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How does gameplay influence the fun in video games? This article will search for an answer to this question by using a self-made video game created from scratch. This video game will be programmed in two versions with differences only in gameplay. Several test persons are then to play this game. A survey will be answered afterwards. In order to gain values that are merely influenced by gameplay changes, thoughts on the game design and conception were made. Results suggest that gameplay has a big impact on fun in video games. But gameplay isn't the only responsible factor that makes a video game amusing. Psychological aspects are present when the gameplay of a video game changes.
The present thesis gives an overview of the general conditions for the programming of graphics cards. For this purpose, the most important Application Programming Interfaces (APIs) available on the market are presented and compared. Subsequently, two standard algorithms from the field data processing, prefix sum and radixsort are presented and examined with regard to the implementation with parallel programming on the GPU. Both algorithms were implemented using the OpenGL-API and OpenGL compute shaders. Finally, the execution times of the two algorithms were compared.
Topic models are a popular tool to extract concepts of large text corpora. These text corpora tend to contain hidden meta groups. The size relation of these groups is frequently imbalanced. Their presence is often ignored when applying a topic model. Therefore, this thesis explores the influence of such imbalanced corpora on topic models.
The influence is tested by training LDA on samples with varying size relations. The samples are generated from data sets containing a large group differences i.e language difference and small group differences i.e. political orientation. The predictive performance on those imbalanced corpora is judged using perplexity.
The experiments show that the presence of groups in training corpora can influence the prediction performance of LDA. The impact varies due to various factors, including language-specific perplexity scores. The group-related prediction performance changes for groups when varying the relative group sizes. The actual change varies between data sets.
LDA is able to distinguish between different latent groups in document corpora if differences between groups are large enough, e.g. for groups with different languages. The proportion of group-specific topics is under-proportional to the share of the group in the corpus and relatively smaller for minorities.
Organic substances play an essential role for the formation of stable soil structures. In this context, their physico-chemical properties, interactions with mineral soil constituents and soil-water interactions are particu-larly important. However, the underlying mechanisms contributing to soil particle cementation by swollen or-ganic substances (hydrogels) remains unclear. Up to now, no mechanistic model is available which explains the mechanisms of interparticulate hydrogel swelling and its contribution to soil-water interactions and soil structur-al stability. This mainly results from the lack of appropriate testing methods to study hydrogel swelling in soil as well as from the difficulties of adapting available methods to the system soil/hydrogel.
In this thesis, 1H proton nuclear magnetic resonance (NMR) relaxometry was combined with various soil micro- and macrostructural stability testing methods in order to identify the contribution of hydrogel swelling-induced soil-water interactions to the structural stability of water-saturated and unsaturated soils. In the first part, the potentials and limitations of 1H NMR relaxometry to enlighten soil structural stabilization mechanism and vari-ous water populations were investigated. In the second part, 1H-NMR relaxometry was combined with rheologi-cal measurements of soil to assess the contribution of interparticulate hydrogel swelling and various polymer-clay interactions on soil-water interactions and soil structural stability in an isolated manner. Finally, the effects of various organic and mineral soil fractions on soil-water interactions and soil structural stability was assessed in more detail for a natural, agriculturally cultivated soil by soil density fractionation and on the basis of the experiences gained from the previous experiments.
The increased experiment complexity in the course of this thesis enabled to link physico-chemical properties of interparticulate hydrogel structures with soil structural stability on various scales. The established mechanistic model explains the contribution of interparticulate hydrogels to the structural stability of water-saturated and unsaturated soils: While swollen clay particles reduce soil structural stability by acting as lubricant between soil particles, interparticulate hydrogel structures increase soil structural stability by forming a flexible polymeric network which interconnects mineral particles more effectively than soil pore- or capillary water. It was appar-ent that soil structural stability increases with increasing viscosity of the interparticluate hydrogel in dependence on incubation time, soil texture, soil solution composition and external factors in terms of moisture dynamics and agricultural management practices. The stabilizing effect of interparticulate hydrogel structures further in-crease in the presence of clay particles which is attributed to additional polymer-clay interactions and the incor-poration of clay particles into the three-dimensional interparticulate hydrogel network. Furthermore, the simul-taneous swelling of clay particles and hydrogel structures results in the competition for water and thus in a mu-tual restriction of their swelling in the interparticle space. Thus, polymer-clay interactions not only increase the viscosity of the interparticulate hydrogel and thus its ability to stabilize soil structures but further reduce the swelling of clay particles and consequently their negative effects on soil structural stability. The knowledge on these underlying mechanisms enhance the knowledge on the formation of stable soil structures and enable to take appropriate management practices in order to maintain a sustainable soil structure. The additionally out-lined limitations and challenges of the mechanistic model should provide information on areas with optimization and research potential, respectively.
Entrepreneurship plays a vital role in scientific literature and in public debates. Especially in these hightech and digitized times it happens more and more frequently that young entrepreneurs with a good idea make the breakthrough and set up an established company. Basically, there are an increasing number of start-ups and a trend towards independence. The economy of a country depends on young entrepreneurs in order to remain economically competitive in international competition. It follows that young entrepreneurs must be encouraged and supported. This support is expressed in various stages of foundation and through various fields of action. In the meantime, there are many offers for start-up support. These networks satisfy different fields of action along a foundation. However, a structured overview of these networks on which a young founder can orient himself and gain easily access to the offers of the networks, is missing until then.
This work attempts to present these offers clearly on a map and to categorize and present the commitment in the respective fields of action. In addition to this main objective, the following three key questions are investigated and answered in this work:
1. How can the Entrepreneurship Networks be assigned to the respective fields of action of Entrepreneurship Education?
2. What is the benefit of such a classification for potential entrepreneurs in detail?
3. Are these Entrepreneurship networks missing an important step? Might they improve their offer? Does the value chain cover every need a young entrepreneur might have?
For this purpose, the respective fields of action of the networks are first separated from each other along a founding and defined individually. Subsequently, a combination of quantitative and qualitative approaches was used to filter and analyze the contents of the websites of the networks. The results of this investigation were transformed in a classification
The aim of this work is to produce a map that displays the existing networks in the world clearly. The map also contains information that is more detailed and the classifica-tion of the networks in the respective fields of action.
Different techniques (weight loss, electrochemical, and spray
corrosion measurements) have been used to evaluate four sarcosine derivatives to inhibit corrosion and one commercial compound as synergist. The basic metal was low carbon steel CR4 tested at different conditions. As working media mainly neutral water and 0.1 M NaCl was applied. The protective film was formed on the steel surface via direct absorption of the tested substances during the immersion process. A highly improved corrosion protection with direct correlation to the molecular weight and carbon chain length of the tested compounds was detected. The protection of steel CR4 against corrosion in 0.1 M NaCl enhanced with increasing concentration of selected sarcosine compounds. The best inhibitor throughout all tested concentrations and all evaluation systems was Oleoylsarcosine (O) with efficiencies up to 97 % in potentiodynamic polarization (PP), 83 % electrochemical impedance spectroscopy (EIS), and 85 % weight loss (WL) at 100 mmol/L as highest concentration tested here. The second best inhibitor was Myristoylsarcosine (M) with efficiencies up to 82 % in PP, 69 % in EIS, and 75 % in WL at highest concentration. The inhibitor with the shortest hydrocarbon chain in this series is Lauroylsarcosine (L). It showed lowest effects to inhibit corrosion compared to O and M. The efficiencies of L were a bit more than 50 % at 75 and 100 mmol/L and less than 50 % at 25 and 50 mmol/L in all used evaluation systems. Furthermore, the overall efficiency is promoted with longer dip coating times during the steel CR4 immersion as shown for 50 mmol/L for all present derivatives. This survey indicated 10 min as best time in respect of cost and protection efficiency. The commercial inhibitor Oley-Imidazole (OI) improved significantly the effectiveness of compound Cocoylsarcosine (C), which contains the naturally mixture of carbon chain lengths from coconut oil (C8 - C18), and enhanced protection when used in combination (C+OI, 1:1 molar ration). In this system the efficiency increased from 47 % to 91 % in PP, from 40 % to 84 % in EIS, and from 45 % to 82 % in WL at highest concentration. Spray corrosion tests were used to evaluate all present sarcosine substances on steel CR4 in a more realistic system. The best inhibitor after a 24 h test was O followed by the combination C+OI and M with efficiencies up to 99 %, 80 %, and 79 %, respectively. The obtained results indicate a good stability of the protective film formed by the present inhibitors even after 24 h. All evaluation systems used in the current investigation were in good agreement and resulted in the same inhibitor sequence. Furthermore, the adsorption process of the tested compounds is assumed to follow the Langmuir type isotherm. Response surface methodology (RSM) is an optimization method depending on Box- Behnken Design (BBD). It was used in the current system to find the optimum efficiency for inhibitor O to protect steel CR4 against corrosion in salt water. Four independent variables were used here: inhibitor concentration (A), dip coating time (B), temperature (C), and NaCl concentration (D); each with three respective levels: lower (-1), mid (0), and upper (+1). According to the present result, temperature has the greatest effect on the protection process as individual parameter followed by the inhibitor concentration itself. In this investigation an optimum efficiency of 99 % is calculated by the following parameter and level combination: upper level (+1) for inhibitor concentration, dip coating time, and NaCl concentration while lower level (-1) for temperature.
This Master Thesis is an exploratory research to determine whether it is feasible to construct a subjectivity lexicon using Wikipedia. The key hypothesis is that that all quotes in Wikipedia are subjective and all regular text are objective. The degree of subjectivity of a word, also known as ''Quote Score'' is determined based on the ratio of word frequency in quotations to its frequency outside quotations. The proportion of words in the English Wikipedia which are within quotations is found to be much smaller as compared to those which are not in quotes, resulting in a right-skewed distribution and low mean value of Quote Scores.
The methodology used to generate the subjectivity lexicon from text corpus in English Wikipedia is designed in such a way that it can be scaled and reused to produce similar subjectivity lexica of other languages. This is achieved by abstaining from domain and language-specific methods, apart from using only readily-available English dictionary packages to detect and exclude stopwords and non-English words in the Wikipedia text corpus.
The subjectivity lexicon generated from English Wikipedia is compared against other lexica; namely MPQA and SentiWordNet. It is found that words which are strongly subjective tend to have high Quote Scores in the subjectivity lexicon generated from English Wikipedia. There is a large observable difference between distribution of Quote Scores for words classified as strongly subjective versus distribution of Quote Scores for words classified as weakly subjective and objective. However, weakly subjective and objective words cannot be differentiated clearly based on Quote Score. In addition to that, a questionnaire is commissioned as an exploratory approach to investigate whether subjectivity lexicon generated from Wikipedia could be used to extend the coverage of words of existing lexica.