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With the emergence of current generation head-mounted displays (HMDs), virtual reality (VR) is regaining much interest in the field of medical imaging and diagnosis. Room-scale exploration of CT or MRI data in virtual reality feels like an intuitive application. However in VR retaining a high frame rate is more critical than for conventional user interaction seated in front of a screen. There is strong scientific evidence suggesting that low frame rates and high latency have a strong influence on the appearance of cybersickness. This thesis explores two practical approaches to overcome the high computational cost of volume rendering for virtual reality. One lies within the exploitation of coherency properties of the especially costly stereoscopic rendering setup. The main contribution is the development and evaluation of a novel acceleration technique for stereoscopic GPU ray casting. Additionally, an asynchronous rendering approach is pursued to minimize the amount of latency in the system. A selection of image warping techniques has been implemented and evaluated methodically, assessing the applicability for VR volume rendering.
This Work analyzes if a hardware prototype on an Arduino basis for an Adhoc Network can be created. The objective of the prototype development is, the creation of a sensor node with a modular design, where components can be easily changed. Furthermore the application area has requirements, which the node must fulfill. These requirements are derived from the Tmote Sky sensor node, therefore the new created sensor node must be a possible alternative for it and fulfill the same functions. For that purpose this study reviews some available Arduino microprocessors on their suitability for a sensor node. Later in the work the composition of the sensor node is documented. For this, the hardware and their costs are illustrated. The created hardware prototype allows, through easily changed radio modules, the covering of 433 MHz, 866 MHz and 2,40 GHz radio frequencies. At the end of the work, the sensor node prototype is used in an experiment to check for the suitability for water monitoring. For this, an experiment was performed on land and on water and the results evaluated. In the end the prototype fulfilled most of the requirements, but the cost was a little too high.
This bachelor thesis deals with the development of an application for the Microsoft HoloLens. The application is used for the marketing of advertis- ing spaces that belongs to the company awk AUSSENWERBUNG GmbH. On basis of the development, the question is answered which are the pos- sibilities and limitations of the HoloLens and the Mixed Reality Platform. Problems are also addressed, that come along with the development of an application for such a new technology, like the HoloLens is. Beside the new technologies, some challenges come also from the applications oper- ational locations. Several application examples and presentations suggest, that the HoloLens is primarily designed for indoor usage. Instead the de- veloped application is for outdoor use only. During the development, sev- eral insights can be gained about this new technology. On the one hand it becomes clear, that the HoloLens and also the development environment aren’t completely matured yet. On the other hand, that the HoloLens isn’t an outdoor device at all. Despite the difficulties during the development, there occur many possibilities that are associated with this new technology.
Im schulischen Kontext wird dem Prozess der Erkenntnisgewinnung in eigenverantwortlichen Lernprozessen immer mehr Bedeutung beigemessen. Experimentelles Arbeiten wird in den nationalen Bildungsstandards als Prozess beschrieben, welcher vier Teil-schritte durchläuft: (1) Fragestellung entwickeln, (2) Experimente durchführen, (3) Daten notieren und (4) Schlussfolgerung ziehen [1]. In der fachdidaktischen Forschung gibt es bisher keine Untersuchungen, die explizit den Teilschritt der Datenaufnahme und dessen Bedeutung behandeln.
In dieser Arbeit werden die unterschiedlichen Definitionen der naturwissenschaftlichen Protokollformen voneinander abgegrenzt sowie im Rahmen von drei Teilstudien die Bedeutung des Protokollierens für die Lernwirksamkeit untersucht. Zusätzlich wird eine Auswertungsmethode für die Qualität von Erarbeitungsprotokollen vorgestellt.
This thesis tests several methods and measures in pathtracing for selecting either the Line Space or the Bounding Volume Hierarchy data structure to make use of the advantages of both. The structures are defined locally around each object and each Line Space shaft contains one candidate ID each. All implementation is done as a C++ and OpenGL framework with compute shaders handling the pathtracing and Line Space generation. The measures include the probability distribution, the effect dependency, as well as a distance threshold and are tested against several different scenes. In most situations, the results show a noticeable increase in performance, partly only with minor visual differences, with the probability measure producing the highest quality images for a given performance. The fundamental problems of the Line Space concering the high memory consumption and a long generation time compared to the BVH still persist, despite the object local structure, a minimal amount of data per shaft and the compute shader implementation.
Campuszeitung Ausg. 1/2017
(2017)
Coordination and awareness mechanisms are important in systems for Computer-Supported Cooperative Work (CSCW) and traditional groupware systems. It has been a key focus of research into collaborative groupware and its capability to enable people to efficiently collaborate and coordinate work. Until now, no classification of the mechanisms has been undertaken to identify commonalities and differences in coordination and awareness mechanisms and to show their significance in collaborative environments. In addition, there is a little investigation of coordination and awareness mechanisms in new forms of groupware such as socially enabled Enterprise Collaboration Systems (ECS). Indeed, both in science and in practices, ECS incorporating social software have become increasingly important. Based on the combination of traditional groupware and social software, ECS also include coordination and awareness mechanisms that may simplify collaboration, but these have not yet been investigated.
Therefore, the aim of this thesis is to identify coordination and awareness mechanisms in the academic literature to provide a general overview of those mechanisms examples. Additionally, this thesis aims to classify the mechanism examples. Based on a deep literature analysis, concepts described in literature are chosen and applied with the intension to analyse the mechanisms and to reach a classification. Based on the classification of the identified mechanisms their commonalities and differences are examined and described to gain a better understanding of them. For illustration purpose, examples of coordination and awareness mechanisms and their application are portrayed. The mechanisms examples refer to the classification groups derived. The selection of the mechanisms for the visualization is based on significant differences in their functionality. Subsequently, the selected mechanisms, more based on traditional groupware, are checked to a limited extend whether they can be found in socially enabled ECS. The collaborative platform of IBM Connections serves as a practical example of ECS incorporating social software. IBM Connections is used at the University of Koblenz to run the platform "UniConnect". On the platform it is investigated which of the identified mechanisms examples of the literature are applied in IBM Connections and which additional mechanisms are created by users. This work is the first step in the study of coordination and awareness mechanisms in socially-enabled ECS. In addition, it is expected to detect new mechanisms which are used while the social factor to collaborative work is new.
The purpose of this thesis is to examine and collect coordination and awareness mechanisms examples in literature to analyse them. Additionally, the purpose is to provide a first overview of mechanisms and to classify them by investigating their commonalities. Beside this thesis should give incentive for further investigations to investigate coordination and awareness mechanisms in socially integrated ECS.
The European weatherfish (Misgurnus fossilis) is a benthic freshwater fish species belonging to the family Cobitidae, that is subjected to a considerable decline in many regions across its original distribution range. Due to its cryptic behavior and low economic value, the causes of threat to weatherfish remained partly unknown and the species is rarely at the center of conservation efforts. In order to address these concerns, the overall aim of the present thesis was to provide a comprehensive approach for weatherfish conservation, including the development of stocking measures, investigations on the species autecology and the evaluation of potential threats. The first objective was to devise and implement a regional reintroduction and stock enhancement program with hatchery-reared weatherfish in Germany. Within this program (2014-2016), a total number of 168,500 juvenile weatherfish were stocked to seven water systems. Recaptures of 45 individuals at two reintroduction sites supported the conclusion that the developed stocking strategy was appropriate. In order to broaden the knowledge about weatherfish autecology and thereby refining the rearing conditions and the selection of appropriate stocking waters, the second objective was to investigate the thermal requirements of weatherfish larvae. Here, the obtained results revealed that temperatures higher than previously suggested were tolerated by larvae, whereas low temperatures within the range of likely habitat conditions increased mortality rates. As weatherfish can be frequently found in agriculturally impacted waters (e.g. ditch systems), they are assumed to have an increased probability to be exposed to chemical stress. Since the resulting risk has not yet been investigated with a focus on weatherfish, the third objective was to provide a methodical foundation for toxicity testing that additionally complies with the requirements of alternative test methods. For this purpose, the acute fish embryo toxicity test was successfully transferred to weatherfish and first results exhibited that sensitivity of weatherfish towards a tested reference substance (3,4-dichloroaniline) was highest compared to other species. On the basis of these findings, the fourth objective was to apply weatherfish embryos for multiple sediment bioassays in order to investigate teratogenic effects derived from sediment-associated contaminants. In this context, weatherfish revealed particular sensitivity to water extractable substances, indicating that sediment contamination might pose a considerable risk. Moreover, as an endangered benthic fish species with high ecological relevance for European waters that are specifically exposed to hazardous contaminants, the weatherfish might be a prospective species for an ecological risk assessment of sediment toxicity. Overall, the present thesis contributed to the conservation of weatherfish by considering a variety of aspects that interact and reinforce one another in order to achieve improvements for the species situation.
Die Analyse ortsbezogener Strukturdaten und Merkmale ist eine der wesentlichen Voraussetzungen für die Bewertung von Standorten und Räumen. Durch die Erfassung der lokalen Ausprägung ausgewählter Standortfaktoren und unter Zuhilfenahme eines Geographischen Informationssystems werden in der vorliegenden Dissertation die Städte und Gemeinden des hessischen Rheingau-Taunus-Kreises kategorisiert und miteinander verglichen. Hierbei erfolgt eine besondere Fokussierung auf die lokal bestehende technische und soziale Infrastruktur, um vorrangig das vorhandene Gewerbe- und Wohnumfeld sowie die darüber hinaus existierenden räumlichen Disparitäten eingehend veranschaulichen und beurteilen zu können.
The Internet of Things (IoT) is a network of addressable, physical objects that contain embedded sensing, communication and actuating technologies to sense and interact with their environment (Geschickter 2015). Like every novel paradigm, the IoT sparks interest throughout all domains both in theory and practice, resulting in the development of systems pushing technology to its limits. These limits become apparent when having to manage an increasing number of Things across various contexts. A plethora of IoT architecture proposals have been developed and prototype products, such as IoT platforms, been introduced. However, each of these architectures and products apply their very own interpretations of an IoT architecture and its individual components so that IoT is currently more an Intranet of Things than an Internet of Things (Zorzi et al. 2010). Thus, this thesis aims to develop a common understanding of the elements forming an IoT architecture and provide high-level specifications in the form of a Holistic IoT Architecture Framework.
Design Science Research (DSR) is used in this thesis to develop the architecture framework based on the pertinent literature. The development of the Holistic IoT Architecture Framework includes the identification of two new IoT Architecture Perspectives that became apparent during the analysis of the IoT architecture proposals identified in the extant literature. While applying these novel perspectives, the need for a new component for the architecture framework, which was merely implicitly mentioned in the literature, became obvious as well. The components of various IoT architecture proposals as well as the novel component, the Thing Management System, were combined, consolidated and related to each other to develop the Holistic IoT Architecture Framework. Subsequently, it was shown that the specifications of the architecture framework are suitable to guide the implementation of a prototype.
This contribution provides a common understanding of the basic building blocks, actors and relations of an IoT architecture.
This dissertation will discuss the theories of exponents of the philosophy of dialogue. Through that it shall establish the basis to reflect entrepreneurial leadership action. The goal is to find an approach for the development of a dialogical leadership culture.
The empirical part shall examine on what basis, in correlation with a dialogical leadership style, subjective assumptions are made by managers in their leadership action who work in inpatient nursing services. Furthermore, it shall address the question of how those subjective assumptions can be considered and utilized towards establishing future dialogically oriented leadership cultures and the development of coinciding management personnel.
It shall also debate the question to what extent the philosophy of dialogue includes theoretical concepts which can be used to describe a leadership culture. The intellectual approach of Martin Bubers is especially taken into consideration.
Based on these theoretical grounds, the attempt shall be made to develop the basic intention of a dialogical leadership culture which will appropriately justify a didactical concept for the development of management personnel in nursing services.
Grundwasser ist eine lebenswichtige Ressource und gleichzeitig ein thermisch stabiler Lebensraum mit einer außergewöhnlichen Fauna. Aufgrund der Klimageschichte der letzten ca. 1,8 Millionen Jahre in Mitteleuropa war die Ausgangshypothese, dass die meisten Grundwasserarten an Temperaturen unterhalb von 14 °C angepasst sind und sich Temperaturerhöhungen daher negativ auf die Grundwasserfauna auswirken.
Um die Folgen einer Klimaerwärmung in situ beurteilen zu können, wurden anthropogen erwärmte Grundwässer als Modelle herangezogen. In ersten Teil dieser Arbeit wurden die Crustaceagemeinschaften natürlich temperierter und anthropogen erwärmter Standorte untersucht. Dazu wurden insgesamt 70 Grundwassermessstellen im Oberrheingraben über ein Jahr (2011 bis 2012) sechsmal beprobt. Ergänzend zu diesem synökologischen Ansatz wurde in einem zweiten Teil die Temperaturpräferenz ausgewählter Arten überprüft. Für diese autökologische Betrachtung wurde ein deutschlandweiter Datensatz herangezogen.
Die ausgewählten Untersuchungsgebiete haben sich als geeignete Modelle für die prognostizierten Temperaturerhöhungen herausgestellt. Die Temperatur erwies sich als einer der wichtigsten Parameter für die Crustaceagemeinschaften. Erwärmungen beeinflussen die Zusammensetzung der Gemeinschaften und die Diversität. Dabei zeigte sich, dass es artspezifisch unterschiedliche Temperaturpräferenzen gibt. Einige vermutlich weniger streng stygobionte Arten scheinen höhere Temperaturen zu tolerieren. Der Großteil der stygobionten Grundwasserarten bevorzugt allerdings Temperaturen unterhalb von 14 °C, wobei wenige Arten als „extrem kalt¬steno-therm“ einzustufen sind. Diese Arten wurden an Standorten nachgewiesen, die aufgrund der hydrologischen Verhältnisse relativ kühl sind und der Fauna auch zukünftig als kalte Refugien Schutz bieten könnten. Einer dieser Standorte ist aufgrund seiner Artenvielalt als „Hot Spot“ einzustufen. Die Ergebnisse legen nahe, dass vor allem kaltstenotherme Arten durch eine Klimaerwärmung und anthropogene Wärmeeinträge gefährdet sind.
Die Untersuchung zeigt, dass Grundwasserlebensräume vor Temperaturerhöhungen zu bewahren sind. Lokale anthropogene Wärmeeinträge sollten keine dauerhafte und großflächige Grundwassererwärmung über 14 °C zur Folge haben. Thermische Ein-träge sollten überwacht und bewertet werden. Es wird empfohlen, die bestehenden rechtlichen Rahmenbedingungen den ökologischen Erfordernissen anzupassen.
This thesis explores different approaches for the acceleration of raytracing calculations on the graphics processing unit (GPU). For that a voxel grid is used and extended by the linespace data structure. The linespace consists of direction based shafts and stores the objects located in those shafts in a candidate list. Different methods for the sorting and traversal of the linespace are presented and evaluated. The shown methods cannot provide a speed up of the frame rate without resulting in a loss of image quality.
World’s ecosystems are under great pressure satisfying anthropogenic demands, with freshwaters being of central importance. The Millennium Ecosystem Assessment has identified anthropogenic land use and associated stressors as main drivers in jeopardizing stream ecosystem functions and the
biodiversity supported by freshwaters. Adverse effects on the biodiversity of freshwater organisms, such as macroinvertebrates, may propagate to fundamental ecosystem functions, such as organic matter breakdown (OMB) with potentially severe consequences for ecosystem services. In order to adequately protect and preserve freshwater ecosystems, investigations regarding potential and observed as well as direct and indirect effects of anthropogenic land use and associated stressors (e.g. nutrients, pesticides or heavy metals) on ecosystem functioning and stream biodiversity are needed. While greater species diversity most likely benefits ecosystem functions, the direction and magnitude of changes in ecosystem functioning depends primarily on species functional traits. In this context, the functional diversity of stream organisms has been suggested to be a more suitable predictor of changes in ecosystem functions than taxonomic diversity.
The thesis aims at investigating effects of anthropogenic land use on (i) three ecosystem functions by anthropogenic toxicants to identify effect thresholds (chapter 2), (ii) the organic matter breakdown by three land use categories to identify effects on the functional level (chapter 3) and (iii)on the stream community along an established land-use gradient to identify effects on the community level.
In chapter 2, I reviewed the literature regarding pesticide and heavy metal effects on OMB, primary production and community respiration. From each reviewed study that met inclusion criteria, the toxicant concentration resulting in a reduction of at least 20% in an ecosystem function was standardized based on laboratory toxicity data. Effect thresholds were based on the relationship between ecosystem functions and standardized concentration-effect relationships. The analysis revealed that more than one third of pesticide observations indicated reductions in ecosystem functions at concentrations that are assumed being protective in regulation. However, high variation within and between studies hampered the derivation of a concentration-effect relationship and thus effect thresholds.
In chapter 3, I conducted a field study to determine the microbial and invertebrate-mediated OMB by deploying fine and coarse mesh leaf bags in streams with forested, agricultural, vinicultural
and urban riparian land use. Additionally, physicochemical, geographical and habitat parameters were monitored to explain potential differences in OMB among land use types and sites. Regarding results, only microbial OMB differed between land use types. The microbial OMB showed a negative relationship with pH while the invertebrate-mediated OMB was positively related to tree cover. OMB responded to stressor gradients rather than directly to land use.
In chapter 4, macroinvertebrates were sampled in concert with leaf bag deployment and after species identification (i) the taxonomic diversity in terms of Simpson diversity and total taxonomic
richness (TTR) and (ii) the functional diversity in terms of bio-ecological traits and Rao’s quadratic entropy was determined for each community. Additionally, a land-use gradient was established and the response of the taxonomic and functional diversity of invertebrate communities along this gradient was investigated to examine whether these two metrics of biodiversity are predictive for the rate of OMB. Neither bio-ecological traits nor the functional diversity showed a significant relationship with
OMB. Although, TTR decreased with increasing anthropogenic stress and also the community structure and 26 % of bio-ecological traits were significantly related to the stress gradient, any of these shifts propagated to OMB.
Our results show that the complexity of real-world situations in freshwater ecosystems impedes the effect assessment of chemicals and land use for functional endpoints, and consequently our potential to predict changes. We conclude that current safety factors used in chemical risk assessment may not be sufficient for pesticides to protect functional endpoints. Furthermore, simplifying real-world stressor gradients into few land use categories was unsuitable to predict and quantify losses in OMB. Thus, the monitoring of specific stressors may be more relevant than crude land use categories to detect effects on ecosystem functions. This may, however, limit the large scale assessment of the status of OMB. Finally, despite several functional changes in the communities the functional diversity over several trait modalities remained similar. Neither taxonomic nor functional diversity were suitable predictors of OMB. Thus, when understanding anthropogenic impacts on the linkage between biodiversity and ecosystem functioning is of main interest, focusing on diversity metrics that are clearly linked to the stressor in question (Jackson et al. 2016) or integrating taxonomic and functional metrics (Mondy et al., 2012) might enhance our predictive capacity.
Agricultural land-use may lead to brief pulse exposures of pesticides in edge-of-field streams, potentially resulting in adverse effects on aquatic macrophytes, invertebrates and ecosystem functions. The higher tier risk assessment is mainly based on pond mesocosms which are not designed to mimic stream-typical conditions. Relatively little is known on exposure and effect assessment using stream mesocosms.
Thus the present thesis evaluates the appliacability of the stream mesocosms to mimic stream-typical pulse exposures, to assess resulting effects on flora and fauna and to evaluate aquatic-terrestrial food web coupling. The first objective was to mimic stream-typical pulse exposure scenarios with different durations (≤ 1 to ≥ 24 hours). These exposure scenarios established using a fluorescence tracer were the methodological basis for the effect assessment of an herbicide and an insecticide. In order to evaluate the applicability of stream mesocosms for regulatory purposes, the second objective was to assess effects on two aquatic macrophytes following a 24-h pulse exposure with the herbicide iofensulfuron-sodium (1, 3, 10 and 30 µg/L; n = 3). Growth inhibition of up to 66 and 45% was observed for the total shoot length of Myriophyllum spicatum and Elodea canadensis, respectively. Recovery of this endpoint could be demonstrated within 42 days for both macrophytes. The third objective was to assess effects on structural and functional endpoints following a 6-h pulse exposure of the pyrethroid ether etofenprox (0.05, 0.5 and 5 µg/L; n = 4). The most sensitive structural (abundance of Cloeon simile) and functional (feeding rates of Asellus aquaticus) endpoint revealed significant effects at 0.05 µg/L etofenprox. This concentration was below field-measured etofenprox concentrations and thus suggests that pulse exposures adversely affect invertebrate populations and ecosystem functions in streams. Such pollutions of streams may also result in decreased emergence of aquatic insects and potentially lead to an insect-mediated transfer of pollutants to adjacent food webs. Test systems capable to assess aquatic-terrestrial effects are not yet integrated in mesocosm approaches but might be of interest for substances with bioaccumulation potential. Here, the fourth part provides an aquatic-terrestrial model ecosystem capable to assess cross-ecosystem effects. Information on the riparian food web such as the contribution of aquatic (up to 71%) and terrestrial (up to 29%) insect prey to the diet of the riparian spider Tetragnatha extensa was assessed via stable isotope ratios (δ13C and δ15N). Thus, the present thesis provides the methodological basis to assess aquatic-terrestrial pollutant transfer and effects on the riparian food web.
Overall the results of this thesis indicate, that stream mesocosms can be used to mimic stream-typical pulse exposures of pesticides, to assess resulting effects on macrophytes and invertebrates within prospective environmental risk assessment (ERA) and to evaluate changes in riparian food webs.
Since software influences nearly every aspect of everyday life, the security of software systems is more important than ever before. The evaluation of the security of a software system still poses a significant challenge in practice, mostly due to the lack of metrics, which can map the security properties of source code onto numeric values. It is a common assumption, that the occurrence of security vulnerabilities and the quality of the software design stand in direct correlation, but there is currently no clear evidence to support this. A proof of an existing correlation could help to optimize the measurements of program security, making it possible to apply quality measurements to evaluate it. For this purpose, this work evaluates fifty open-source android applications, using three security and seven quality metrics. It also considers the correlations between the metrics. The quality metrics range from simple code metrics to high-level metrics such as object-oriented anti-patterns, which together provide a comprehensive picture of the quality. Two visibility metrics, along with a metric that computes the minimal permission request for mobile applications, were selected to illustrate the security. Using the evaluation projects, it was found that there is a clear correlation between most quality metrics. By contrast, no significant correlations were found using the security metrics. This work discusses the correlations and their causes as well as further recommendations based on the findings.
Die vorliegende Doktorarbeit hatte zum Ziel zu prüfen, ob Emulsionspolymere auf Acrylatbasis als neuartige Photokatalysatoren bzw. Katalysatoren genutzt werden können.
Auf Grund der Beschaffenheit und der Eigenschaften von Emulsionspolymeren ist davon auszugehen, dass die Nutzung selbiger als Katalysatoren eine neue Art einer chemischen Katalyse ermöglicht. So sollen die Vorteile der heterogenen und homogenen Katalyse vereint und die jeweiligen Nachteile minimiert werden. Als besonders erfolgversprechend hat sich während der praktischen Arbeit die Nutzung von Emulsionspolymeren als Photokatalysatoren herausgestellt.
Die Anbindung der photokatalytisch aktiven Moleküle an/in den Polymerstrang soll kovalent erfolgen. Deshalb war ein erstes Teilziel dieser Arbeit prototypische Katalysatormoleküle zu synthetisieren, die über einen Acrylat-Substituenten verfügen, der in einer radikalischen Polymerisationsreaktion reagieren kann. Als Photokatalysatoren wurden Ruthenium- Polypyridin-Komplexe ausgewählt, die sowohl für eine inter- als auch intramolekulare Photokatalyse zur Herstellung von Wasserstoff aus Wasser geeignet sind. Für organokatalytische Zwecke wurde ein L-Prolin-Derivat synthetisiert, welches jedoch nicht auf seine Polymerisierbarkeit getestet wurde.
In einem ersten Schritt wurden die prototypischen 2,2’-Bipyridin-Liganden synthetisiert. Dabei konnte eine verbesserte Synthesemethode für 4-Brom-2,2’-bipyridin ausgearbeitet werden. Die Funktionalisierung erfolgte letztendlich durch eine Horner-Wadsworth-Emmons-Reaktion, die anschließend an eine Eintopfsynthese zur Darstellung von 4-Formyl-2,2’-biypridin erfolgte. Die prototypischen Photokatalysatoren zeigten mäßige Erfolge (TON: 37-136, 6h, 10% H2O, 470 nm) in Bezug auf die photokatalytische Wasserstoffproduktion, sodass an dieser Stelle eine Verbesserung der entsprechenden katalytischen Systeme erfolgen sollte.
Die Polymerisationsreaktion konnte für zwei intermolekulare Photokatalysatoren und zwei intramolekulare Photokatalysatoren durchgeführt werden. Dabei fiel auf, dass die intermolekularen Photokatalysatoren besser polymerisieren als die intramolekularen Photokatalysatoren. Es wird angenommen, dass dies mit der Löslichkeit der Substanzen im Monomer Ethylmethacrylat zusammen hängt.
Die photokatalytisch funktionalisierten Emulsionspolymere zeigten eine ähnliche photokatalytische Aktivität (TON: 9-101, 6h, 10% H2O, 470 nm) wie die jeweiligen Ausgangsstoffe selbst. Es konnte jedoch bewiesen werden, dass Emulsionspolymere als Photokatalysatoren genutzt werden können, wenn auch noch weitere Arbeiten zur Optimierung der Systeme nötig sind.
The market for virtual reality is rapidly evolving regarding its hardware components. Further applications are the result of this progress. In addition to the gaming market virtual reality offers further possibilities and advantages in research. That way this technology provides the investigation of perceptual phenomena. Therefore the present thesis aimed to examine the induced roelofs effect in a virtual environment and in reality in front of a computer screen. The roelofs effect describes a misperception that occurs if a persons midline and a target surrounding frame are offset, which results in a false localisation of the object. Thus the present study provides insight into the influence of a computer screen regarding this effect. Moreover, conclusions concerning the suitability of virtual reality in perceptual research are drawn. The results obtained by the virtual reality indicated a greater degree of perceptual distortion. Therefore the fixed frame of the computer screen can be assumed as an additional orientation.
An assistance system has been developed for the purpuse of supporting the surgeon during the repositioning phase of intramedullary nailing of femural shaft fractures. As a basic principle the high forces generated by femural muscles and ligaments are taken by a linear sledge and a threaded rod. In order to move bone fragments directly Schanz screws are used as bone-machine interface. Two more Schanz screws are used for fine tuning orientation and position of the fragments according to the well known Joystick technique. The screws are fixed to two articulated arms, one passive and one fully robotic with manipulator. Thanks to the serial kinematic configuration of the system only minmal space of the surgeons working area gets occupied. Running a realtime operating system, the central control unit consits could be implemented as an embedded system comprising of a ARM Cortex-M0 microcontroller at it’s heart. This enables realtime computation and motor control of each joints value of the robotic arm using inverse kinematics. As inverse kinematics solver the iterative FABRIK algorithm was chosen. Serving as innovative and single user interface for the surgeon an optical force-torque sensor is used. The robotic arm always follows the surgeons motion when interacting with the sensor. Using the proposed demonstrator system a positioning resulution of <0,1mm could be accomplished. Thus by using the proposed solution during intramedullary nailing of femural shaft fractures a tremendous gain in positioning precision of bone fragments can be achieved. Furthermore a massive reduction of x-ray exposition of the surgeon is possible when applying the proposed approach. Also this approach enables the chance of cost reduction of femural fracture therapy due to reduction of needed time and staff.