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Aktuelle Schätzungen bestätigten, dass Binnengewässer eine erhebliche Menge Methan (CH4) und Kohlendioxid (CO2) sowohl auf regionaler Ebene, als auch global freisetzen. Jedoch basieren diese Schätzungen auf extrapolierten gemessenen Daten, ungenügender Auflösung der räumlich-zeitlichen Variabilität und es mangelt an Daten aus ariden und semi-ariden Gebieten, sowie den Kohlestoffquellen aus Kläranlagen.
Für die hier vorliegende Studie analysierten wir monatliche hydrologische und meteorologische Daten sowie Daten zur Wasserqualität von drei Stauseen aus dem Gebiet des unteren Jordans, die zur Trinkwassergewinnung und zur Bewässerung genutzt werden, und schätzten damit deren Emissionsrate an CO2 ab. Wir untersuchten den Effekt von Kläranlagen auf die umliegenden Gewässer im Hinblick auf CH4 und CO2-Emissionen indem wir saisonal aufgelöste Daten der Konzentration der beiden gelösten Gase in Kläranlagenauslässen und in Vorflutern von neun Kläranlagen in Deutschland analysierten. Mithilfe von Low-Cost-Methoden die die CO2-Transportrate und die Ausgasungsrate über Gasblasen messen, untersuchten wir die räumliche und zeitliche Variabilität der CH4 und CO2-Emissionen von aquatischen Süßwasser-Ökosystemen.
Unsere Schätzungen zeigen, dass Stauseen in semi-ariden Regionen CO2 übersättigt sind und somit CO2 an die Atmosphäre abgeben, also eine Netto-Quelle sind.
Die Größenordnung der beobachteten Transportraten der drei jordanischen Stauseen ist vergleichbar mit denen von tropischen Stauseen (3,3 g CO2 m-2 Tag-1). Die CO2-Emissionsrate ist abhängig von Änderungen der Wasseroberfläche, welche durch den Betrieb der Stauseen verursacht sind. Kläranlagen entlassen eine beachtlichen Menge an CH4 (30.9±40.7 kg Jahr-1) und CO2 (0.06±0.05 Gg Jahr-1) in ihre umgebenden Flüsse und Bäche. Deren Emissionsraten sind durch diese Einleitung der Kläranlagen um 1,2-fach für CH4 oder 8,6-fach für CO2 erhöht. Unsere Ergebnisse zeigen, dass sowohl die diffusive als auch die Gasblasenemissionsrate räumlich und zeitlich variabel ist, weshalb beide Emissionsraten bei zukünftigen Studien auch in der nötigen Auflösung gemessen werden sollten.
Wir schlussfolgern, dass bei zukünftigen Emissionsmessungen und –schätzungen von Binnengewässern auch die Gewässerbewirtschaftung, die Kohlenstoffquelle von Kläranlagen und die räumliche und zeitliche Variabilität der Emissionen beachtet werden sollten.
The application of pesticides to agricultural areas can result in transport to adjacent non-target environments. In particular, surface water systems are likely to receive agricultural pesticide input. When pesticides enter aquatic environments, they may pose a substantial threat to the ecological integrity of surface water systems. To minimize the risk to non-target ecosystems the European Union prescribes an ecotoxicological risk assessment within the registration procedure of pesticides, which consists of an effect and an exposure assessment.
This thesis focuses on the evaluation of the exposure assessment and the implications to the complete regulatory risk assessment, and is based on four scientific publications. The main part of the thesis focuses on evaluation of the FOCUS modelling approach, which is used in regulatory risk assessment to predict pesticide surface water concentrations. This was done by comparing measured field concentrations (MFC) of agricultural insecticides (n = 466) and fungicides (n = 417) in surface water to respective predicted environmental concentrations (PEC) calculated with FOCUS step 1 to step 4 at two different levels of field relevance. MFCs were extracted from the scientific literature and were measured in field studies conducted primarily in Europe (publications 1 and 3).
In addition, an alternative fugacity-based multimedia mass-balance model, which needs fewer input parameters and less computing effort, was used to calculate PECs for the same insecticide MFC dataset and compared to the FOCUS predictions (publication 3). Furthermore, FOCUS predictions were also conducted for veterinary pharmaceuticals in runoff from an experimental plot study, to assess the FOCUS predictions for a different class of chemicals with a different relevant entry pathway (publication 2).
In publication 4, the FOCUS step-3 approach was used to determine relevant insecticide exposure patterns. These patterns were analysed for different monitoring strategies and the implications for the environmental risk assessment (publication 4).
The outcome of this thesis showed that the FOCUS modelling approach is neither protective nor appropriate in predicting insecticide and fungicide field concentrations. Up to one third of the MFCs were underpredicted by the model calculations, which means that the actual risk might be underestimated. Furthermore, the results show that a higher degree of realism even reduces the protectiveness of model results and that the model predictions are worse for highly hydrophobic and toxic pyrethroids.
In addition, the absence of any relationship between measured and predicted concentrations questions the general model performance quality (publication 1 and 3). Further analyses revealed that deficiencies in protectiveness and predictiveness of the environmental exposure assessment might even be higher than shown in this thesis, because actual short-term peak concentrations are only detectable with an event-related sampling strategy (publication 4). However, it was shown that the PECs of a much simpler modelling approach are much more appropriate for the prediction of insecticide MFC, especially for calculations with a higher field relevance (publication 3). The FOCUS approach also failed to predict concentrations of veterinary pharmaceuticals in runoff water (publication 2). In conclusion, the findings of this thesis showed that there is an urgent need for the improvement of exposure predictions conducted in the environmental risk assessment of pesticides as a group of highly relevant environmental chemicals, to ensure that the increasing use of those chemicals does not lead to further harmful effects in aquatic ecosystems.
Die vorliegende Arbeit behandelt Techniken zur interakativen und physikalisch basierten Darstellung von Haaren für Computer-Generated Imagery (CGI). Dafür werden Techniken zur Simulation und Approximierung der Interaktionen von Licht mit Haar hergeleitet und vorgestellt. Des Weiteren wird beschrieben, wie Haare, trotz solch berechnungsintensiver Algorithmen, sehr interaktiv dargestellt werden können. Verfahren zur Berechnung von Schatten in Haaren sowie Ansätze zur effizienten Darstellung von Haar als transparente Geometrie werden ebenfalls vorgestellt. Einen Hauptschwerpunkt der Arbeit bildet dabei der DBK-Buffer, welcher im Rahmen dieser konzeptioniert, implementiert und evaluiert wurde. Mit Hilfe des DBK-Buffers ist es möglich tausende von transparenten Haaren sehr effizient darzustellen ohne auf Funktionalitäten der neusten Grafikkarten-Generation, oder sehr viel Videospeicher, angewiesen zu sein. Darüber hinaus wurde eine umfassende Evaluierung der beschriebenden Techniken bezüglich der visuellen Qualität, der Performanz und des Speicheraufwandes durchgeführt. Dabei wurde gezeigt, dass Haare nicht nur mit interaktiven, sondern sogar mit echtzeitfähigen Bildwiederholungsraten physikalisch basiert dargestellt werden können.
“Did I say something wrong?” A word-level analysis of Wikipedia articles for deletion discussions
(2016)
Diese Arbeit beschäftigt sich damit, linguistische Erkenntnisse auf Wortebene über schriftlichen Diskussionen zu gewinnen. Die Unterscheidung zwischen Botschaften, welche sich förderlich auf Diskussionen auswirken und jene, welche diese unterbrechen, spielte dabei eine besondere Rolle. Hierbei lag ein Schwerpunkt darauf, zu ermitteln, ob Ich- und Du-Botschaften charakteristisch für die beiden Kommunikationsarten sind. Diese Botschaften sind über Jahre hinweg zu Empfehlungen für erfolgreiche Kommunikation avanciert. Ihre zugeschriebene Wirkung wurde zwar mehrfach bestätigt, jedoch geschah dies stets in kleineren Studien. Deshalb wurde in dieser Arbeit mithilfe der Löschdiskussionen der englischen Wikipedia und der Liste gesperrter Nutzer eine vollautomatische Erstellung eines annotierten Datensatzes entwickelt. Dabei wurden Diskussionsbotschaften entweder als förderlich oder schädlich für einen konstruktiven Diskussionsverlauf markiert. Dieser Datensatz wurde anschließend im Rahmen einer binären Klassifikation verwendet, um charakteristische Worte für die beiden Kommunikationsarten zu bestimmen. Es wurde zudem untersucht, ob anhand von Synsemantika (auch bekannt als Funktionswörter) wie Pronomen oder Konjunktionen eine Entscheidung über die Kommunikationsart einer Botschaft getroffen werden kann. Du-Botschaften wurden, übereinstimmend mit ihrer zugeschriebenen negativen Auswirkung auf Kommunikation, als schädlich in den durchgeführten Untersuchungen identifiziert. Entgegen der zugeschriebenen positiven Auswirkung von Ich-Botschaften, wurde bei diesen ebenfalls eine schädlich Wirkung festgestellt. Eine klare Aussage über die Relevanz von Synsemantika konnte anhand der Ergebnisse nicht getroffen werden. Weitere charakteristische Worte konnten nicht festgestellt werden. Die Ergebnisse deuten darauf hin, dass ein anderes Modell textliche Diskussionen potentiell besser abbilden könnte.
How entrepreneurs become successful with their business ideas has been a topic of discussion within entrepreneurial research circles for many years. Business success has been related to psychological characteristics and many research findings have explained how people become entrepreneurs and furthermore, how they find success in regards to their business ventures. People always wanted to know what defines an entrepreneur and more importantly, what is needed to become a successful entrepreneur. Curious minds began to search for the recipe for success. Personality Traits have been researched for years, leading to the discovery of many diverse and distinct forms which are still recognized today. Researchers compared the Behavioral Approach or the analysis of demographical characteristics to success.
This raises the question of what an entrepreneur needs to become successful which is made more difficult due to the fact that entrepreneurship and who an entrepreneur is can be difficult do define exactly. Entrepreneurs are diverse and distinct individuals that each possess their own characteristics, behavior and reasons for starting a business. Many people assume that it is just someone who starts their own business. While partially correct, this only scratches the surface of what it is to be an entrepreneur.
This thesis answers the following three research questions: 1. Which personality traits were found in the almost sixty years of researching? 2. What triggers do entrepreneurs need for starting a new business? 3. Which factor makes the entrepreneur successful with their business idea? Also, reading the thesis, one may gain a better understanding of what entrepreneurship is, what defines an entrepreneur and what one needs to become a successful entrepreneur.
In this thesis the reviewing literature method developed by Wolfswinkel et al. (2011) was used to identify suitable literature and references for the main chapters. For that the five stages of the grounded-theory method for reviewing the literature were used in an iterative fashion. In step one inclusion and exclusion criterias for literature were defined. Then literature was searched matching the criterias of step one. In step three the samples were refined. Then in step four the found literature was analyzed and coded before the results of this research was presented in the following text. Many entrepreneurial personality traits were discovered and confirmed during the studies conducted over the last sixty years, these include but are not limited to Need for Achievement, Locus of Control, or risk taking propensity. Motivation is clearly the main trigger to start your own business. During the studies reasons were discovered of how and why an entrepreneur may become successful outside of posessing the right combination of traits. For example: having human, financial and social capital, an entrepreneurial behavior and the right economic conditions to start a business that will survive for more than five years.
Bei der Olivenölproduktion fallen innerhalb kürzester Zeit große Mengen Olivenabwasser (OMW) an. OMW kann aufgrund seines hohen Nährstoffgehalts als landwirtschaftlicher Dünger eingesetzt werden. Doch seine öligen und phenolischen Bestandteile schaden dem Boden. Es ist nicht bekannt, inwiefern jahreszeitliche Temperatur- und Niederschlagsschwankungen den Verbleib und die Wirkung der Abwasserkomponenten im Boden längerfristig beeinflussen. Um dem nachzugehen, wurden jeweils 14 L OMW m-2 im Winter, Frühling und Sommer auf verschiedenen Parzellen einer Olivenplantage ausgebracht. Hydrologische Bodeneigenschaften (Wassertropfeneindringzeit, Wasserleitfähigkeit, Kontaktwinkel), physikalisch-chemische Parameter (pH, EC, lösliche Ionen, phenolische Verbindungen, organischer Kohlenstoff) sowie der biologische Abbau (Köderstreifen) wurden erfasst, um den Zustand des Bodens nach der Applikation zu beurteilen. Nach einer Regensaison war die Bodenqualität der im Sommer behandelten Flächen signifikant reduziert. Dies wurde insbesondere anhand einer dreimal niedrigeren biologischen Fraßaktivität, zehnmal höherer Hydrophobizität, sowie einem viermal höheren Gehalt an phenolischen Substanzen im Vergleich zu den Kontrollflächen deutlich. Die Ausbringung im Winter zeigte gegenteilige Effekte, welche das natürliche Regenerierungspotential des Bodens erkennen lassen. Der Einfluss der Frühlingsapplikation lag zwischen den zuvor genannten. Es wurden keinerlei Anzeichen auf Verlagerung von OMW-Bestandteilen in tiefere Bodenschichten beobachtet. Während der feuchten Jahreszeiten gilt die Ausbringung gesetzlich begrenzter Mengen Olivenabwasser somit als vertretbar. Weitere Forschung ist notwendig um den Einfluss von Frühlingsapplikationen zu quantifizieren und weitere Erkenntnisse über die Zusammensetzung und Mobilität organischer OMW-Bestandteile im Boden zu gewinnen.
Statistical Shape Models (SSMs) are one of the most successful tools in 3Dimage analysis and especially medical image segmentation. By modeling the variability of a population of training shapes, the statistical information inherent in such data are used for automatic interpretation of new images. However, building a high-quality SSM requires manually generated ground truth data from clinical experts. Unfortunately, the acquisition of such data is a time-consuming, error-prone and subjective process. Due to this effort, the majority of SSMs is often based on a limited set of this ground truth training data, which makes the models less statistically meaningful. On the other hand, image data itself is abundant in clinics from daily routine. In this work, methods for automatically constructing a reliable SSM without the need of manual image interpretation from experts are proposed. Thus, the training data is assumed to be the result of any segmentation algorithm or may originate from other sources, e.g. non-expert manual delineations. Depending on the algorithm, the output segmentations will contain errors to a higher or lower degree. In order to account for these errors, areas of low probability of being a boundary should be excluded from the training of the SSM. Therefore, the probabilities are estimated with the help of image-based approaches. By including many shape variations, the corrupted parts can be statistically reconstructed. Two approaches for reconstruction are proposed - an Imputation method and Weighted Robust Principal Component Analysis (WRPCA). This allows the inclusion of many data sets from clinical routine, covering a lot more variations of shape examples. To assess the quality of the models, which are robust against erroneous training shapes, an evaluation compares the generalization and specificity ability to a model build from ground truth data. The results show, that especially WRPCA is a powerful tool to handle corrupted parts and yields to reasonable models, which have a higher quality than the initial segmentations.
This thesis is providing an overview over the current topics and influences of mobile components on Enterprise Content Management (ECM). With a literature review the core topics of enterprise mobility and ECM have been identified and projected on the context of using mobile Apps within the environment of ECM. An analysis of three ECM systems and their mobile software lead to an understanding of the functionalities and capabilities mobile systems are providing in the ECM environment. These findings lead to a better un- derstanding for the usage of mobile Enterprise Content Management and is preparation. The thesis focuses the most important topics, which need to be considered for the usage and adoption of mobile Apps in ECM.
We are entering the 26th year from the time the World Wide Web (WWW) became reality. Since the birth of the WWW in 1990, the Internet and therewith websites have changed the way businesses compete, shifting products, services and even entire markets.
Therewith, gathering and analysing visitor traffic on websites can provide crucial information to un- derstand customer behavior and numerous other aspects.
Web Analytics (WA) tools offer a quantity of diverse functionality, which calls for complex decision- making in information management. Website operators implement Web Analytic tools such as Google Analytics to analyse their website for the purpose of identifying web usage to optimise website design and management. The gathered data leads to emergent knowledge, which provides new marketing opportunities and can be used to improve business processes and understand customer behavior to increase profit. Moreover, Web Analytics plays a significant role to measure performance and has therefore become an important component in web-based environments to make business decisions.
However, many small and medium –sized enterprises try to keep up with the web business competi- tion, but do not have the equivalent resources in manpower and knowledge to stand the pace, there- fore some even resign entirely on Web Analytics.
This research project aims to develop a Web Analytics framework to assist small and medium-sized enterprises in making better use of Web Analytics. By identifying business requirements of SMEs and connecting them to the functionality of Google Analytics, a Web Analytics framework with attending guidelines is developed, which guides SMEs on how to proceed in using Google Analytics to achieve actionable outcomes.
The largest population of the anadromous Allis shad (A. alosa) of the 19th century was found in River Rhine and has to be considered extinct today. To facilitate the return of A. alosa into River Rhine an EU LIFE-project was initiated in 2007. The overall objective of this thesis was to assist aquaculture and stocking-measures at River Rhine, as well as to support restoration and conservation of populations of Allis shad in Europe.
By culturing the free-swimming nematode T. aceti in a solution of cider vinegar we developed a cost-effective live food organism for the larviculture of fish. As indicated by experiments with C. maraena, T. aceti cannot be regarded as an alternative to Artemia nauplii. However it has to be considered a suitable supplemental feed in the early rearing of C. maraena by providing essential fatty acids, thereby optimizing growth.
Also mass-marking practices with Oxytetracycline, as they are applied in the restocking of Allis shad have been evaluated. In experiments with D. rerio we demonstrated that water hardness can detrimentally affect mortality during marking and has to be considered crucial in the development of marking protocols for freshwater fish.
In order to get independent from wild spawners an ex-situ Broodstock-facility for Allis shad was established in 2011. Upon examination of two complete year classes of this broodstock, we found a high prevalence of various malformations, which could be traced back to distinct cysts developing one month post hatch. Despite applying a variety of clinical tests we could not identify any infectious agents causing these malformations. The observed malformations are probably a consequence of suboptimal feeding practices or the properties of the physio-chemical rearing environment.
The decline of stocks of A. alosa in Europe has been largely explained with the increase of river temperatures as a consequence of global warming. By investigating the temperature physiology of larval Allis shad we demonstrated that A. alosa ranges among the most thermo-tolerant species in Europe and that correlations between rising temperatures and the disappearance of this species have to be understood in a synecological context and by integrating a variety of stressors other than temperature. By capturing and examining juvenile and adult Allis shad from River Rhine, we demonstrated the first natural reproduction of A. alosa in River Rhine since nearly 100 years and the success of stocking measures within the framework of the LIFE project.