density currents did not vary, the euphotic zone usually covered the entire depth, and vertical mixing was observed on a daily basis, turning the flow path of the density currents irrelevant. At downstream regions, the remobilization of nutrients in the sediment was the main source for primary production. Even though density currents had a seasonal pattern in the downstream region, thermal stratification conditions were the driver for variations in chlorophyll-a concentrations, with peaks after vertical mixing. This mechanism had in its favor the frequent anoxic conditions in the hypolimnion that enhanced the dissolution of reactive phosphorus from the sediment. Anoxic conditions were easily reached because the sediment in the downstream area was rich in organic matter. Phytoplankton produced in the upstream area was transported by the density currents, and for this reason, large concentrations of chl-a was observed below the euphotic zone. Further, the extensive measurements of temperature, and flow velocities, together with the hydrodynamic models, provided insights about the hydrodynamics of reservoirs. For instance, that the relevant processes occurred along the longitudinal, and mixing conditions varied along it. The relevance of inflow conditions regarding the presence of structures such as forebays and pre-dams, and the degree of stream shading in the catchment was assessed. And turbulence and internal waves had different features than the documented for high latitudes. Those findings can assist on the management of reservoirs, based on the comprehension of the physical processes.

Enterprise Collaboration Systems (ECS) werden zunehmend als Kernkomponenten des digitalen Arbeitsplatzes in Unternehmen eingesetzt, die mit der Implementierung dieser neuen Softwaregattung jeweils unterschiedliche Ziele für die innerbetriebliche Zusammenarbeit verfolgen. Diese Ziele werden in der Praxis oftmals nicht eindeutig genug formuliert. Der Einsatz von traditionellen Controlling-Kennzahlen mit dem Schwerpunkt auf Termineinhaltung und Kosten sind zudem ungeeignet, um die Realisierung des individuellen Nutzens von ECS zu messen. Diese Forschungsarbeit beschreibt die Entwicklung und Anwendung des Benefits Scorecards for Collaboration Platforms in Enterprises (SCoPE) Frameworks, das als ein Rahmenwerk für die kennzahlengestützte Nutzenmessung von ECS dient und an dem Goal-Question-Metrics-Approach der NASA sowie der Balance Scorecard von Kaplan & Norton angelehnt ist. Die Ergebnisse tragen zu einem breiteren Verständnis der kennzahlenbasierten Nutzenanalyse für ECS in Organisationen bei. Das Benefits-SCoPE-Framework wurde in enger Zusammenarbeit mit Experten aus 16 Anwenderunternehmen im Rahmen der Initiative IndustryConnect entwickelt. In einem design-orientierten Ansatz wurde ein ausgewählter Methodenmix angewandt, inklusive Experteninterview, Fokusgruppe, Workshop und Card Sorting. Der von Anwenderunternehmen erwartete Nutzen des ECS wird in spezifische, durch Kennzahlen beantwortbare Fragestellungen umformuliert und fragmentiert. Insgesamt konnten so 313 nutzenorientierte Fragen von drei Anwenderunternehmen identifiziert werden. Die durchgeführte Kategorisierung der Fragen verdeutlicht zum einen das gemeinsame Verständnis der Unternehmen hinsichtlich der entscheidenden Faktoren für die Nutzenrealisierung von ECS und zum anderen die Nutzen-ziele, die die Unternehmen durch den Einsatz des ECS anvisieren. Die Entwicklung und Erhebung von Kennzahlen zur quantitativen Beantwortung von ausgewählten Fragestellungen wird mit funktions-fähigen Prototypen auf einer operativen Kollaborationsplattform demonstriert, die seit mehr als sieben Jahren im Einsatz ist und mehr als 5.000 registrierte Benutzer aufweist. Die Kennzahlenentwicklung, die Auswahl der Datenerhebungsmethode, die Durchführung der Messung sowie die Interpretation der Messergebnisse werden im Framework durch die Verwendung von Benefits Scorecards unterstützt. Die individuelle Orchestrierung mehrerer Benefits Scorecards repräsentiert die Struktur eines Ordnungssystems zur ECS-Nutzenanalyse in Anwenderunternehmen und verdeutlicht das Vorgehen zur Erhebung der äquivalenten Daten.

Currently, there are a variety of digital tools in the humanities, such as annotation, visualization, or analysis software, which support researchers in their work and offer them new opportunities to address different research questions. However, the use of these tools falls far short of expectations. In this thesis, twelve improvement measures are developed within the framework of a design science theory to counteract the lack of usage acceptance. By implementing the developed design science theory, software developers can increase the acceptance of their digital tools in the humanities context.

To render the surface of a material capable of withstanding mechanical and electrochemical loads, and to perform well in service, the deposition of a thin film or coating is a solution. In this project, such a thin film deposition is carried out. The coating material chosen is titanium nitride (TiN) which is a ceramic material known to possess a high hardness (>10 GPa) as well as good corrosion resistance. The method of deposition selected is high power impulse magnetron sputtering (HiPIMS) that results in coatings with high quality and enhanced properties. Sputtering is a physical process that represents the removal or dislodgment of surface atoms by energetic particle bombardment. The term magnetron indicates that a magnetic field is utilized to increase the efficiency of the sputtering process. In HiPIMS, a high power is applied in pulses of low duty cycles to a cathode that is sputtered and that consists of the coating material. As result of the high power, the ionization of the sputtered material takes place giving the possibility to control these species with electric and magnetic field allowing thereby the improvement and tuning of coating properties. However, the drawback of HiPIMS is a low deposition rate. In this project, it is demonstrated first that it is possible to deposit TiN coating using HiPIMS with an optimized deposition rate, by varying the magnetic field strength. It was found that low magnetic field strength (here 22mT) results in a deposition rate similar to that of conventional magnetron sputtering in which the average power is applied continuously, called also direct current magnetron sputtering (dcMS). The high deposition rate at low magnetic field strength was attributed to a reduction in the back attraction probability of the sputtered species. The magnetic field strength did not show noticeable influence on the mechanical properties. The proposed explanation was that the considered peak current density interval 1.22-1.72 A∙cm-2 does not exhibit dramatic changes in the plasma dynamics. In a second part, using the optimized deposition rate, the optimized chemical composition of TiN was determined. It was shown that the chemical composition of TiN does not significantly influence the corrosion performance but impacts considerably the mechanical properties. It was also shown that the corrosion resistance of the coatings deposited using HiPIMS was higher than that of the coatings deposited using dcMS. The third study was the effect of annealing post deposition on the properties of TiN coating deposited using HiPIMS. The hardness of the coatings showed a maximum at 400°C reaching 24.8 GPa. Above 400°C however, a lowering of the hardness was measured and was due to the oxidation of TiN which led to the formation of TiN-TiO2 composites with lower mechanical properties. The coating microscopic properties such as crystal orientation, residual stresses, average grain size were determined from X-ray diffraction data and the roughness was measured using atomic force microscopy. These properties were found to vary with the magnetic field strength, the chemical composition as well as the annealing temperature.

The present study deals with the synthesis of N-phenacylpyridinium salts and their use as photoinitiators for epoxy resins. The use and suitability of phenacyl salts as photoinitiators for epoxy resins has already been described in previous studies. The individual impact of the specific components on the rate constants of epoxy reaction has not been investigated in detail. Based on the structure of N-phenacylpyridinium salt the substances described in the present study were varied due to the exchange of counter ion and different substituents. Investigating the impact of the specific substituent with focus on the reaction of epoxy groups there is a dependence found for three main factors. First, depending on whether to use a phenyl or methyl group as substituent there was found an impact on the process of photolysis. Furthermore, concerning the dependences on the pyridine derivative and the counter ion, it was found that pyridine derivatives with electron withdrawing groups and counter ions, which can build strong acids, accelerate the rate constants of the epoxy reaction. Vice versa, pyridine derivatives with electron donating groups and counter ions, which can form weaker acids, decrease the rate constants. The determined rate constants and the formulation of substances discussed in the present thesis in an adhesive formulation show the suitability of selected substances as photoinitiators for the polymerization of epoxy resins.

Inland waters play an active role in the global carbon cycle. They collect carbon from upstream landmasses and transport it downstream until it finally reaches the ocean. Along this path, manifold processing steps are evident, resulting in (permanent) retention of carbon by sediment burial as well as loss by evasion to the atmosphere. Constraining these carbon fluxes and their anthropogenic perturbation is an urgent need. In this context, attention needs to be set on a widespread feature of inland waters: their partial desiccation. This results in the emergence of formerly inundated sediments to the atmosphere, referred to as dry inland waters. One observed feature of dry inland waters are disproportional high carbon dioxide (CO2) emissions. However, this observation was so far based on local case studies and knowledge on the global prevalence and fundamental mechanisms of these emissions is lacking. Against this background, this thesis aims to provide a better understanding of the magnitude and mechanisms of carbon emissions from dry inland waters on the global and local scale and to assess the impact of dry inland waters on the global carbon cycle. The specific research questions of this thesis were: (1) How do gaseous carbon emissions from dry inland waters integrate into the global carbon cycle and into global greenhouse gas (GHG) budgets? (2) What effect do seasonal and long term drying have on the carbon cycling of inland waters? The thesis revealed that dry inland waters emit disproportional large amounts of CO 2 on a global scale and that these emissions share common drivers across ecosystems. Quantifying global reservoir drawdown and upscaling carbon fluxes to the global scale suggests that reservoirs emit more carbon than they bury, challenging the current understanding of reservoirs as net carbon sinks. On the local scale, this thesis revealed that both, heterogeneous emission pattern between different habitats and seasonal variability of carbon emissions from the drawdown area, needs to be considered. Further, this thesis showed that re-mobilization of buried carbon upon permanent desiccation of water bodies can explain the observed emission rates, supporting the hypothesis of a positive feedback-loop between climate change and desiccation of inland waters. Overall, the present thesis highlights the importance of adding emissions from dry inland waters as a pathway to the global carbon cycle of inland waters.

Invasive species play increasing roles worldwide. Invasions are considered successful when species establish and spread in their exotic range. Subsequently, dispersal is a major determinant of species’ range dynamics. Mermessus trilobatus, native to North America, has rapidly spread in Europe via aerial dispersal. Here we investigated the interplay of ecological and evolutionary processes behind its colonisation success. First, we examined two possible ecological mechanisms. Similar to other invasive invertebrates, the colonisation success of Mermessus trilobatus might be related to human-induced habitat disturbance. Opposite to this expectation, our results showed that densities of Mermessus trilobatus decreased with soil disturbance in grasslands suggesting that its invasion success was not connected to a ruderal strategy. Further, invasive species often escape the ecological pressures from novel enemies in their exotic ranges. Unexpectedly, invasive Mermessus trilobatus was more sensitive to a native predator than native Erigone dentipalpis during our predator susceptibility trials. This indicates that the relation between the invasive spider and its native predator is dominated by prey naïveté rather than enemy release. The remaining three chapters of the thesis investigated the dispersal behaviour of this invasive species. Hitherto, studies of passive aerial dispersal used wind as the primary dispersal-initiating factor despite a recent demonstration of the effects of the atmospheric electric fields on spiders’ pre-dispersal behaviour. During our experiments, only the wind facilitated the flight, although electric fields induced pre-dispersal behaviour in spiders. Consequently, studies around passive aerial dispersal should control electric fields but use wind as a stimulating factor. Rapidly expanding species might be disproportionately distributed in their exotic range, with an accumulation of dispersive genotypes at the leading edge of their range. Such imbalanced spatial segregation is possible when the dispersal behaviour of expanding species is heritable. Our results showed that the dispersal traits of Mermessus trilobatus were heritable through both parents and for both sexes with recessive inheritance of high dispersal ability in this species. Following the heritability experiments, we documented an accelerated spread of Mermessus trilobatus in Europe and tested whether dispersal, reproduction or competing ability was at the source of this pattern. Our results showed that the accumulation of more mobile but not reproductive or competitive genotypes at the expansion front of this invasive species gave rise to an accelerated range expansion by more than 1350 km in under 45 years. Invasive Mermessus trilobatus is inferior to native sympatric species with respect to competing ability (Eichenberger et al., 2009), disturbance tolerance and predation pressure. Nevertheless, the species successfully established in its exotic range and spread by accelerating its expansion rate. Rapid reproduction that balances the high ecological pressures might be the other potential mechanism behind its colonisation success in Europe and deserves further investigation.

Agricultural intensification is leading to a severe decline in farmland biodiversity worldwide. The resulting landscape simplification through the expansion of monocultures and removal of non-crop habitats has a major impact on arthropod communities in agricultural landscapes. While arable fields are often highly disturbed and ephemeral habitats that are unsuitable for many species, non-crop habitats in agroecosystems can provide important refugia. The creation of non-crop habitats through agri-environmental schemes (AES) in intensive agricultural landscapes, such as the ‘Maifeld’ region in western Germany, is intended to mitigate the negative effects of agricultural intensification, although the effectiveness of these measures for nature conservation is still controversial. Therefore, this work focuses on the taxonomic and functional diversity of beetles (Coleoptera) and spiders (Araneida), being important providers of ecosystem services, between wheat fields and different non-crop habitats, namely grassy field margins adjacent to wheat and oilseed rape fields, small- and large-scale set-aside areas sown with wildflowers, and permanent grassland fallows. Arthropods were collected between 2019 and 2020 using pitfall traps and suction sampling. Land-use type influenced beetle and spider diversity in the study area, with significantly higher values in grassland fallows than wheat fields. Surprisingly, species diversity differed little among all non-crop habitats, but all harboured distinct species assemblages. In particular, large long-term grassland fallows showed the largest within-group variation of beetle and spider assemblages and represented important habitats, especially for habitat specialists and threatened species, likely due to their variable soil moisture and complex habitat structure. In contrast, the homogeneous arthropod assemblages of wheat fields exhibited lower trait richness and were dominated by a few predatory species adapted to such disturbed, man-made habitats. Interestingly, all conservation measures complemented each other in that they contributed in different ways to supporting beetles and spiders in agricultural landscapes. Even small-scale non-crop habitats and existing habitat boundaries in an agricultural matrix appear to be valuable habitats for farmland arthropods by enhancing taxonomic diversity. Field margins and small wildflower-sown patches can link isolated non-crop habitats and contribute to a heterogeneous agricultural landscape. Consequently, a combination of various small- and large-scale greening measures leads to increased compositional and configurational landscape heterogeneity, resulting in improved beetle and spider diversity. Considering the ongoing loss of farmland biodiversity worldwide, agri-environmental schemes should be promoted in the future, as they are particularly important for arthropod conservation in intensive agricultural landscapes such as the Maifeld region.

Agriculture requires a sustainable intensification to feed the growing world population without exacer-bating soil degradation and threatening soil quality. Globally, plastic mulching (PM) is increasingly used to improve crop growth and yields and consequently agronomic productivity. However, recent literature reported also critical aspects of PM for soil quality and showed contradictory outcomes. This might result from the numerous applications of PM in different climates across various crops, soils and agri-cultural techniques. Thus, a closer look is necessary on how PM influences soil processes under certain climate and cultivation conditions to obtain a comprehensive understanding of its effects, which is im-portant to evaluate PM in terms of a sustainable agriculture. The aim of this PhD thesis was to understand how multiannual PM influences soil properties and pro-cesses under the temperate, humid Central European cultivation conditions and to evaluate the resulting consequences for soil quality. I designed a three-year field study to investigate the influence of PM (black polyethylene, 50 μm) on microclimate, structural stability, soil organic matter (SOM) and the concentrations of selected fungicides and mycotoxins in three soil layers (0–10, 10–30 and 30–60 cm) compared to straw mulching (SM). Both mulching types were applied in a drip-irrigated ridge-furrow system in strawberry cultivation. PM shifted the soil microclimate to higher soil temperatures and lower soil moistures. The higher soil temperature seems thus to be the key factor for the increased crop growth and yields under the present humid climate. The reduced soil moisture under PM indicated that under PM the impeded rainfall infil-tration had a stronger effect on the water balance than the reduced evaporation. This indicate an ineffi-cient rainwater use in contrast to arid climates. PM changed the water cycling in the ridges from down-ward directed water flows to lateral water flows from furrows to ridges. This reduced nitrogen leaching in the topsoil (0–10 cm) in the strawberry establishment period. The plastic mulches avoided aggregate breakdown due to rapid soil wetting and excess water during rainfalls and thus maintained a loose and stable soil structure in the surface soil, which prevents soil compaction and made soil less prone to erosion. PM changed carbon fluxes and transformation so that a larger total and more stable SOM was observed. Thus, the higher belowground biomass productivity under PM compensated the impeded aboveground biomass input and the temperature-induced SOM decomposition. However, SM increased the labile and total SOM in the topsoil after the first experiment year and promoted microbial growth due to the aboveground biomass incorporation. PM reduced fungicide entry into soil compared to SM and reduced consequently the fungal biomass reduction and the biosynthesis of the mycotoxin deoxyni-valenol. The modified microclimate under PM did not increase mycotoxin occurrence. In this context, PM poses no risk for an increased soil contamination, impairing soil quality. This PhD thesis demon-strated that the PM effects on soil can vary depending on time, season and soil depth, which emphasizes the importance to include soil depth and time in future studies. Compared to semiarid and arid regions, the PM effects found in this PhD thesis were small, absent or in another way. I attributed this to the fact that PM under humid climate reduced instead of increased soil moisture and that SM had due to straw und strawberry canopy a similar ‘covering effect’ as PM. Thus, generalizing the PM effects on soil across different climates seems hardly possible as they differ in type and extent depending on climate. A differentiated consideration is hence necessary to evaluate the PM effects on soil quality. I conclude that PM under temperate, humid climate might contribute to reduce soil degradation (e.g., SOM depletion, erosion, nutrient leaching, soil compaction and soil contamina-tion), which sustains soil quality and helps to enable a sustainable agricultural intensification. However, further research is necessary (1) to support my findings on a larger scale, longer time periods and across various soil and crop types, (2) to address remaining open questions and (3) to develop optimization to overcome the critical aspects of PM (e.g. macro- and microplastic waste in soil, mulch disposal).

Over the past few decades, Single-Particle Analysis (SPA), in combination with cryo-transmission electron microscopy, has evolved into one of the leading technologies for structural analysis of biological macromolecules. It allows the investigation of biological structures in a close to native state at the molecular level. Within the last five years the achievable resolution of SPA surpassed 2°A and is now approaching atomic resolution, which so far has only been possible with Xray crystallography in a far from native environment. One remaining problem of Cryo-Electron Microscopy (cryo-EM) is the weak image contrast. Since the introduction of cryo-EM in the 1980s phase plates have been investigated as a potential tool to overcome these contrast limitations. Until now, technical problems and instrumental deficiencies have made the use of phase plates difficult; an automated workflow, crucial for the acquisition of 1000s of micrographs needed for SPA, was not possible. In this thesis, a new Zernike-type Phase Plate (PP) was developed and investigated. Freestanding metal films were used as a PP material to overcome the ageing and contamination problems of standard carbon-based PPs. Several experiments, evaluating and testing various metals, ended with iridium as the best-suited material. A thorough investigation of the properties of iridium PP followed in the second part of this thesis. One key outcome is a new operation mode, the rocking PP. By using this rocking-mode, fringing artifacts, another obstacle of Zernike PPs, could be solved. In the last part of this work, acquisition and reconstruction of SPA data of apoferritin was performed using the iridium PP in rocking-mode. A special semi-automated workflow for the acquisition of PP data was developed and tested. The recorded PP data was compared to an additional reference dataset without a PP, acquired following a conventional workflow.

The Web is an essential component of moving our society to the digital age. We use it for communication, shopping, and doing our work. Most user interaction in the Web happens with Web page interfaces. Thus, the usability and accessibility of Web page interfaces are relevant areas of research to make the Web more useful. Eye tracking is a tool that can be helpful in both areas, performing usability testing and improving accessibility. It can be used to understand users' attention on Web pages and to support usability experts in their decision-making process. Moreover, eye tracking can be used as an input method to control an interface. This is especially useful for people with motor impairment, who cannot use traditional input devices like mouse and keyboard. However, interfaces on Web pages become more and more complex due to dynamics, i.e., changing contents like animated menus and photo carousels. We need general approaches to comprehend dynamics on Web pages, allowing for efficient usability analysis and enjoyable interaction with eye tracking. In the first part of this thesis, we report our work on improving gaze-based analysis of dynamic Web pages. Eye tracking can be used to collect the gaze signals of users, who browse a Web site and its pages. The gaze signals show a usability expert what parts in the Web page interface have been read, glanced at, or skipped. The aggregation of gaze signals allows a usability expert insight into the users' attention on a high-level, before looking into individual behavior. For this, all gaze signals must be aligned to the interface as experienced by the users. However, the user experience is heavily influenced by changing contents, as these may cover a substantial portion of the screen. We delineate unique states in Web page interfaces including changing contents, such that gaze signals from multiple users can be aggregated correctly. In the second part of this thesis, we report our work on improving the gaze-based interaction with dynamic Web pages. Eye tracking can be used to retrieve gaze signals while a user operates a computer. The gaze signals may be interpreted as input controlling an interface. Nowadays, eye tracking as an input method is mostly used to emulate mouse and keyboard functionality, hindering an enjoyable user experience. There exist a few Web browser prototypes that directly interpret gaze signals for control, but they do not work on dynamic Web pages. We have developed a method to extract interaction elements like hyperlinks and text inputs efficiently on Web pages, including changing contents. We adapt the interaction with those elements for eye tracking as the input method, such that a user can conveniently browse the Web hands-free. Both parts of this thesis conclude with user-centered evaluations of our methods, assessing the improvements in the user experience for usability experts and people with motor impairment, respectively.

As a consequence of the world population increase and the resulting water scarcity, water quality is the object of growing attention. In that context, organic anthropogenic molecules — often defined as micropollutants— represent a threat for water resources. Among them, pharmaceuticals are the object of particular concerns due to their permanent discharge, their increasing consumption and their effect-based structures. Pharmaceuticals are mainly introduced in the environment via wastewater treatment plants (WWTPs), along with their metabolites and the on-site formed transformation products (TPs). Once in the aquatic environment, they partition between the different environmental compartments in particular the aqueous phase, suspended particulate matter(SPM) and biota. In the last decades, pharmaceuticals have been widely investigated in the water phase. However, extreme polar pharmaceuticals have rarely been monitored due to the lack of robust analytical methods. Moreover, metabolites and TPs have seldom been included in routine analysis methods although their environmental relevance is proven. Furthermore, pharmaceuticals have been only sporadically investigated in SPM and biota and adequate multi-residue methods are lacking to obtain comprehensive results about their occurrence in these matrices. This thesis endeavors to cover these gaps of knowledge by the development of generic multi-residue methods for pharmaceuticals determination in the water phase, SPM and biota and to evaluate the occurrence and partition of pharmaceuticals into these compartments. For a complete overview, a particular focus was laid on extreme polar pharmaceuticals, pharmaceutical metabolites and TPs. In total, three innovative multi-residue methods were developed, they include analytes covering a broad range of physico-chemical properties. First, a reliable multi-residue method was developed for the analysis of extreme polar pharmaceuticals, metabolites and TPs dissolved in water. The selected analytes covered a significant range of elevated polarity and the method would be easily expendable to further analytes. This versatility could be achieved by the utilization of freeze-drying as sample preparation and zwitterionic hydrophilic interaction liquid chromatography (HILIC) in gradient elution mode. The suitability of HILIC chromatography to simultaneously quantify a large range of micropollutants in aqueous environmental samples was thoroughly studied. Several limitations were pointed out: a very complex and time-consuming method development, a very high sensitivity with regards to modification of the acetonitrile to water ratio in the eluent or the diluent and high positive matrix effects for certain analytes. However, these limitations can be overcome by the utilization of a precise protocol and appropriate labeled internal standards. They are overmatched by the benefits of HILIC which permits the chromatographic separation of extreme polar micropollutants. Investigation of environmental samples showed elevated concentrations of the analytes in the water phase. In particular, gabapentin, metformin, guanylurea and oxypurinol were measured at concentrations in the µg/L range in surface water. Subsequently, a reliable multi-residue method was established for the determination of 57 pharmaceuticals, 47 metabolites and TPs sorbed to SPM down to the low ng/g range. This method was conceived to cover a large range of polarity in particular with the inclusion of extreme polar pharmaceuticals. The extraction procedure was based on pressurized liquid extraction (PLE) followed by a clean-up via solvent exchange and detection via direct injection-reversed-phase LC-MS/MS and freeze-drying HILIC-MS/MS. Pharmaceutical sorption was examined using laboratory experiments. Derived distribution coefficients Kd varied by five orders of magnitude among the analytes and confirmed a high sorption potential for positively charged and nonpolar pharmaceuticals. The occurrence of pharmaceuticals in German rivers SPM was evaluated by the investigation of annual composite SPM samples taken at four sites at the river Rhine and one site at the river Saar between the years 2005 and 2015. It revealed the ubiquitous presence of pharmaceuticals sorbed to SPM in these rivers. In particular, positively charged analytes, even very polar and nonpolar pharmaceuticals showed appreciable concentrations. For many pharmaceuticals, a distinct correlation was observed between the annual quantities consumed in Germany and the concentrations measured in SPM. Studies of composite SPM spatial distribution permitted to get hints about specific industrial discharge by comparing the pollution pattern along the river. For the first time, these results showed the potential of SPM for the monitoring of positively charged and nonpolar pharmaceuticals in surface water. Finally, a reliable and generic multi residue method was developed to investigate 35 pharmaceuticals and 28 metabolites and TPs in fish plasma, fish liver and fish fillet. For this matrix, it was very challenging to develop an adequate clean-up allowing for the sufficient separation of the matrix disturbances from the analytes. In the final method, fish tissue extraction was performed by cell disruption followed by a non-discriminating clean-up based on silica gel solid-phase extraction(SPE) and restrictive access media (RAM) chromatography. Application of the developed method to the measurement of bream and carp tissues from German rivers revealed that even polar micropollutants such as pharmaceuticals are ubiquitously present in fish tissues. In total, 17 analytes were detected for the first time in fish tissues, including 10 metabolites/TPs. The importance of monitoring metabolites and TPs in fish tissues was confirmed with their detection at similar concentrations as their parents. Liver and fillet were shown to be appropriate for the monitoring of pharmaceuticals in fish, whereas plasma is more inconvenient due to very low concentrations and collection difficulties. Elevated concentrations of certain metabolites suggest possible formation of human metabolites in fish. Measured concentrations indicate a low bioaccumulation potential for pharmaceuticals in fish tissues.

In dieser vergleichenden Untersuchung werden die Philosophien David Humes und John Deweys gegenübergestellt. Es werden sämtliche philosophischen und wissenschaftlichen Disziplinen, denen sich beide Denker gewidmet haben, einbezogen: Anthropologie, Bewusstseinstheorie, Psychologie, Erkenntnistheorie, Ethik (Moralphilosophie), Politik, Ökonomie, Soziologie, Sozialphilosophie, Geschichtswissenschaft und Religionswissenschaft. Dabei wird thesengeleitet vorgegangen. - Pragmatismus-These: David Hume sei Pragmatist avant la lettre gewesen. - Begriffs-These: Begriffe (hier etwa nature und experience) seien breit genug zu fassen, um mit ihnen zielführend zu operieren. - Quasi-System-These: Die Vielfalt der philosophischen und wissenschaftlichen Disziplinen, mit denen sich beide Denker befassten, bilde jeweils ein System, ohne als solches angelegt worden zu sein. - Klassik-These: Es sei ergiebig, sich mit Philosophen zu beschäftigen, die bislang noch nicht oder kaum verglichen wurden, da es neben Entsprechungen, Ähnlichkeiten und Weiterentwicklungsmöglichkeiten auch Lerneffekte aus Überwindungen und Differenzen gebe. - Instrumentalismus-These: Deweys Philosophie sei dem Streben nach Lösungen für das praktische soziale Zusammenleben dienlich. Benannte Disziplinen werden einzeln in der folgenden Reihenfolge behandelt: 1) David Humes Gedanken 2) John Deweys Gedanken 3) Prüfung, inwieweit sich Dewey auf Hume direkt oder indirekt bezog 4) Verbindungslinien zwischen den Gedanken beider Philosophen Diesen Untersuchungsschwerpunkten werden vorgelagert bzw. beigestellt: - Ausführliche Begriffsarbeit, insbesondere zu den „Ismen“, welche man beiden Denkern zurechnet: Empirismus, Pragmatismus/Pragmatiszismus, Skeptizismus, Naturalismus. Der Verfasser geht dabei auch Bezüge dieser Ismen untereinander ein. - Die Philosophie William James‘ als eventueller Verbindung zwischen Hume und Dewey - Der Darwinismus als möglicher missing link zwischen beiden Denkern - Die Thematik Willensfreiheit/Determinismus als Scharnierstelle zwischen theoretischer und praktischer Philosophie Als Hauptsäulen seiner Untersuchung arbeitet der Verfasser folgende Konzeptionen heraus. - Den „pragmatistic turn“, mit dem der Verfasser aussagt, dass Hume durch die unterschiedliche Behandlung seiner skeptischen Denkergebnisse in seinen Hauptwerken Treatise und Enquiry Pragmatist avant la lettre gewesen sei - Die Idee des „Instrumentalismus zu einem höheren Zweck“, gemäß dem Dewey (und im Effekt auch Hume) zwar instrumentalistisch operierte (was ihm u. a. von Horkheimer vorgeworfen wurde), diesen Instrumentalismus selbst aber dem höheren Zweck der sozialen Gemeinschaft untergeordnet habe. Als Nebenergebnisse der Arbeit (neben der systematischen Prüfung der Thesen in allen benannten Disziplinen) entstanden Reflexionen über - Kreativität - Kommunikation - Kultur - Natur - Meliorismus, Kommunitarismus und Voluntarismus - Die Stellung der Philosophie in Bezug zu geistes-, natur- und Sozialwissenschaften - Rekonstruktion, jeweils in Bezug zum Werk beider Denker. Darüber hinaus werden die Biographien beider als „Faktor Existenz und Authentizität“ mit Blick auf die jeweilige Entsprechung zwischen Leben und Werk ausgewertet. Die vorliegende Arbeit umfasst die Auswertung des jeweils umfangreichen Gesamtwerkes sowohl von Hume als auch von Dewey und bezieht den aktuellen Stand der Sekundärliteratur mit ein. Die bisherige Forschungslage zu einem Vergleich zwischen den beiden Philosophen ist sehr spärlich; diese Arbeit ist in diesem Sinne innovativ im Themenbezug. Ergebnis der Untersuchung ist, dass in nicht wenigen Teilbereichen große Entsprechungen beider Philosophien vorhanden sind. Aber auch durch Unterschiede und bislang nicht weiterverfolgte Interpretationsansätze werden mögliche Denklinien in der Bewertung beider Philosophien und in der Betrachtung des Bezugs zwischen klassischem Empirismus und dem Pragmatismus sichtbar gemacht.